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研究生: 吳庭昀
Ting-Yun Wu
論文名稱: 銀-聚苯乙烯殼核球於高分子分散液晶薄膜元件之應用
Application of Ag-PS Core Shell Microspheres Doped Polymer Dispersed Liquid Crystal Film
指導教授: 陳啟昌
Chii-Chang Chen
詹佳樺
Chia-Hua Chan
口試委員:
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Optics and Photonics
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 87
中文關鍵詞: 高分子分散液晶薄膜液晶
外文關鍵詞: PDLC, LC
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  • 在本論文中,我們探討PMMA微米球及銀微米球摻雜在高分子分散液晶(Polymer Dispersed Liquid Crystal, 簡稱PDLC)中的光電特性,藉由操作電壓的調變可以控制此元件從散射態轉為穿透態。
    本實驗分成三部分,實驗的第一部分我們利用不同的高分子材料,分析材料對於PDLC光電性質之影響,第二部分我們在PDLC元件中摻入直徑為3m之PMMA微米球,維持穿透態應有穿透率並降低操作電壓,第三部分的實驗,將直徑為3m之銀微米球摻入PDLC元件,大幅降低了元件從散射態至穿透態所需之操作電壓。
    PDLC光電性質優化之結果,我們利用摻雜5 wt%、直徑為3微米之銀微米球摻入PDLC中,操作電壓為44伏特且穿透態維持高穿透率70%,有效的降低操作電壓,減少元件操作時能源的損耗。最後,我們利用此結果,進行大尺寸之PDLC元件製作,增加實際的應用性。


    In this study, we investigate the electro-optic properties of Polymer Dispersed Liquid Crystal (PDLC) doped with PMMA and Ag microspheres. It can be switched from light scattering to transparent states by modulating the applied AC voltage.
    The study in this thesis is divided into three parts. In the first part, we discussed the influence of the weight ratio of LC and polymer on their electric-optic properties. In the second part of experiment, the required applied AC voltage to obtain transparent state can be reduced by doping PMMA microspheres whose diameter is about 3 um. In the third part of experiment, it is demonstrated that the applied AC voltage can be further reduced by doping with 3 m-diameter silver microspheres.
    By doping with 5 wt% 3 m-diameter silver microspheres into PDLC cell, the electro-optic properties of PDLC can be optimized. The operating voltage to provide 70 % transmittance is reduced to 44 V, so that the energy consumption can be reduced significantly. Additionally, we have also successfully demonstrated such a PDLC device having large panel size.

    摘要……………………………………………………………………...…I Abstract………………………………………………………………….…II 致謝……………………………………………………………………….III 圖目錄…………………………………………………………………..VIII 表目錄…………………………………………………………….……..XII 第一章 緒論 …………………………………………...…………..……..1 1.1 前言 ………………………………………………………….......1 1.2 液晶簡介 ………………………………………………………...3 1.2.1 液晶分類 ……………………………………………….....4 1.2.2 液晶的光電特性 …………………………………….....…5 1.3 增強材料之應用 ………………………………………….....…10 1.3.1 高分子分散液晶摻雜染料 …………………….….....….10 1.3.2 液晶填充奈米粒子 ………………………………..….....11 1.3.3 高分子分散液晶摻雜奈米粒子 …………………....…...12 1.4 本章結論與研究動機 …………………………………..……...14 第二章 基本原理 ………………………………….…………….…...…16 2.1高分子分散液晶簡介與散射理論 …………………………......16 2.1.1 PDLC聚合型式及聚合物材料介紹 ….……………...….16 2.1.2 PDLC散光原理 ………………………………………….18 2.1.3 穿透率變化與對比度計算 ………………………….......21 2.1.4 反應時間計算 ……………………………………….......22 2.2 金屬球殼簡介 ……………………………………………...…..23 2.3 結論 ………………………………………………………...…..25 第三章 實驗製程 …………………………………………………….....26 3.1 實驗材料 ……………………………………………………….26 3.2 製作流程 ……………………………………………………….28 3.3 量測儀器與架構 ……………………………………………….32 3.4 結論 …………………………………………………………….32 第四章 實驗結果與討論 ……………………………………………….34 4.1 高分子膠對PDLC之影響 …………………………………….34 4.1.1 高分子膠摻雜濃度對PDLC之影響 …………………...35 4.1.2 交聯劑含量對PDLC光電性質影響 …………………...38 4.2 高分子分散液晶摻雜PMMA ……………………………...…..43 4.3 高分子分散液晶摻雜微米金屬球 …………………………….47 4.3.1 微米金屬球摻雜對PDLC光電性質之影響 …………...49 4.3.2 較大面積之金屬微米球摻入PDLC元件 …………...…61 4.4 結論 …………………………………………………………….63 第五章 總結與未來工作 ……………………………………………….65 5.1 總結 …………………………………………………………….65 5.2 未來工作 ……………………………………………………….66 參考文獻 ……………………………………………………….………..68

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