| 研究生: |
王升平 Shen-Ping Wang |
|---|---|
| 論文名稱: |
四氯化鈦 製作納米二氧化鈦透明結晶膜及其應用 |
| 指導教授: |
陳郁文
Yu-Wen Chen |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程與材料工程學系 Department of Chemical & Materials Engineering |
| 畢業學年度: | 88 |
| 語文別: | 中文 |
| 論文頁數: | 82 |
| 中文關鍵詞: | 二氧化鈦 、過氧化氫 、四氯化鈦 |
| 相關次數: | 點閱:5 下載:0 |
| 分享至: |
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本論文以四氯化鈦為原料,研究製作透明納米級二氧化鈦微結晶粒子覆膜液的方法,期望製備出高表面積且具銳鈦礦結晶的二氧化鈦薄膜。
四氯化鈦經過水解、沈澱、酸解及水熱反應等步驟,可製作穩定懸浮的二氧化鈦粒子溶液。利用XRD、DLS、FTIR、TGA、DTA、DSC、BET及TEM等儀器分析探討溶液的酸鹼值、過氧化氫添加量和加熱溫度時間的影響,可以決定最佳的溶液組成及加熱條件如下:
TiO2 / H2O2 / H2O = 1 / 2 / 97 (重量比)
酸鹼值為8、加熱溫度為90℃、加熱時間6~8小時
此時二氧化鈦大部分為長條狀的一次粒子,以TEM觀察粒徑,長軸約10 nm、短軸約4 nm。
將此二氧化鈦粒子溶液以浸漬覆膜方式鍍於玻璃上,可得透明且牢固的光觸媒薄膜基材。在紫外光照射下,測量水與基材間的接觸角,顯示有強烈的親水性。最後以醋酸作為反應測試物進行液相光催化反應,實驗結果證明本研究製備的二氧化鈦具有不錯的光催化能力。
Aegerter, M. A.; Jafelicci, M.; Souza, D. F.; Zanotto, E. D., Sol-Gel Science and Technology, 1989.
Ahmed M. S. and Attia Y. A., Aerogel Materials for Photocatalytic Detoxification of Cyanide Wastes in Water, J. Non-crystalline Solids , 1995, 186, pp. 402-407.
Azaroff L. V. and Buerger, M. J., The powder Method in X-Ray Crystallography, 1970, pp.254-258.
Bischoff, B. L.; Anderson, M. A., Peptization Process in the Sol-Gel Preparation of Porous Anatase(TiO2), Chem. Mater., 1995, 7, pp.1772-1778.
Brinker, C. J. and Scherer G. W., Sol-Gel Science, Academic Press. San Diego U.S.A., 1990.
Chopin, T.; Denis, S. and Fourre, P., Preparation of Sulfur-Free Titanium Dioxide, United States Patent 5,149,519, 1992.
Chrysicopoulou, P.; Davazoglou, D.; Trapalis, C. and Kordas, G., Optical Properties of very thin Sol-Gel TiO2 films., Thin Solid Films, 1998, 323, pp.188-193.
Dibble, L. A. and Raupp, G. B., Fluidized-Bed Photocatalytic Oxidation of Trichloroethylene in Contaminated Air Streams , Environ. Sci. Technol, 1992, 26 (3), pp.492-500.
Fox, G. R.; Adair, J. G. and Newnham, R. E., Effects of pH and H2O2 upon Coprecipitated PbTiO3 Powders, J. Mater. Sci., 1991, 26, pp.1187-1191.
Fu, X.; Zeltner, W. A. and Anderson, M. A., Application in photocatalytic purification of air, Stud. Surf. Sci. Catal., 1996, 103.
Fujigira, M.; Satoh Y. and Wsa, T., Hetergeneous Photocatalytic Reaction on Semiconductor Materials. III . Effect of pH and Cu2+ Ions on the Photo-Fenton Type Reaction, Bull. Chem. Soc. Jpn., 1982, 55 (3), pp. 666-671.
Grishchenko, L. I.; Medvedkova, N. G.; Nazarov, V. V. and Frolov, Y. G., Aggregation stabiliby of titanium dioxides hydrosols, Colloid J., 1994, 56 (2), pp.215-217.
Hung, C. H. and Marinas, B. J. Role of Chloride and Oxygen in the Photocatalytic Degration of Trichloroethylene Vapor on TiO2 Films, Environ. Sci. Technol., 1997, 31, pp.562-568.
Ito, S.; Inoue, S.; Kawada, H.; Iwasaki, M. and Tada, H., Low-Temperature Synthesis of Nanometer-Sized Crystalline TiO2 Particles and Their Photoinduced Decomposition of Formic-Acid, J. Colloid Inter. Sci., 1999, 216 (1), pp.59-64.
