| 研究生: |
黃金鍾 Jing-Chung Huang |
|---|---|
| 論文名稱: |
氮離子佈植於氮化鎵之特性研究 |
| 指導教授: |
李清庭
Ching-Ting Lee |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 光電科學與工程學系 Department of Optics and Photonics |
| 畢業學年度: | 88 |
| 語文別: | 中文 |
| 論文頁數: | 85 |
| 中文關鍵詞: | 氮化鎵 、離子佈植 、深層能階暫態光譜 |
| 外文關鍵詞: | GaN, implantation, DLTS |
| 相關次數: | 點閱:13 下載:0 |
| 分享至: |
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本文的實驗是研究氮離子佈植於n型氮化鎵的特性研究,以不同的佈植濃度1e11、1e12、1e13、1e14、1e15cm-2之疊加,造成5e16、5e17、5e19cm-3之佈植濃度,佈植在濃度為3.3e16cm-3、1.4e17cm-3、2.8e18cm-3之n型氮化鎵試片上﹔藉以了解氮離子佈植後的氮化鎵試片特性。利用光激發螢光光譜(photoluminescence)的量測顯示,氮離子之佈植不會增進氮化鎵之發光機制﹔由拉曼(Raman) 量測顯示,在離子佈植濃度超過5x1017cm-3時,佈植之表面才會對於拉曼光譜產生影響,藉由A1(LO)模之變化發現,氮離子佈植後在熱處理之後會填補與A1(LO)相關之缺陷。
在電性方面,由蕭特基二極體之內阻計算可得在離子佈植之後電阻明顯的隨佈植濃度上升而上升,在5e19cm-3之佈植量可造成1e10之高電阻,而且在750oC有熱穩定性。由電容-電壓(C-V)量測結果顯示,在低濃度氮離子佈植至低濃度之試片上可以在表面增加電子的濃度,經由DLTS之量測結果,發現是產生高濃度氮的空缺(VN)所導致。而在高濃度之佈植,不同濃度試片會在750oC 30分鐘的加熱後在拉曼光譜中360cm-1位置會有一種新振動模式產生,經由DLTS之分析結果我們認為是與氮化鎵結構相關之缺陷,其能階位置在導電帶以下0.465eV,缺陷截面積3.5e-17cm2。
[1] S. J. Pearton, C. B. Vartuli, J. C. Zolper, C. Yuan, R.
A. Stall, ”Ion implantation doping and isolation of
B. GaN”, Appl. Phys. Lett. 67, 1435, 1995.
[2] S. C. Binari, H. B. Dietrich, G. Kelner, L. B. Rowland,
K. Doverspike, D. K. Wickenden, ”H, He, and N implant isolation of n-type GaN”, J. Appl. Phys. 78, 3008, 1995.
[3] D. Haase, M. Schmid, W. Kurner, A. Dornen, V. Harle, F.
Scholz, M. Burkard, H. Schweizer, “Deep-level defects
and n-type-carrier concentration in nitrogen
implanted GaN”, Appl. Phys. Lett. 69, 2525, 1996.
[4] Dimity Kirillov, Heon lee, and James S. Harris,
Jr., ”Raman scattering study of GaN films”, J. Appl.
Phys. 80, 4058, 1996.
[5] T Azuhata, T Sota, K Suzuki and S Nakamura, ”Polarized
Raman spectra in GaN”, Letter to Edit, IOP Publishing
Lid, L129, 1995.
[6] 曾建峰,‘有機金屬氣象磊晶法低溫砷化鎵的變溫霍爾量測
及深層能階暫態能譜量測 “,交通大學電子物理所,碩士
論文。
[7] Jorg Neugebauer, Chris G. Van de Walle, “Atomic geometry
and electronic structure of native defects in GaN”,
Physical Review B50, 8067, 1994.
[8] Z. Yang, L. K. Li, J. Alperin, and W.I. Wang, ”Nitrogen
Vacancy as the Donor: Experimental Evidence in the
Ammonia-Assisted Molecular Beam Epitaxy of GaN”, J.
Electrochem. Soc. 144, 3474, 1997.
[9] I. Gorczyca, N. E. Christensen, E. L. Peltzer Y Blanca,
and C. O. Rodriguez, “Optical phonon modes in GaN and
AlN”, Phys. Rev B51, 11936, 1995.
[10] W. Limmer, W. Ritter, and R. Sauer, “Raman scattering
in ion-implanted GaN”, Appl. Phys. Lett. 72, 1998.
[11] T. Kozawa, T. Kachi, H. Kano, and H. Nagase, “Thermal
stress in GaN epitaxial layers grown on sapphire
substrates”, J. Appl. Phys. 77, 4389, 1995.
[12] In-Hwan Lee and In-Hoon Choi, “Stress relaxation in
Si-doped GaN studied by Raman spectroscopy”, J. Appl.
Phys. Vol. 83, 5787, 1998.
[13] T. Kozawa, T. Kachi, H. Kano, Y. Taga, and M. Hashimoto,
“Raman scattering from LO phonon-plasmon coupled modes
in gallium nitride”, J. Appl. Phys. 75, 1098, 1994.
[14] 盧建志,”矽摻雜氮化鎵薄膜之特性研究”,交通大學電子物
理所,碩士論文,民國八十八年。
[15] T.L Tansley and R.J. Egan, “Point-defect energies in the
nitrides of aluminum, gallium, and indium”, Phys. Rev
B45, 10942,1992.
[16] D.W. Jekins and J. D. Dow “Electronic structures and
doping of InN, InxGa1-xN, and InxAl1-xN”, Phys. Rev. B39,
3317,1989.
[17] W. Gotz and N. M. Johnson, A. Amano and I. Akasaki, ”Deep
defects in n-type GaN”, Appl. Phys. Lett. 65, 463,1994.
[18] P. Hacke, T. Detchoprohm, K. Hirmatsu, and N. Sawaki,
K. Tadatomo and K. Miyake, ”Analysis of deep levels in
n-type GaN by transient capacitance methods”, J. Appl.
Phys. 76, 304, 1994.
[19] W. I. Lee and T. C. Huang, J. D. Guo and M. S.
Feng, ”Effects of colum Ⅲ alkyl sources on deep levels
in GaN grown by organometallic vapor phase epitaxy”,
Appl. Phys. Lett 67, 1721, 1995.
[20] P. Hacke, A. Maekawa, N. Koide, K. Hiramatsu, and N.
Sawaki, “Characterization of the shallow and Deep
Levels in Si Doped GaN Grown by Metal-Organic Vapor
Phase Epitaxy”, Jpn. J. Appl. Phys. 33, 6443, 1994.
[21] Jorg Neugebauer, Chris. G. Van de Walle, ”Gallium
vacancies and the yellow luminescence in GaN”, Appl.
Phys. Lett. 69, 503, 1996.
[22] Eric Silkowski, Gernoi S. Pomrenke, Yung Kee Yeo and
Robert L. Hengehold, “Optical Activation of Ion
Implanted and Annealed GaN”, Physica Scripta. Vol.
T69, 1997.