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研究生: 邱沛儒
CHIU, PEI-JU
論文名稱: Chitosan 應用於窄帶濾光片之研究
指導教授: 李正中
Cheng-Chung Lee
口試委員:
學位類別: 碩士
Master
系所名稱: 理學院 - 照明與顯示科技研究所
Graduate Institute of Lighting and Display Science
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 57
中文關鍵詞: 窄帶濾光片幾丁聚醣
外文關鍵詞: narrow-band pass filter, chitosan
相關次數: 點閱:21下載:0
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  •   本論文為研究利用生物環保材料chitosan製成窄帶濾光片,首先利用Macleod軟體找出此種材料之n、k值,進而設計在可見光波段之窄帶。實驗中利用磁控濺鍍方法鍍製第一層Ag後,接著在Ag層上塗佈chitosan,利用不同轉速控制chitosan層的厚度,接著再鍍上一層Ag,樣品完成後即進行光譜量測並與原先的設計進行比較與分析。
      由於chitosan有著良好的吸濕性,藉由放置在不同的濕度環境下,量測光譜後觀察其波峰偏移的情形,再利用Macleod軟體推算樣品的折射率變化及厚度變化,最後再計算靈敏度。


      In this research, we design and make a narrow-band pass filter by using chitosan, an environment-friendly material as a spacer. Macleod software is used to find out the refractive index and extinction coefficient of the material, and then design narrow-band pass filters in visible light band. First, Ag film was deposited on a substrate by magnetron sputtering. Second, chitosan was spin-coated on the Ag layer. Last, Ag film was deposited on the chitosan layer. The thickness of the chitosan layer was controlled by different rotational speed. After the sample was completed, we compared with the original design and do the analysis.
    Chitosan is hygroscopic, so we placing the sample in different humidity environment and measuring the redshift. And then we calculate the changes of refractive index, thickness and sensitivity of chitosan.

    目錄 第一章 緒論 1 1-1 研究背景 1 1-2 研究動機 2 第二章 材料與理論介紹 3 2-1 幾丁質與幾丁聚醣 3 2-2 光學薄膜理論 4 2-2-1 Maxwell電磁波方程式 5 2-2-2 單介面之反射與透射 7 2-2-3 單層膜與多層膜 8 2-3 窄帶濾光片(narrow-band pass filter) 11 2-4 薄膜堆積密度 13 第三章 實驗方法與設備 14 3-1 實驗儀器 14 3-1-1 磁控濺鍍機 14 3-2 量測儀器 15 3-2-1 紫外光/可見光光譜儀 15 3-2-2 Alpha-step 17 3-2-3 AFM 17 3-3 實驗流程 18 3-3-1 調配溶液 18 3-3-2 鍍製樣品 20 3-3-3 量測光譜 21 第四章 實驗分析與結果 22 4-1 粗糙度量測 22 4-2 腐蝕測試 25 4-3 Chitosan膜特性量測 27 4-3-1 Chitosan膜之n, k 27 4-3-2 薄膜堆積密度 28 4-4 設計與製作窄帶濾光片 29 4-5 擬和實驗數據 30 4-6 濕度及光譜圖變化 32 4-7 靈敏度分析 37 4-8 回復性測試 38 第五章 結論與未來工作 40 參考文獻 41

