本論文討論Rb-Co-Fe相、K-Ni-Cr相、與核殼結構的類普魯士藍(PBA)的磁性現象，Rb-Co-Fe相兩個樣品分別在7與8 K觀察到磁的相轉變，而K-Ni-Cr相有兩個磁的相轉變分別在72與68 K時產生。 核殼結構Rb-Co-Fe@ K-Ni-Cr則有三個磁相變變化分別72、68與5 K ，而核Rb-Co-Fe相的磁矩是比較弱的，而且磁矩方向是與殼K-Ni-Cr相是相反的。
核殼結構Rb-Co-Fe@ K-Ni-Cr奈米粒子進行了中子實驗，中子散射結果顯示核殼結構Rb-Co-Fe@ K-Ni-Cr奈米粒子具有鐵磁性，Rb-Co-Fe相是光敏材料，而照光後發現K-Ni-Cr相與Rb-Co-Fe相磁性增加，我們認為Rb-Co-Fe相跟K-N-Cr相做成核殼結構的奈米粒子讓K-N-Cr相也變成光敏材料。

In this thesis, we will discuss magnetic phenomena of Prussian Blue Analogue with Rb-Co-Fe phase, K-Ni-Cr phase and core/shell PBA heterostructure. Rb-Co-Fe phase in the two samples were 7 and 8 K magnetic phase transition was observed. Two separated magnetic phase transition at 72 and 68 K are found in K-Ni-Cr phase. Three separated magnetic phase transition at 72、68 and 5 K are found in core/shell Rb-Co-Fe@ K-Ni-Cr heterostructure. The development of weak magnetic moments in the core(Rb-Co-Fe phase). Apparently, the moments in the core and on the shell (K-Ni-Cr phase) point in the opposite directions.
The observation of ferromagnetic of the Rb-Co-Fe@ K-Ni-Cr nanoparticle are studied through the ac magnetic susceptibility and neutron diffraction measurements, Although the CoFe material is a well established photomagnet, the magnetic of Rb-Co-Fe phase and KN-Cr phase are both increased, we believe that Rb-Co-Fe phase with KN-Cr phase formed core-shell structure nanoparticles make K-Ni-Cr phase has become photosensitive material.

第一章
[1]. Bartoll, Ｊ.; 9th International Conference on NDT of Art, Jerusalem Israel, (2008).
[2]. Wiberg, E.; Wiberg , N.; Inorganic chemistry, Academic Press,( 2001)
[3]. Pajerowski, D. M.; Yamamoto, T. and Einaga, Y.; Inorg. Chem., 2012, 51, 3648-3655.
[4]. Sato, O.; Einaga, Y. ; Fujishima, A. and Hashimoto, K.; Inor. Chem. 38, 20,(1999)
[5]. Chapman, Karena W.; Chupas, P. J. and Kepert, C. J.; J. Am. Chem. Soc. 128, 21, (2006)
[6]. Bleuzen, A.; Lomenech, C.; Escax, V.; Villain, F.; Varret, F.; Cartier dit Moulin, C. and Verdaguer, M.; J. Am. Chem. Soc. 122,(2000)
[7]. Margadonna, S.; Prassides, K. and Fitch, A. N.; J. AM. CHEM. SOC., 126, (2004)
[8]. O. Sato, T. Iyoda, A. Fujishima, K. Hashimoto, Science 272 (1996)
[9]. Knowles, E. S.; Li, C. H.; Dumont, M. F.; Pepraha, M. K.; Andrus, M. J.; Talhamb, D. R.; Meisel, M. W.; Polyhedron. 66, (2013)
第二章
[1] C. Kittel, Introduction to Solid State Physics 8th edition, ISBN 978-0-471-41526-8
[2] P. B. Barna, and M. Adamik, "Fundamental Structure Forming Phenomena of Polycrystalline Films and The Structure Zone Models", Thin Solid Films, 317 ,27-33(1998)
[3] S. Chikazumi, S. H. Charap, Physics of Magnetism, ISBN 978-0-882-75662-2
[4] N. W. Ashcroft, N. D. Mermin, Solid State Physics, ISBN 978-0-03-083993-1(1976)
第三章
[1]. Matthieu F. Dumont, Elisabeth S. Knowles, Amandine Guiet, Daniel M. Pajerowski, Ariel Gomez,Stefan W. Kycia, Mark W. Meisel, and Daniel R. Talham, Inorg. Chem. 50, 4295–4300,(2011)
[2]. A.C. Larson and R.B. Von Dreele, General Structure Analysis System (GSAS), Los Alamos National Labaratory Report LAUR 86-748(2004)
[3]. 許樹恩、吳泰伯，X 光繞射原理與材料結構分析，中國材料科學 學會發行(1993)
[4]. C. Kittel, Introduction to Solid State Physics 8th edition, ISBN 978-0-471-41526-8
[5]. N. W. Ashcroft, N. D. Mermin, Solid State Physics, ISBN 978-0-03-083993-1(1976)
第四章
[1]. Matthieu F. Dumont, Elisabeth S. Knowles, Amandine Guiet, Daniel M. Pajerowski, Ariel Gomez,Stefan W. Kycia, Mark W. Meisel, and Daniel R. Talham, Inorg. Chem. 50, 4295–4300,(2011)
[2]. A.C. Larson and R.B. Von Dreele, General Structure Analysis System (GSAS), Los Alamos National Labaratory Report LAUR 86-748(2004)
[3]. 許樹恩、吳泰伯，X 光繞射原理與材料結構分析，中國材料科學 學會發行(1993)
[4]. C. Kittel, Introduction to Solid State Physics 8th edition, ISBN 978-0-471-41526-8
[5]. N. W. Ashcroft, N. D. Mermin, Solid State Physics, ISBN 978-0-03-083993-1(1976)
第五章
[1]. Matthieu F. Dumont, Elisabeth S. Knowles, Amandine Guiet, Daniel M. Pajerowski, Ariel Gomez,Stefan W. Kycia, Mark W. Meisel, and Daniel R. Talham, Inorg. Chem. 50, 4295–4300,(2011)
[2]. A.C. Larson and R.B. Von Dreele, General Structure Analysis System (GSAS), Los Alamos National Labaratory Report LAUR 86-748(2004)
[3]. 許樹恩、吳泰伯，X 光繞射原理與材料結構分析，中國材料科學 學會發行(1993)
[4]. C. Kittel, Introduction to Solid State Physics 8th edition, ISBN 978-0-471-41526-8
[5]. N. W. Ashcroft, N. D. Mermin, Solid State Physics, ISBN 978-0-03-083993-1(1976)
[6]. S. Mørup, EPL 77, 27003 (2007.)
[7]. G. E. Bacon, Neutron Diffraction, 3th Ed., (Clarendon press, Oxford, 1975)