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研究生：	Hendriquita Karonsih Widyapsari Hendriquita Karonsih Widyapsari
論文名稱：	The Preliminary Study on Rheological Behavior of Polymer Modified Warm Mix Asphalt in Taiwan
指導教授：	Chen Shihuang Shih-Huang Chen
口試委員:
學位類別：	碩士 Master
系所名稱：	工學院 - 土木工程學系 Department of Civil Engineering
論文出版年：	2025
畢業學年度：	114
語文別：	英文
論文頁數：	122
中文關鍵詞：	溫拌瀝青、聚合物、車轍和疲勞、溫拌瀝青、聚合物、車轍和疲勞
外文關鍵詞：	Warm Mix Asphalt, polymer, rutting and fatigue., Warm Mix Asphalt, polymer, rutting and fatigue
相關次數：	點閱：17 下載：0
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查詢本校圖書館目錄查詢臺灣博碩士論文知識加值系統勘誤回報

淨零排放是一個被廣泛討論的話題，溫拌瀝青（WMA）預計也將在臺灣路面中得到應用。臺
灣氣候多雨、夏季炎熱、交通繁忙，享情況為全臺，帶來了巨大的挑戰。在這種情況下，車轍
和鱷魚裂縫是高速公路常見問題。而在瀝青中添加聚合物是解決這些問題的標準方法。許多路
面工程關注的是溫拌瀝青混凝土是否可以與多種聚合物混合使用。本研究旨在評估不同聚合物
在臺灣溫拌瀝青混凝土中的性能。研究使用了五種添加劑，包括三種聚合物苯乙烯-丁二烯-苯
乙烯（SBS）、苯乙烯-乙烯-丁烯-苯乙烯（SEBS）與苯乙烯-異戊二烯-苯乙烯（SIS）。此外，
還使用了兩種溫拌瀝青混凝土添加劑：蠟S和化學添加劑Z。所用基質瀝青為AC-20，聚合物
添加量為 3-5%、蠟 S 添加量為 3%、化學品 Z添加量為 0.07%。本研究的另一個目標為確定
AC-20、聚合物和溫拌瀝青（WMA）添加劑的最佳組合。將對黏合劑進行物理和流變學測試，
以評估上述所有組合。研究結果如下：可知所有聚合物改質瀝青（PMB）皆能提升基質瀝青
AC-20 與溫拌瀝青（WMA）混合料的性能，且性能通常會隨聚合物摻量的增加而改變。流變
學測試顯示SBS C 具有最佳綜合性能、而化學添加劑 Z 的改善幅度相對有限。與 AC-20 加蠟
S 相比、所有聚合物與 AC-20 及蠟 S 的組合均可使抗車轍性能提升約 21%，其中 4% SEBS 的
組合更可提升至 24%。在抗疲勞測試中，4% SBS C 與 AC-20 加蠟 S 的組合能使疲勞壽命提升
約四倍，顯示所有聚合物皆有助於提高承載能力並增強瀝青的抗疲勞特性。然而，儘管 SBS C
加蠟 S 兼具良好的抗車轍與抗疲勞性能，其黏結強度卻有所下降，表示黏結料與骨材界面的黏
附力減弱，可能導致更易受潮；化學添加劑 Z 則呈現相反的趨勢，在黏結性能方面表現較佳。
綜合性能評估顯示，4% SBS C 加蠟 S 在臺灣高溫潮濕氣候與中、重交通乘載力下具最均衡表
現，但黏結強度仍是確保裂縫產生後抗水侵害能力的重要指標。因此，添加聚合物以提升溫拌
瀝青的抗車轍與抗疲勞能力具有明顯可行性與研究價值，值得進一步探討。

Net-zero emissions is a widely discussed topic, and warm-mix asphalt (WMA) is also expected
to be adopted in Taiwanese pavements. Taiwan's climate is typically rainy, with hot summers,
and heavy traffic presents a significant challenge across the island. Given these conditions,
rutting and fatigue are common issues on highways, and adding polymers to bitumen is a
standard method to address them. Many pavement engineers are concerned about whether
WMA can be used with various polymers together. The objective of this study is to evaluate the
performance of WMA with different polymers in Taiwan. Five polymers were used, including
three types of Styrene-Butadiene-Styrene (SBS), Styrene-Ethylene-Butylene-Styrene (SEBS),
and Styrene-Isoprene-Styrene (SIS). Additionally, two WMA additives, wax S and chemical Z,
were applied. The base asphalt used is AC-20; polymers were added at 3-5%, wax S at 3%, and
chemical Z at 0.07%. Another goal of the study is to identify the best combinations of AC-20,
polymers, and WMA additives. The physical and rheological tests of the binder will assess all
combinations. The findings show all PMBs improved both base and WMA binder properties,
with performance generally increasing with polymer dosage. Rheological results identified SBS
C as the best overall performance, while chemical Z contributed minimal improvement. PMBs
increased rutting resistance by up to 21% relative to AC-20 + wax S. Fatigue resistance under
standard moderate traffic improved up to fourfold with 4% SBS C + wax S. However, although
SBS + wax S improved rutting and fatigue, it reduced tenacity, indicating weaker binder
aggregate bonding and potential moisture susceptibility, whereas the chemical additive showed
the opposite trend. Overall, 4% SBS C + wax S provided the most balanced performance for
Taiwan’s climatic and traffic conditions, though tenacity remains essential for ensuring post
cracking moisture durability. Thus, it is feasible to add polymers to improve the rutting
resistance and fatigue performance of WMA, and further research is warranted.

