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研究生: 蕭博元
Po-Yen Xiao
論文名稱: 丙烯酸系粉體聚合物與強塑劑應用於水泥砂漿之反應影響研究
指導教授: 李釗
Chau Lee
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 土木工程學系
Department of Civil Engineering
畢業學年度: 95
語文別: 中文
論文頁數: 100
中文關鍵詞: 強塑劑強度流度粉體聚合物
外文關鍵詞: flow, powdered polymer, superplasticizer, strength
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  • 土木工程技術日新月異,在材料方面,從礦物摻料到化學摻料均可應用於水泥基材以求改善產品性質,但除了不同的摻料對產品的性質有不同的影響外,混合使用時常會顧此失彼,所以摻料的選擇、使用方法與用量,將是應用上的重要課題。
    本研究在符合一般施工條件與考量混凝土工作性不佳的前提下,尋找適當粉體型態的聚合物與促進劑,與水泥混合製成粉體複合水泥,並進而探討其在新拌與硬固漿體的工程性質。另外也添加了數種強塑劑,藉以觀察其對聚合物效用的影響。
    新拌漿體的試驗結果顯示粉體聚合物與促進劑的摻用具有30~60分鐘緩凝效果,同時也增加了新拌漿體的流動性,尤其是長時間(90~120分鐘)的流動性增加5~10%。其次,在部分實驗條件下,聚合物對硬固砂漿的抗彎與抗壓強度,有提升的效果;再者,亦有效減少吸水率與吸水膨脹率。另外,為了控制相同起始流度而摻入的強塑劑,種類與用量的不同會影響粉體聚合物對水泥漿體的效用。


    The technique of civil engineering is being continuously updated. The usage of mineral or chemical admixtures in cement can both improve the cement properties. Besides taking into consideration the different effects of different admixtures on cement properties, the selection, application method and quantity of admixtures are also very important issues to be discussed since all factors can hardly be taken care simultaneously during mixture.
    Under the general requirements of practical construction and considering the unsatisfactory workability of concrete, we seek by this research a suitable powdered polymer and promoter to be mixed with cement for forming a powdered polymer-modified cement (powdered PMC), and we further look into the engineering properties of powdered PMC on fresh-mixed and hardened mortar. We have also added several superplasticizer for observing their effects on polymer.
    The test results of setting time on fresh-mixed mortar show that the application of powdered polymer and promoter has a 30 to 60 minute retarding effect, and at the same time it increases the flowability of fresh-mixed mortar, especially the long-period flowability (90 ~ 120 minutes) which is by 5 ~ 10%. Also, under some testing conditions, the polymer improves the flexural and compressive strength of hardened mortar. Furthermore, the absorption and sorptive expansion ratio can be improved when the polymer be added. As for the usage of superplasticizer for the control of initial flow, the different types and quantities of superplasticizer have different effect of powdered polymer on cement mortar.

    摘 要 II Abstract III 誌 謝 IV 目 錄 VI 圖目錄 VIII 表目錄 VIII 第一章 緒 論 1 1.1 研究動機 1 1.2 研究方法與目的 2 第二章 文獻回顧 3 2.1 聚合物水泥複合材料發展史簡述 3 2.2 複合機構的形成與模型 4 2.3 聚合物水泥複合材料種類 5 2.4 新拌混凝土的性質 8 2.4.1 水化速率 9 2.4.2 凝結時間 9 2.4.3 工作性 10 2.4.4 拌合水量 12 2.5 硬固混凝土的性質 12 2.5.1 強度 12 2.5.2 體積穩定性 15 第三章 試驗材料及研究方法 16 3.1 試驗材料 16 3.2 試驗設備 18 3.3 試驗規劃 24 3.3.1 研究範圍 24 3.3.2 試驗內容 24 3.4 試驗方法 26 第四章 試驗結果與分析 36 4.1 粉體篩選 36 4.2 新拌水泥砂漿 38 4.2.1 凝結時間 38 4.2.2 流度值 40 4.3 硬固水泥砂漿 46 4.3.1 強度 46 4.3.2 體積變化 86 4.3.3 吸水率 91 第五章 結論與建議 94 5.1 結論 94 5.2 建議 95 參考文獻 97

    1.Belie, N. D., and Monteny, J. (1998).”Resistance of concrete containing styrol acrylic acid ester latex to acids occurring on floors for livestock housing.” Cement and Concrete Research, 28(11), 1621–1628.