Jalava, J. P.; Heikkila, L.; Hovi, O.; Laiho, R.; Hiltunen, E.; Hakanen, A. and Harma, H., Structural Investigation of Hydrous TiO2 Precipitates and Their Aging Products by X-ray Diffraction, Atomic Force Microscopy, and Transmission Electron Microscopy., Ind. Eng. Chem. Res., 1998, 37, pp.1317-1323.
Leofanti, G.; Padovan, M.; Tozzola, G. and Venturelli, B., Surface Area and Pore Texture of Catalysts, Catal. Today, 1998, 41, pp.207-219.
Mills, A.; Davies, R. H.and Worsley, D., Water Purification by Semiconductor Photocatalysis, Chem. Soci. Rev., 1993, pp. 417-425.
Muhlebach, K.; Muller, K. and Schwarzenbach, G., The Peroxo Complexes of Titania, Inorg. Chem., 1970, 9, pp.2381-2390.
Nair, J.; Nair, P.; Mizukami, F.; Oosawa, Y. and Okubo, T., Microstructure and Phase Transformation Behavior of Doped Nanostructured Titania, Mater. Res. Bulle., 1999, 9, 8, pp. 1275-1290.
Nam H. D.; Lee, B. H.; Kim, S.J.; Jung, C. H.; Lee, J. H. and Park, S., Preparation of Ultrafine Crystalline TiO2 Powders from Aqueous TiCl4 Solution by Precipitation, Jpn. J. Appl. Phys., 1998, 37,pp. 4603-4608.
Navio, J. A.; Marchena, F. J.; Macias, M. and Sanchez-soto, P. J., Formation of Zirconium Titanate Powder from a Sol-Gel Prepared Reactive Precursor, J. Mater. Sci., 1992, 27, pp.2463-2467.
Negishi, N.; Takeuchi, K. and Ibusuki, T., Surface Structure of the TiO2 Thin Film Photocatalyst, J. Mater. Sci., 1998, 33, pp.5789-5794.
Park, H. K.; Kim, D. K. and Kim, C. H., Effect of Solvent on Titania Particle Formation and Morphology in Thermal Hydrolysis of TiCl4, J. Am. Ceram. Soc., 1997, 80, 743-749.
Qian, Y.; Chen, Q., Chen, Z., Fan, C. and Zhou, G., Preparation of Ultra Powders of TiO2 by Hydrothermal H2O2 Oxidation Starting from Metallic Ti, J. Mater. Chem., 1993, 3, pp.203-205.
Ragai, J., Characterization of Hydrous Titania from Titanous Chloride:1.Thermal Studies, Chem. Tech. Biotechnol., 1987, 40, pp. 75- .
Richardson S. D.; Thruston A. D.; Collette T. M.; Patterson K. S.; Lykins B. W. and Ireland J. C., Identification of TiO2/UV Disinfection by-Products in Drinking-Water, Environ. Sci. Technol. , 1996, 30, pp. 3327-3334.
Sakamoto, M.; Yokkaichi, H. O., Suzuka, S. K. and Yokkaichi, Y.Y., Titania Sol, United States Patent 5,049,309, 1991.
Sato, G.; Arima, Y.; Tanaka, H. and Hiraoka, S., Titanium dioxide sol and process for preparation thereof, United States Parent 5,403,513, 1995.
Velasco, M. J.; Rubio, F.; Rubio, J. and Oteo, J. L., DSC and FT-IR Analysis of The Drying Process of Titanium Alkoxide Derived Precipitates, Thermochimica Acta, 1999, 326, pp. 91-97.
Wang, H and Adesina, A. A., Photocatalytic Causticization of Sodium Oxalate Using Commercial TiO2 Particles, App. Catal. B Environ., 1997, 14 (3-4), pp.241-247.
Wang, R.; Hashimoto, K.; Fujishima, A.; Chikuni, M.; Kojima, E.; Kitamura, A.; Shimohigoshi, M. and Watanabe, T., Light-induced amphiphilic surfaces, Nature, 1997, 388, pp.431.
Weir, B. A. and Sundstrom D. W., Rate of Destruction of Trichloroethylene by UV Light Catalyzed Oxidation with Hydrogen Peroxide, Paper 52B, AICHE National Meeting, San Francisco, 1989.
Zhang, Q.; Gao, L. and Guo, J., Effects of Calcinations on the Photocatalytic Properties of Nanosized TiO2 Powders Prepared by TiCl4 Hydrolysis, Appl. Catal. B: Envi., 2000, 26, 207-215.