| 研究生: |
謝宗錦 Tsung-Chin Hsieh |
|---|---|
| 論文名稱: |
4-甲基 The Study of the Synthesis and characteristic for r-picoline cyanine compounds |
| 指導教授: |
郭坤土
Kung-Tu Kuo |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程與材料工程學系 Department of Chemical & Materials Engineering |
| 畢業學年度: | 89 |
| 語文別: | 中文 |
| 論文頁數: | 87 |
| 中文關鍵詞: | 4-甲基 、鹽性基染料 、花青染料 |
| 外文關鍵詞: | r-picoline, base dyes, cyanine |
| 相關次數: | 點閱:2 下載:0 |
| 分享至: |
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花青染料(cyanine)為鹽性基染料,因顏色鮮豔、染色容易,早期為紡織業所用。在十八世紀末被人發現有特殊感光性質,因此可作為彩色底片的感光乳化劑。此外,因儲存資料的快速演變,已由原本的手寫記載演變成現今的光學記載,而光學材料中光敏感之塗料(色料),以花青染料(cyanine)染料為主。
花青染料(cyanine)的種類很多,大部分是由
The cyanine belong to base dyes. In the early stage because of they have high tinctorial power and easy to dye, they were used as textile dyes. In the end of 18 century, it was first discovered that cyanine dyes had photosensitive properties; therefore they could be used as photographic emulsions. Besides, owing to record storage of the information are changed fast, the memory type was transferred from written by hand to optical storage. The optical material is photosensitive dyes (colorants). The dyes were almost used as cyanine.
There is much kind of cyanine dyes; the most of cyanine are constitute by quinoline. They are divided into merocyanine、isocyanine、aza methine cyanine etc.
In this study we use r-picoline that is made for r-picolinium salts then condense with aromatic aldehydes、triethyl orthoformate、1,1,3,3-teramethoxypropane and aromatic nitroso compound in isopropanal-piperidine. Finally we discuss on the characteristic of the synthetic dyes and find out these optimized conditions
1.邱永亮, 魏盛德 編譯, ”染色化學”, 徐氏基金會, 八版, (1985)
2.Chemistry of Carbon Compounds;Ⅳ-B
3.Spalteholz; Chem.Ber.;16;1847;(1883)
4.Mills, W. H.; Wishart, R. S.; J.C.S.; 117; (1920); 579
5.Mills, W. H.; Hamer, F. M.; J.C.S.; 117; (1920); 1550
6.Ciemo; Swan,; J.Chem.Soc,; 1454; (1938)
7.Hamser, C. R.; Humphlett, W. J.; J.A.C.S,; 72; (1950); 3805
8.Compton, C.; Bergmann, W.; J.Org.Chem.; 12; (1947); 363
9.Chem.Abtr.; (1952); 46; 10983d; 10984e; 10985g.
10.Weiss; Hamser; J.A.C.S.; 71; (1949); 2023
11.Horwitz, L.; J.Org.Chem.; 21; (1956); 1039
12.Matsui, M.; Kawamura, S.; Sbibata, K.; Muramatsu, H.; Bull. Chem.Soc.Jpn.; 65; (1992); 71-74
13.Mishra, A.; Behera, R. K.; Fronczek, F. R.; Vidyasagar, M.; Behera, G. B.; Indian J.Chem.Sect.B; EN; 38; 8; (1999); 982-985
14.Cyanine I:Pilyngin, G. T.; Izvest. Akad. Nauk S.S.S.R. otdel. Khim. Nauk; (1952); 512-519
15.Cyanine V:Turitsyna, N. F.; Levkoev, I. I.; Zhur, Obschei, Khim; J.Gen.Chem.; 22; (1952); 309-321
16.Cyanine VII:Levkoev, I. I.; Vompe, A. F.; Sveshnikov, N. N.; Barvyn, N. S.; Zhur. Obshehei. Khim.; 22; (1952); 879-886
17.Phillips; J.Org.Chem.; 14; (1949); 302-303
18.Phillips; J.Amer.Chem.Soc.; 72; (1950); 2780
19.Kung-Tu Kuo,; J. Chinese Chem. Soc.; 25; (1978); 131-139
20.Langhals. H.; Chem.Ber.144; (1981); 2907-2913
21.Zheng, Haipeng; Zhang, Ruifeng; Wu, Ying; Shen, Jiacong; Chem.Lett.; 9; (1998); 909-910
22.賴義成 編著, ”染色化學”, 修定版, (1994)
23.Bergmann et al.; J.Amer.Chem.Soc.; 74; (1952); 5979-5981
24.Coleman; Fuoss; J.Amer.Chem.Soc.; 77; (1955); 5472-5473
25.Ikegami, Yusaku; Muramatsu, Takashi; Hanaya, Kaoru; J.Amer.Chem.Soc.; EN; 111; 15; (1989); 5782-5787
26.Kung-Tu Kuo, Y. N. Shyr,; J. Chinese Chem. Soc.; 39; 3; (1981); 110-114
27.彭正中著, ”染料與染色”, 台灣中華書局印行, (1985)
28.最新化學工業概論, 465~476
29.M. Matsui; S. Kawamura; K. Sbibata and H. Muramatsu; Bull, Chem. Soc. Jpn.; 65; (1992); 71-74
30.C. S. Marvel and P. K. Porter; ”Organic Syntheses vol.1” John Wiley&Sons; Inc. (1951); 411
31.Langhals. H.; Chem. Ber.; 144; (1981); 2907-2913
32.Katritzky et al.; J. Chem. Soc. Perkin Trans.2; (1979); 690-691
33.Kosower; Klinedinst; J. Amer. Chem. Soc.; 78; (1956); 3493
34.McDonald, R. N. et al.; J. Org. Chem.; 38; (1973); 1106-1113
35.Mayr, Herbert; Ofial, Armin R.; Sauer, Juergen; Schmied, Bernhard; J. Org. Chem.; 11; (2000); 2013-2020
36.Zoltewicz; Jacobson; J. Org. Chem.; 43; (1978); 19
37.Juskowiak, Bernard; Ohba, Mitsuyoshi; Sato, Masao; Takenaka, Shigeori; Takagi, Makoto; Kondo, Hiroki; Bull.Chem.Soc.Jpn. ; 72; 2; (1999); 265-278
38.Zheng, Haipeng; Zhang, Ruifeng; Wu, Ying; Shen, Jiacong; Chem.Lett. ; 9; 1998; 909-910
39.Moon, Ki-Jeong; Shim, Hong-Ku; Lee, Kwang-Sup; Mol. Cryst. Liq. Cryst. Sci. Technol. Sect.A; 247; (1994); 91-98
40.Hartwell; Pogorelskin; J. Amer. Chem. Soc.; 72; (1950); 2040- 2042
41.Bunting, John W.; Toth, Andrea; Kanter, James P.; Can. J. Chem.; 70; 4; (1992); 1195-1203
42.Yu, L. J.; Lang, F. C.; Lee, J. S.; J. Phys. Chem.; 92; 15; (1988); 4543-4546
43.Mishra, J K; Behera, P K; Parida, S K; Mishra, B K; Indian J. Chem. Sect.B; 31; 2; (1992); 118-122