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研究生: 沈杰倫
Jie-Lun Shen
論文名稱: 等通道轉角擠型製程對含Sc之Al-Mg合金微結構及機械性質之影響
指導教授: 李勝隆
Sheng-Long Lee
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
畢業學年度: 93
語文別: 中文
論文頁數: 59
中文關鍵詞: 等通道轉角擠型Sc含量動態回復再結晶
外文關鍵詞: recrystallization, Sc content, equal-channel-angular-extrusion, dynamic recovery
相關次數: 點閱:8下載:0
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  • 等通道轉角擠型(ECAE)製程具有許多優點,擠製時可旋轉角度來控制材料之變形結構,而經由多次擠製可使材料的塑性變形量達到相當大的程度,且擠製後之材料截面積不會改變,同時亦可獲得均勻且細晶之材料結構。於鋁合金中添加Sc元素能有效細化晶粒及提升合金再結晶溫度,且Al3Sc相於高溫下能有效使晶粒保持細小且穩定之結構。
    本研究利用等通道轉角擠型(ECAE)製程對不同Sc含量之Al-5Mg-0.7Mn合金進行擠製,藉以瞭解ECAE製程與Sc含量(0wt.%、0.3wt.%、0.58wt.%)對合金微結構及機械性質之影響,並觀察不同溫度下進行退火處理後之微結構穩定性及其影響程度,且對擠型後之細晶材料進行高溫拉伸測試,評估其超塑性表現。
    實驗結果指出,添加0.3wt.%Sc即可使鑄態Al-5Mg-0.7Mn合金晶粒細化,而合金強度因細晶強化作用而提升。於300℃下進行ECAE Route BC之方式擠型,可使合金達到細化效果且獲得均勻之微結構,而合金內部極易發生動態回復作用,使得加工硬化率下降。鑄造晶出之Al3Sc相於高溫下能有效阻止晶界移動,提升合金再結晶溫度,此有助於提升合金之高溫延伸率。於450℃下以1×10-2S-1及5×10-2S-1速率進行拉伸,含Sc之合金延伸率皆可達300%以上。


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    摘要………………………………………………………………… Ⅰ 謝誌………………………………………………………………… Ⅱ 總目錄…………………………………………………………….. Ⅲ 圖目錄…………………………………………………………….. Ⅴ 表目錄…………………………………………………………….. Ⅶ 壹、前言…………………………………………………………… 1 一、Al-Mg合金簡介……..………………………………….. 1 二、Sc對鋁合金之影響………………...…………………… 1 三、加工方式…………………………...……………………. 5 四、超塑性………………………………………………..….. 11 五、實驗目的與設計………………………………………… 13 貳、實驗步驟與方法……………………………………………… 15 一、鑄造、擠型與退火處理..……………………………….. 15 1.合金配製及成分分析……………………………………. 15 2.等通道轉角擠型(ECAE)………………………………… 15 3.退火處理…………………………………………………. 17 二、微結構分析…………..………………………………….. 19 1 OM金相觀察……………………………………………… 19 2.穿透式電子顯微鏡觀察(TEM)….………………………. 19 3.導電度量測(IACS%).……………………………………. 19 三、機械性質分析…………………………………………… 21 1.微硬度試驗……………………………….………..…….. 21 2.常溫拉伸試驗…………………………….……………… 21 3.高溫拉伸試驗……….……………………………..…….. 21 參、結果與討論…………………………………………………… 23 一、微結構分析……………………………………………… 23 1.鑄態及ECAE金相觀察…………………………….……. 23 1.1 OM金相觀察………………………………………… 23 1.2穿透式電子顯微鏡觀察(TEM)……………………... 29 1.3導電度量測(IACS%)………………………………... 33 2.退火金相觀察……………………………………………. 33 二、機械性質分析………………………….………………... 42 1.硬度試驗…………………………………………………. 42 1.1鑄態及ECAE擠型…………………………………. 42 1.2退火處理……………………………………………. 44 2.常溫拉伸試驗……………………………………………. 46 3.高溫拉伸試驗……………………………………………. 46 肆、結論…………………………………………………………….54 伍、未來研究方向………………………………………………… 55 陸、參考資料……………………………………………………… 56

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