    2.Bonapasta, A. A. Buda, F. Colombet, P. (2000) .” Cross-linking of poly(vinyl alcohol) chains by Al ions in macro-defect-free cements: a theoretical study.” Chem. Mater., 12, 738-743.
    3.Bonapasta, A. A. Buda, F. Colombet, P., and Guerrini, G. (2002) .” Cross-linking of poly(vinyl alcohol) chains by Ca ions in macro-defect-free cements: a theoretical study.” Chem. Mater., 1016-1022.
    4.Chen, P. W., and Chung, D. D. L. (1995).“Effect of polymer addition on the thermal stability and thermal expansion of cement.” Cement and Concrete Research, 25(3), 465-469.
    5.Czarnecki, L. Garbacz, A., and Kurach, J. (2001).”On the characterization of polymer concrete fracture surface.” Cement and Concrete Research, 23, 399-409.
    6.Delucchi, M., and Cerisola, G. (2001).”Influence of organic coatings on the stability of macrodefect-free cements exposed to water.” Construction and Building Materials, 15, 351-359.
    7.Fattah, H. A., and Hawary, M. M. E. (1999).”Flexural behavior of polymer concrete.” Construction and Building Materials, 12, 253-262.
    8.Fichet, R. O. Gauthier, C. Clamen, G., and Boch, P. (1998).“Microstructural aspects in a polymer-modified cement.” Cement and Concrete Research, 28(12), 1687-1693.
    9.Hall, C. (1981).”Water movement in porous building materials - IV. the. initial surface absorption and the sorptivity.” Building and Enviornment, 16(3), 201-207.
    10.Hall, C. (1989).” Water sorptivity of mortars and concrete: a review.” Magazine of Concrete Research, 41(147), 51-61.
    11.Isci, S. Gunister, E. Ece, O. I., and Gungor, N. (2004).” The modification of rheologic properties of clays with PVA effect.” Materials Letters, 58, 1975-1978.
    12.Jensen, O. M., and Hansen, P. F. (2001).”Water-entrained cement-based materials I. Principles and theoretical background.” Cement and Concrete Research, 31, 647-654.
    13.Khayat, K. H. (1998).”Viscosity-enhancing admixtures for cement-based materials—an overview.” Cement and Concrete Composites, 20, 171-188.
    14.Kim, J. H. Robertson, R. E., and Naaman, A. E. (1999).”Structure and properties of poly(vinyl alcohol)-modified mortar and concrete.” Cement and Concrete Research, 29, 407-415.
    15.Kim, J. H., and Robertson, R. E. (1997).”Prevention of air void formation in polymer-modified cement mortar by pre-wetting.” Cement and Concrete Research, 27(2), 171-176.
    16.Kim, J. H., and Robertson, R. E. (1998).”Effects of polyvinyl alcohol on aggregate-paste bond strength and the interfacial transition zone.” Advn Cem Bas Mat, 66-76.
    17.Kong, H. J. Bike, S. G., and Li, V. C. (2003).”Constitutive rheological control to develop a self-consolidating engineered cementitious composite reinforced with hydrophilic poly(vinyl alcohol) fibers.” Cement & Concrete Composites, 25, 333–341.
    18.Kong, H. J. Bike, S. G., and Li, V. C. (2003).”Development of a self-consolidating engineered cementitious composite employing electrosteric dispersion/stabilization.” Cement & Concrete Composites, 25, 301–309.
    19.Maggio, R. D. Volpe, C. D. Gialanella, S., and Guerrini, G. (2001).” Macrodefect-free cements: the effect of chemical composition on microstructure.” Chem. Mater., 13, 4335-4341.
