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研究生: 董孟軒
Meng-Syuan Doong
論文名稱: Sc與Cu含量對A201合金銲接特性之研究
指導教授: 李勝隆
Sheng-Long Lee
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
畢業學年度: 93
語文別: 中文
論文頁數: 61
中文關鍵詞: A201合金銲接熱裂W相TIG銲
外文關鍵詞: Sc, hot cracking in weld, Zr, W phase, A201 alloy, TIG weld
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  • 由於A201合金具有較寬之固液兩相區(123~127℃),容易於鑄件中產生缺陷,故銲接性質差,極易發生銲接熱裂等問題。在Al-Cu合金中添加微量Sc、Zr後,將使晶粒大幅細化而降低銲接熱裂發生,提升合金銲接性;但W(Al5.4-8Cu6.6-4Sc)相之生成,將降低析出強化效果,造成合金強度不足的問題。
    本實驗擬於Al-4.6Cu-0.3Mg-0.6Ag合金中添加0.4Sc及0.1Zr,並分別提高Cu(或卅與Mg、Ag)含量而配置成三種銲料合金,爾後分別對母材A201合金施以TIG銲接,並施以T7時效熱處理,探討Sc與Cu含量對A201合金銲接前後之微結構與機械性質之影響。利用光學顯微鏡(OM)、電子微探儀(EPMA)、導電度計(%IACS)、微差掃描熱分析儀(DSC)、穿透式電子顯微鏡(TEM)、掃描式電子顯微鏡(SEM)、硬度試驗、拉伸試驗(Tensile Test)等方法,探討各銲料合金與TIG銲後試片之微結構與機械性質之關係,並與母材A201合金做一比較。
    結果顯示,含微量Sc、Zr之Al-Cu-Mg-Ag合金,於凝固時會晶出Al3(Sc,Zr)相及W相,使晶粒大幅細化;而W相之生成會消耗Cu元素,且無法藉由固溶處理回溶至基地內,減少Cu原子固溶量,導致降低合金強度及延性。提高Cu含量後,可提升材料強度,且不改變合金中良好的細晶組織;提高Mg含量,亦可提升材料強度,但大幅降低延性。此外,以含Sc、Zr之Al-Cu-Mg-Ag合金銲料於母材A201合金上實施TIG銲接後之銲件,其銲道組織皆為等軸細小晶粒,且無熱裂發生;銲件之時效強度皆能維持在A201合金母材之80%以上,延性也可維持在母材A201合金之60%以上。


    摘要………………………………………………………………Ⅰ 謝誌………………………………………………………………Ⅱ 總目錄……………………………………………………………Ⅲ 圖目錄……………………………………………………………Ⅴ 表目錄……………………………………………………………Ⅶ 壹、前言…………………………………………………………1 貳、實驗步驟與方法……………………………………………12 參、結果與討論…………………………………………………18 肆、結論…………………………………………………………55 伍、未來研究方向………………………………………………56 陸、參考資料……………………………………………………57

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