    1. Irimia-Vladu, Mihai, Niyazi Serdar Sariciftci, and Siegfried Bauer. "Exotic materials for bio-organic electronics." Journal of Materials Chemistry 21.5 (2011); 1350-1361.
    2. Rinaudo, Marguerite. "Chitin and chitosan: properties and applications." Progress in polymer science 31.7 (2006); 603-632.
    3. Pillai, C. K. S., Willi Paul, and Chandra P. Sharma. "Chitin and chitosan polymers: Chemistry, solubility and fiber formation." Progress in polymer science 34.7 (2009); 641-678.
    4. Stevens, Eugene S. Green plastics: an introduction to the new science of biodegradable plastics. Princeton University Press, 2002.
    5. Somashekar, D., and Richard Joseph. "Chitosanases—properties and applications: a review." Bioresource technology 55.1 (1996); 35-45.
    6. Pham, Gia Dien, et al. "Some biomedical applications of chitosan-based hybrid nanomaterials." Advances in Natural Sciences: Nanoscience and Nanotechnology 2.4 (2011); 045004.
    7. Venkatesan, Jayachandran, and Se-Kwon Kim. "Chitosan composites for bone tissue engineering—An overview." Marine drugs 8.8 (2010); 2252-2266.
    8. Mi, Fwu-Long, et al. "Fabrication and characterization of a sponge-like asymmetric chitosan membrane as a wound dressing." Biomaterials 22.2 (2001); 165-173.
    9. Dutta, P. K., et al. "Perspectives for chitosan based antimicrobial films in food applications." Food chemistry 114.4 (2009); 1173-1182.
    10. Avila-Sosa, Raúl, et al. "Antifungal activity by vapor contact of essential oils added to amaranth, chitosan, or starch edible films." International journal of food microbiology 153.1 (2012); 66-72.
    11. Anchisi, C., M. C. Meloni, and A. M. Maccioni. "Chitosan beads loaded with essential oils in cosmetic formulations." Journal of cosmetic science 57.3 (2005); 205-214.
    12. Bautista-Baños, Silvia, et al. "Chitosan as a potential natural compound to control pre and postharvest diseases of horticultural commodities." Crop Protection 25.2 (2006); 108-118.
    13. Rhazi, M., et al. "Influence of the nature of the metal ions on the complexation with chitosan.: Application to the treatment of liquid waste." European Polymer Journal 38.8 (2002); 1523-1530.
    14. Flieger, M., et al. "Biodegradable plastics from renewable sources." Folia microbiologica 48.1 (2003); 27-44.
    15. Ormrod, Douglas J., Connor C. Holmes, and Thomas E. Miller. "Dietary chitosan inhibits hypercholesterolaemia and atherogenesis in the apolipoprotein E-deficient mouse model of atherosclerosis." Atherosclerosis 138.2 (1998); 329-334.
    16. Gallaher, Daniel D., et al. "A glucomannan and chitosan fiber supplement decreases plasma cholesterol and increases cholesterol excretion in overweight normocholesterolemic humans." Journal of the American College of Nutrition 21.5 (2002); 428-433.
    17. 李正中,“薄膜光學與鍍技術”,第七版,藝軒圖書出社,台北, (2009).
    18. Ogura, S. Some features of the behaviour of optical thin films. Diss. Ph. D. Thesis, Newcastle upon Tyne Polytechnic, England, 1975.
    19. Zhang, Xueqin, et al. "The effect of the prefrozen process on properties of a chitosan/hydroxyapatite/poly (methyl methacrylate) composite prepared by freeze drying method used for bone tissue engineering." RSC Advances 5.97 (2015); 79679-79686.
    20. Tollerud, Jonathan. Scatter loss and surface roughness of hafnium oxide thin films. Diss. Colorado State University. Libraries, 2007.
    21. Chen, Li Han, et al. "Chitosan based fiber-optic Fabry–Perot humidity sensor." Sensors and Actuators B: Chemical 169 (2012); 167-172.
    22. Sergeev, A., and S. Voznesenskiy. "Specific features of chitosan waveguides optical response formation to changes in the values of relative humidity." Optical Materials 43 (2015); 33-35.
    23. Wiles, J. L., et al. "Water vapor transmission rates and sorption behavior of chitosan films." Journal of Food Science 65.7 (2000); 1175-1179.
    24. Sergeev, A. A., et al. "Investigation of humidity influence upon waveguide features of chitosan thin films." Physics Procedia 23 (2012); 115-118.
    25. Wu, Jianmin, and Michael J. Sailor. "Chitosan Hydrogel‐Capped Porous SiO2 as a pH Responsive Nano‐Valve for Triggered Release of Insulin." Advanced functional materials 19.5 (2009); 733-741.

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