    20.Mehta, P. K., and Monteiro, P. J. M. (1993). Concrete. 2nd edtion. McGraw-Hill, New York.
    21.Mindess, S. Young, J. F., and Darwin, D. (2003). Concrete. 2nd edtion. Upper Saddle River, Prentice Hall, New York.
    22.Mishra, P. C. Singh, V. K. Narang, K. K., and Singh, N.K. (2003).”Effect of carboxymethyl-cellulose on the properties of cement.” Materials and Engineering, A357, 13–19.
    23.Ohama, Y. (1998).”Polymer-based admixtures.” Cement and Concrete Composites, 20, 189-212.
    24.Ohama, Y. (1998).” Recent progress in concrete-polymer composites.” Advn Cem Bas Mat., 31-40.
    25.Ramireza, S. M. Zamaradb, A. Thompsonb, G. E., and Moorec, B. (2002).” Organic and inorganic concrete under SO2 pollutant exposure.” Building and Environment, 37, 933 – 937.
    26.Rastoul, K. Damme, H. V. Lafuma, F. Lequeux, F. Colombet, P. Mansoutre, S., and Pasquier, M. (2003).“A rheological study of associating polymer-particle interaction in tricalcium silicate pastes.“ Polym Int., 52, 633-637.
    27.Rodrigues, F. A. and Joekes, I. (1998).” Macro-defect free cements- a new approach.” Cement and Concrete Research, 28(6), 877-885.
    28.Saija, L. M. (1995).”Waterproofing of portland cement mortars with a specially designed polyacrylic latex.” Cement and Concrete Research, 25(3), 503–509.
    29.Sakai, E., and Sugita, J. (1995).”Composite mechanism of polymer modified cement.” Cement and Concrete Research, 25(1), 127-135.
    30.Santos, L. A. D. Oliveira, L. C. D. Rigo, E. C. S. Carrodeguas, R. G. Boschi, A. O., and Arruda, A. C. F. D. (1999).”Influence of polymeric additives on the mechanical properties of α-Tricalcium phosphate cement.” Elsevier Science Inc., 25(2), 99-102.
    31.Santos, R.S. Rodrigues, F. A. Segre, N., and Joekes, I. (1999).”Macro-defect free cements Influence of poly(vinyl alcohol), cement type, and silica fume.” Cement and Concrete Research, 29, 747–751.
    32.Schulz, J. (1999).”Influence of water-cement ratio and cement content on the properties of polymer-modified mortars.” Cement and Concrete Research, 29, 909-915.
    33.Schulze, J., and Killermann, O. (2001).”Long-term performance of redispersible powders in mortars.” Cement and Concrete Research, 31, 357–362.
    34.Silva, D. A. John, V. M. Ribeiro, J. L. D. Roman, H. R. (2001).“Pore size distribution of hydrated cement pastes modified with polymers.” Cement and Concrete Research, 31, 1177-1184.
    35.Su, Z. Sujata, K. Bijen, J. M. M. Jennings, H. M., and Fraaij, A. L. A. (1996).”The evolution of the microstructure in styrene acrylate poly.” Advn Cem Bas Mat., 3, 87-93.
    36.Vipulanandan, C., and Liu, J. (2002).” Film model for coated cement concret.” Cement and Concrete Research, 32, 1931-1936.
    37.Wen, S., and Chung, D.D.L. (2003).” Pyroelectric behavior of cement-based materials.” Cement and Concrete Research, 33, 1675-1679.
    38.Yahya, G. O. Ali, S. K. A., and Hamad, E. Z. (1996).” Surface and interfacial activities of hydrophobically modified poly(vinyl alcohol)(PVA).” Polymer, 37(7), 1183-1188.
    39.Zhihong, W. Yucuia, H., and Yuan, H. (2003).”Research on increasing effect of solution polymerization for cement-based composite.” Cement and Concrete Research, 33, 1655–1658.

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