探討酸/鹼高分子質子交換膜在無水狀態之研究｜國立中央大學博碩士論文系統

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研究生：	彭元軍 Yuan-Chun Peng
論文名稱：	探討酸/鹼高分子質子交換膜在無水狀態之研究 Studies of Acid/Base Polymer for Anhydrous Proton Exchange Membrane
指導教授：	諸柏仁 Peter Po-Jen Chu
口試委員:
學位類別：	碩士 Master
系所名稱：	理學院 - 化學學系 Department of Chemistry
畢業學年度：	94
語文別：	中文
論文頁數：	113
中文關鍵詞：	直接甲醇燃料電池、酸/鹼高分子複合物、質子交換膜、無水狀態
外文關鍵詞：	Acid/Base Polymer Complex, Proton Exchange Membrane (PEM), anhydrous, Direct methanol fuel cell (DMFC)
相關次數：	點閱：11 下載：0
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直接甲醇燃料電池（Direct Methanol Fuel Cell，DMFC）具備了數個符合未來替代能源需求的優勢，因此被認為是最具開發價值的燃料電池種類之一，其中，質子交換膜為整個燃料電池組中最重要的組件之一，質子交換膜的特性將影響燃料電池未來的應用。具有好的熱穩定性的薄膜可以擴大燃料電池工作的溫度範圍，隨著工作溫度的提高，燃料電池的效能也將大大地改善，但是，在高工作溫度下，無法藉著水分帶動質子導電，因此也需要不同以往的質子傳遞機制。本研究使用不同分子量的酸性高分子PAA（poly(acrylic acid)）和鹼性高分子P4VP（poly(4-vinylpyridine)）經過摻合後，利用酸、鹼官能基之間的作用力—氫鍵和離子鍵作用力，製備成酸/鹼高分子複合物質子交換膜，除了具有良好的熱穩定性外，也建構出新的質子傳遞通道，在新的通道內，酸、鹼官能基因吸引力而相互配對，少數未配對上質子的鹼官能基，可接受周圍傳遞過來的質子，並傳遞至周圍的「proton defect」，這類質子傳遞方式在通道內如同進行「zip-unzip」的行為，利用新的質子傳遞機制且同時具有熱穩性定，即可應用於高溫無水狀態下的燃料電池。

Direct Methanol Fuel Cells (DMFCs) possessing several advantage that tally with the alternative energy source demand in the future. And it is considered to one kind of the fuel cells which having the most developed values. Among them, the proton exchange membrane is one of the most important component in the whole fuel cell. The characteristics of the proton exchange membrane will influence the applications of the fuel cells in the future. If the membrane with good thermal stability, it can expand the operating temperature of the fuel cell. With the increasing of the operating temperature, the performance of the fuel cells will be improved greatly. However, it is unable to deliver the proton by water molecules under higher operating temperature, so need different proton transition mechanisms.
This research uses the acidic polymer PAA (poly(acrylic acid)) of different molecular weight combined with the basic polymer P4VP (poly(4-vinylpyridine)) and P(4VPcoS). Then the proton exchange membranes were prepared by the hydrogen bonding and ionic bonding interaction between the acidic and basic polymers. Besides having good thermal stability, there is a new proton transition channel in the membranes. Since the interaction between the acid and base, the acidic and basic functional groups matched with each other. Other few basic polymer that not matched with proton could accept the proton transmitted over around, then deliver to proton defect nearby. This kind of proton transition mechanism like proceeding zip-unzip behavior. If the membrane has the new proton conductive mechanism and thermal stability, it could have the opportunity to apply in the fuel cells under high temperature and anhydrous conditions.

