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研究生： 簡鴻名
Hung-Ming Chien
論文名稱： 合成吡啶基吲哚配位之鈀金屬錯合物並探討其光電性質
Synthesis of Palladium Complexes with Pyridylindolide Ligands and Investigation of Their Photoelectric Properties
指導教授： 李文仁
Wen-Ren Li
口試委員:
學位類別： 碩士
Master
系所名稱： 理學院 - 化學學系
Department of Chemistry
論文出版年： 2015
畢業學年度： 103
語文別： 中文
論文頁數： 122
中文關鍵詞： 鈀金屬錯合物
相關次數： 點閱：9  下載：0 
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    • 自工業革命以來，人類的生活便無法缺少能源。而新世代的替代能源當中，染料敏化太陽能電池因其低成本，製程簡易等特色受到相當大的矚目。光敏化劑為染敏電池當中影響效率之重要因素，因此科學家無不投入心力以開發新型具更優秀表現之敏化劑。釕金屬錯合物雖擁有高效率表現，但其因價格

    本文所合成之染料IP-101為具有高總產率之有機染料，而我們嘗試開發以其作為配位基之鈀金屬染料，其以Indole此具高莫耳消光係數之雜環作為基本架構，再引入金屬與其配位，生成4配位之錯合物染料。我們於其錯合物與原先配位基的比較上發現了明顯的紅位移現
    象，而我們亦希望此現象能夠應用於染敏電池之敏化劑。

    Since the industrial revolution, energy has dominated our lives. Among the all renewable energy resources, Dye-Sensitized Solar Cells (DSSC) have received much attention of academic and industrial due to its low-cost and simple manufacturing process. Sensitizer is one of the key components which will greatly affect the performance in DSSC; therefore, numerous researchers have developed various kinds of novel dye and achieve significant efficiency. Ruthenium-based dye was one of the best we have;however, it also led to some serious issues, such as environmental pollution and its rarity; thus, we would like to design some novel metal complex sensitizers to replace it.

    The sensitizer IP-101, made up by indole derivatives possessing the advantage of high total yield, was designed and synthesized, and later play as a ligand in 4-coordinated palladium complex. Compared with the original ligand, the UV-Vis spectrum of palladium complex shows obviously red-shift in absorption band which could be beneficial to sensitizers of dye-sensitized solar cells.

    目錄 摘要 I 目錄 IV 圖目錄 V 表目錄 VI 一、 緒論 1 1-1 前言 1 1-2 太陽能電池 6 1-2-1 太陽能電池之進程 6 1-2-2太陽能電池之種類與其簡介 8 1-3 染料敏化太陽能電池 15 1-3-1 基本組成與運作原理 16 1-3-2 元件內部反應 17 1-3-3 電池詳細架構 22 1-3-4 電池元件參數 28 1-4 文獻回顧 33 1-5 設計理念 54 二、 合成方法與實驗討論 56 2-1 逆合成分析 56 2-2 合成規劃策略 58 2-3 實驗步驟 62 2-4 實驗儀器與藥品來源 74 三、 結果與討論 78 3-1 合成討論 78 3-2 錯合物結構鑑定 85 3-3 錯合物光物理性質探討 87 3-4 未來展望 90 參考文獻 92 附錄 98

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