| 研究生: |
呂品瑩 Ping-Ying Lu |
|---|---|
| 論文名稱: |
以液液萃取法結合基質輔助雷射脫附游離飛行時間質譜儀檢測水樣中聚苯乙烯塑膠微粒 |
| 指導教授: |
丁望賢
Wang-Hsien Ding |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 化學學系 Department of Chemistry |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 46 |
| 中文關鍵詞: | 基質輔助雷射脫附游離飛行時間質譜儀 、液液萃取法 、塑膠微粒 、聚苯乙烯 |
| 外文關鍵詞: | MALDI, Liquid-liquid extraction, Micro/nanoplastics, Polystyrene |
| 相關次數: | 點閱:9 下載:0 |
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塑膠產品的廣泛應用衍生出大量廢棄物,廢棄物的處理不當使得大量塑膠汙染物被排放到環境中,如今塑膠微粒對海洋的污染已經成為全球關注的議題,因其聚合物不易被分解的性質,長時間下易累積於環境中,再加上塑膠易吸附其他有機與重金屬汙染物,使其對生物體有著潛在的危害,而建立塑膠汙染物的檢測方法將能為我們追朔汙染源頭,利於進行整治與改善。
現今針對塑膠微粒的標準檢測方法尚未定案,而目前普遍的檢測方法,如FT-IR、Raman等光譜技術常包括費工耗時的樣品純化步驟,因此本研究使用簡單的液液萃取法(Liquid-liquid extraction)和基質輔助雷射脫附游離飛行時間質譜技術(MALDI-TOF-MS),並選擇聚苯乙烯(Polystyrene,PS)塑膠微粒作為代表,探討此兩種快速、簡便的方法是否能優化現今塑膠微粒的檢測。
Currently, microplastic particles have been concerned as a group of emerging contaminants in surface water and marine environment. In this study, we combined two simple and rapid tools—liquid-liquid extraction (LLE) and matrix-assisted laser desorption ionization time-of-flight mass spectrometer (MALDI-TOF MS) in order to improve the time-consuming and laborious defects for microplastics particles detection, and polystyrene (PS) was used as the model microplastic particles.
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