中文摘要	                                             Ⅰ
英文摘要	                                             Ⅱ
目錄	                                             Ⅲ
圖目錄	                                             Ⅷ
表目錄	                                             Ⅸ
第一章	緒論	                                     1
1-1前言	                                              1
1-2研究動機	                                     4
第二章	文獻回顧	                                     5
2-1引言：為什麼要於高溫下操作？	                   6
2-1-1PFSA薄膜與相關技術	                   6
2-1-2為什麼要高溫的高分子電解質薄膜	         12
2-2 PFSA薄膜的修飾                   	         13
2-2-1以不含水的低揮發性溶劑膨潤	         14
2-2-2薄型的PFSA強化膜	                  16
2-2-3和親水氧化物的複合物	                  17
2-2-4無機固態質子導體複合物薄膜	         19
2-3替代的磺酸化高分子薄膜和他們的複合物	         21
2-4酸/鹼複合物薄膜                   	         29
第三章	實驗技術與儀器原理	                           33
3-1樣品之製備	                                    33
3-1-1 PAA/P4VP高分子質子交換膜之製備	         33
3-1-2實驗藥品	                           34
3-2傅立葉轉換紅外線光譜儀（FT-IR）       	         35
3-2-1FT-IR之實驗原理	                  35
3-2-2FT-IT之操作程序	                  39
3-3微差掃瞄熱卡計（DSC）	                           39
3-3-1DSC之實驗原理	                           39
3-3-2DSC之操作程序          	        40
3-4熱重量分析儀（TGA）	                           41
3-4-1TGA之實驗原理	                           41
3-4-2TGA之操作程序          	         41
3-5 X-ray繞射儀（X-ray diffraction）	                  42
3-5-1XRD之實驗原理          	         42
3-5-2XRD之操作程序          	         42
3-6高角度環狀暗場掃瞄穿透式電子顯微鏡（HAADF STEM）	43
3-6-1HAADF STEM之實驗原理	                  43
3-6-2HAADF STEM之操作程序	                  44
3-7固態核磁共振光譜（Solid State NMR）	         44
3-7-1Cross-polarization之簡單介紹	         44
3-7-2S.S.NMR之操作程序	                  46
3-8吸水度（Water Uptale）	                           46
3-9交流阻抗分析儀（AC Impedance）	                  46
3-9-1AC Impedance之實驗原理	                  46
3-9-2AC Impedance之操作程序	                  57
第四章	結果與討論	                           59
4-1PAA/P4VP 系統	                                    61
4-1-1傅立葉轉換紅外線光譜（FT-IR）    	61
4-1-2微差掃瞄熱卡計（DSC）	                  65
4-1-3 X-ray繞射儀（XRD）	                  68
4-1-4HAADF STEM	                           71
4-1-513C 固態核磁共振光譜（13C S.S.NMR）	76
4-1-6吸水度（Water Uptake）	                  83
4-1-7熱重量分析（TGA）	                  86
4-1-8交流阻抗儀（AC Impedance）	         89
4-2PAA/P4VP-o系統	                                     92
4-3PAA/P(4VPcoS)系統	                           100
第五章	結論與未來展望	                           106
參考文獻	                                             109

                                

