| 研究生: |
莊偉祥 Wei-Xiang Zhuang |
|---|---|
| 論文名稱: |
光亮劑於鍍銀銅粉形貌之機制探討及電性影響 The effect of the brightener on the morphology of silver-coated copper powder and its electrical properties |
| 指導教授: |
劉正毓
Cheng-Yi Liu |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程與材料工程學系 Department of Chemical & Materials Engineering |
| 論文出版年: | 2019 |
| 畢業學年度: | 107 |
| 語文別: | 中文 |
| 論文頁數: | 45 |
| 中文關鍵詞: | 無電鍍 、銅 、銀 、光亮劑 |
| 外文關鍵詞: | electroless, copper, sliver, brightener |
| 相關次數: | 點閱:11 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
銀粉廣泛應用於電子元件中的銀膠。但由於銀粉成本高的緣故,銅粉被研究以用來代替銀粉。然而,銅粉表面很容易在大氣中形成氧化物,而造成電阻率高於銀粉。在這項研究中,我們製備了鍍銀銅粉以改善銅粉表面會氧化的情況。首先,製備銅粉溶液和銀離子溶液並混合在一起以將銀沉積在銅粉表面上。並且,在實驗中控制光亮劑的比例。銅粉一開始的形狀為類球狀顆粒,在經過沒有光亮劑的無電鍍,本論文觀察到較少的多面體鍍銀銅粉顆粒。但在具有光亮劑的條件下我們發現了更多的多面體鍍銀銅粉顆粒。光亮劑的作用是因為光亮劑吸附在銅表面上影響鍍銀銅粉形成多面體結構。然後,我們將鍍銀銅粉配置成鍍銀銅膠,測量鍍銀銅膠的電阻率。透過這個測量,我們發現電阻率會隨著多面體顆粒數量的增加而降低。
Silver powders are widely used in electronic devices by silver paste. Because the cost of the silver powders, copper powders was used to replace the silver powders. However copper powders are very easy to be oxides in atmosphere and the resistivity higher than silver powders. In this study, we prepared silver-coated copper powder to improve. Firstly, copper solution and silver solution were prepared and mixed together to deposit the silver on copper powders. Secondly, the composition of brightener was controlled in this experiment. Originally, copper powders were spherical particles and the results showed that less polyhedral particles were observed after electroless plating without brighteners. But more polyhedral particles were found in the conditions with brighteners. The reason for the effect of brightener that brightener adsorbed on copper surface and then affected its structure. Then, we prepared silver-plated copper powder into paste and measure the resistivity of silver-coated copper paste. Through the measurement, we found that the resistivity decrease as the number of polyhedral particles increase.
1. P. J. Clarke, A.K. Ray, and C.A Hogarth, International journal of electronics, Vol. 69(3), 333-338, 1990
2. J. Tao, N. W. Cheung, and C. Hu, IEEE Electron device letters, Vol. 14(12), 213-215, 1993
3. M. Sekiguchi, K. Sawada, M. Fukumoto, and T. Kouzaki, Journal of vacuum science & technology B, Vol. 12(5), 2992-2996, 1994
4. C. E. Ho, S. C. Yang, and C. R. Kao, J Mater Sci: Mater Electron, Vol. 18, 155-174, 2007
5. K. Zeng, and K. N. Tu, Materials Science and Engineering: R: Reports, Vol. 38, 55-105, 2002
6. J. H. Lau Flip, and Chip Technologies. New York: McGraw-Hill, 1996
7. 陳俊榮,觸控面板關鍵材料-UV硬化型導電銀膠,工業材料294期,2011
8. Huann-Wu Chiang, Cho-Liang Chung, Liu-Chin Chen, Yi Li, C. P. Wong and Shen-Li Fu, J. Adhesion Sci. Technol., Vol. 19, 565–578, 2005
9. Zheliang Wei, Dian Tang and Thomas O’Keefe, China Part, Vol. 3, 271-274, 2005
10. T. K. Huang, T. H. Cheng, M. Y. Yen, W. H. Hsiao, L. S. Wang, F. R. Chen, J. J. Kai, C.Y. Lee and H. T. Chiu, Growth of Cu Nanobelt and Ag Belt-Like Materials by Surfactant-Assisted Galvanic Reductions, Langmuir, vol. 23,5722-5726, 2007
11. Melinda Mohl, Dorina Dobo, Akos Kukovecz, Zoltan Konya, Krisztian Kordas, Jinquan Wei, Robert Vajtai, and Pulickel M. Ajayan, J. Phys. Chem. C, 2011, 115, 19, 9403-9409
12. U Schubert, N Hüsing, Synthesis of inorganic materials, Weinheim : WILET-VCH, 2005, pp. 342-343
13. 王鳳英譯,界面活性劑之原理與應用,台北:高立圖書有限公司,1986,第3-4頁。
14. G. Cao and Y. Wang, Nanostructures and nanomaterials, Singapore : World Scientific, 2011, 310-311
15. Tzu-Chi Chen, Yao-Lin Tsai, Chia-Fu Hsu, Wei-Ping Dow, Yasuo Hashimoto, Electrochimica Acta, Vol. 212, 572-582, 2016
16. Chunju Xu, Ruihua Zhou, Huiyu Chen, Xin Hou, Guilin Liu, Yaqing Liu, J Mater Sci, Mater Electron, 4638–4642, 2014
17. Zheliang Wei, Dian Tang and Thomas O’Keefe, China Part, Vol. 3, 271-274, 2005
18. Xinrui Xu, Xiaojun Luo, Hanrui Zhuang, Wenlan Li, Baolin Zhang, Materials Letters, vol. 57, 3987– 3991, 2003
19. Zenglin Wang,Zhijuan Liu, Hongyan Jiang, and Xiu Wei Wang, Journal of Vacuum Science and Technology B, Vol 24, 2006
20. H.T. Hai , J.G. Ahn , D.J. Kim , J.R. Lee , H.S. Chung , C.O. Kim, Surface and coating technology, vol. 201, 3788-3792, 2006
21. Jun Zhao, Dongming Zhang, Xingjuan Song, Applied Surface Science, vol. 258, 7430– 7434, 2012
22. Zhang Ju-Guo, Fu Qiu-Ya, surface technology, vol. 36, 28-36, 2007