Contents 
 
摘要 ............................................................................................................................................ ii 
Abstract ...................................................................................................................................... iii 
Acknowledgement ..................................................................................................................... iv 
Contents ...................................................................................................................................... v 
List of Figure ........................................................................................................................... viii 
List of Table ................................................................................................................................ x 
List of Abbreviations ................................................................................................................. xi 
List of Symbols ......................................................................................................................... xii 
I Introduction .............................................................................................................................. 1 
1 Research Backgrounds ............................................................................................... 1 
2 Research Objectives ................................................................................................... 2 
3 Research Scope ........................................................................................................... 3 
4 Study Flowchart .......................................................................................................... 3 
II Literature Review.................................................................................................................... 7 
1 Warm Mix Asphalt ...................................................................................................... 7 
1.1 Chemical Additive .............................................................................................. 8 
1.2 Wax Additives ..................................................................................................... 8 
2 Warm Mix Asphalt Binder Properties ........................................................................ 9 
3 Polymer Modified Asphalt ....................................................................................... 10 
3.1 Styrene Butadiene Styrene (SBS) ..................................................................... 11 
3.2 Styrene–Ethylene– Butylene–Styrene (SEBS) ................................................. 13 
3.3 Styrene-Isoprene-Styrene (SIS) ........................................................................ 14 
3.4 SBS Modified Asphalt ...................................................................................... 15 
3.5 SEBS Modified Asphalt ................................................................................... 19 
3.6 SIS Modified Asphalt ....................................................................................... 20 
4 Warm Mix Modified Asphalt Binder Properties ....................................................... 21 
4.1 SBS Warm Mix Binder ..................................................................................... 21 
4.2 SEBS Warm Mix Binder .................................................................................. 23 
4.3 SIS Warm Mix Binder ...................................................................................... 24 
5 Summary of Findings ............................................................................................... 24 
III Methodology ........................................................................................................................ 27 
 
 
1 Material ..................................................................................................................... 27 
1.1 Based Asphalt and Polymer Modified Binder .................................................. 27 
1.2 Mixing Method ................................................................................................. 28 
2 Asphalt Binder Physical Test .................................................................................... 28 
2.1 Penetration ........................................................................................................ 29 
2.2 Spec. Gravity .................................................................................................... 29 
2.3 Ductility ............................................................................................................ 30 
2.4 Softening Point ................................................................................................. 31 
2.5 Toughness and Tenacity .................................................................................... 31 
2.6 Elastic Recovery ............................................................................................... 32 
2.7 Storage Test – Softening Point ......................................................................... 33 
2.8 Rotational Viscosity .......................................................................................... 33 
2.9 Capillary Viscosity ........................................................................................... 34 
3 Asphalt Binder Test Treatment ................................................................................. 35 
3.1 Short term Aging .............................................................................................. 35 
3.2 Long term Aging ............................................................................................... 35 
3.3 Storage Stability Test ........................................................................................ 36 
4 Asphalt Binder Rheological Test .............................................................................. 36 
4.1 DSR Grading .................................................................................................... 37 
4.2 Multiple Stress Creep Recovery ....................................................................... 37 
4.3 Linear Amplitude Sweep .................................................................................. 38 
IV Results and discussion ......................................................................................................... 39 
1 Basic Properties ........................................................................................................ 39 
1.1 Penetration ........................................................................................................ 39 
1.2 Specific Gravity ................................................................................................ 40 
1.3 Ductility ............................................................................................................ 42 
1.4 Softening Point ................................................................................................. 44 
1.5 Toughness and Tenacity .................................................................................... 44 
1.6 Elastic Recovery ............................................................................................... 48 
1.7 Storage Stability ............................................................................................... 49 
2 Rheological Properties .............................................................................................. 50 
2.1 Rotational Viscosity .......................................................................................... 51 
2.2 Capillary Viscosity ........................................................................................... 53 
 
 
2.3 Viscoelastic Behavior ....................................................................................... 56 
2.4 Performance Grade Unaged.............................................................................. 64 
2.5 Performance Grade Short Term Aging ............................................................. 70 
2.6 Failed Temperature ........................................................................................... 76 
2.7 Multiple Stress Creep Recovery (MSCR) ........................................................ 76 
2.8 Linear Amplitude Sweep (LAS) ....................................................................... 82 
3 Discussion ................................................................................................................. 86 
V Conclusion and Recommendation ........................................................................................ 89 
1 Conclusion ................................................................................................................ 89 
2 Recommendation ...................................................................................................... 90 
Reference .................................................................................................................................. 91 
Appendix A. Overall test results of PMB ............................................................................... 101 
Appendix B. Overall test results of PMB + wax S ................................................................. 102 
Appendix C. Overall test results of PMB + chemical Z ......................................................... 103 
Appendix D. Ranking Table of Binder Performance .............................................................. 104 
Appendix E. Rutting and Fatigue Performance ...................................................................... 104 
                                

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