(1) R.S. Yeo, J.C. McBreen, J. Electrochem. Soc. 1983, 130, 533
(2) G. Pourcelly, A. Oikonomou, H.D. Hurwitz, C. Gavach, J. Electroanal. Chem. 1990, 287, 43-59
(3) C. J. Lassegues, B. Desbat, O. Trinquet, F. Cruege, C. Poinsignon, Solid State Ionics, 1989, 35, 17-25,
(4) C. J. Lassegues, P. Colomban, Proton Conductors: Solids, Membranes and Gels - Materials and Devices, Cambridge University Press, Cambridge, 1992
(5) K.D. Kreuer, A. Fuchs, M. Ise, M Spaeth, J. Maier, Electrochimica Acta, Vol. 43, pp. 1281-1288, 1998
(6) M. Yamada, I Honma., Chem. Phys. Chem. 2005, 402, 324-328,
(7) J. S. Wainright, J. T. Wang, D. Weng, R. F. Savinell, M. Litt, Journal of Electrochemical Society, 1995, 142, 121-132
(8) Kerres, J., Ullrich, A., Meier, F., Haring, T., Solid State Ionics, 1999, 125, 243-249.
(9) Honma, I., Hirakawa, S., Yamada, K., Bae, J.M., Solid State Ionics, 1999, 118, 29-36,
(10) M. Tiitu, M. Torkkeli, R. Serimaa, T. Makela, O. T. Ikkela., Solid. State Ionics, 2005, 176, 1291-1299
(11) S. M. Haile, P. M. Calkins and D. Boysen. , Journal of Solid State Chemistry, 1998, 139, 2, 373-387
(12) T. Takahashi, S. Tanese, O. Yamamoto., Journal of Solid State Chemistry, 1976, 17, 353-361
(13) Pourcelly, G.; Gavach, C. In Proton Conductors, Solids, Membranes, and Gels - Materials and Devices; Colomban, P., Ed.;Canbridge University Press: New York, 1992.
(14) Fermandez, R. E. In Polymer Data Handbook; Mark, J. E., Ed.; Oxford University Press: New York, 1999; p 233.
(15) Doyle, M.; Rajendran, G. In Handbook of Fuel Cells, Vielstichm,W., Lamm, A., Gasteiger, H. A., Eds.; John Wiley & Sons Ltd.: New York, 2003; Vol. 3, p 351.
(16) Heinzel, A.; Barragan, V. M. J. Power Sources 1999, 84, 70.
(17) Ise, M.; Kreuer, K. D.; Maier, J. Solid State Ionics 1999, 125, 213.
(18) Xiao, G.; Li, Q.; Hjuler, H. A.; Bjerrum, N. J. J. Electrochem. Soc. 1995, 142, 2890.
(19) Oetjen, H.-F.; Schmidt, V. M.; Stimming, U.; Trila, F. J. Electrochem. Soc. 1996, 143, 3838.
(20) Bogdanovic, B.; Schwickardi, M. J. Alloys Compd. 1997, 253--254, 1.
(21) Thomas, C. E. Int. J. Hydrogen Energy 1998, 23, 507.
(22) Schmidt, T. J.; Noeske, M.; Gasteiger, H. A.; Behm, R. J. J Electrochem. Soc. 1998, 145, 925.
(23) Hogarth, M. P.; Hards, G. A. Eur. Fuel Cell News 1997, 4, 14.
(24) Wasmus, S.; Kuever, A. J. Electroanal. Chem. 1999, 461, 14.
(25) Frank, G. Proceedings of the 2nd European PEFC Forum, June 30-July 4 2003, Lucerne, Switzerland; p 749.
(26) Li, Q.; Hjuler, H. A.; Hasiotis, C.; Kallitsis, J. K.; Kontoyannis, C. G.; Bjerrum, N. J. Electrochem. Solid-State Lett. 2002, 5, A125
(27) Choi, W. C.; Kim, J. D.; Woo, S. I. J. Power Sources 2001, 96, 411.
(28) Hobson, L. J.; Nakano, Y.; Ozu, H.; Hayase, S. J. Power Sources 2002, 104, 79.
(29) Yeo, R. S. Polymer 1980, 21, 432.
(30) Florjanczyk, Z.; Wielgus-Barry, E.; Poltarzewski, Z. Solid State Ionics 2001, 145, 119.
(31) Kimmerle; F. M.; Breault, R. Can. J. Chem. 1980, 58, 2225.
(32) Savinell, R.; Yeager, E.; Tryk, D.; Landau, U.; Wainright, J.; Weng, D.; Lux, K.; Litt, M.; Rogers, C. J. Electrochem. Soc. 1994, 141, L46.
(33) Wasmus, S.; Valeriu, A.; Mateescu, G. D.; Tryk, D. A.; Savinell, R. F. Solid State Ionics, 1995, 80, 87.
(34) Savinell, R. F. Private communication, 2002.
(35) Malhotra, S.; Datta, R. J. Electrochem. Soc. 1997, 144, L23.
(36) Doyle, M.; Choi, S. K.; Proulx, G. J. Electrochem. Soc. 2000, 147, 34.
(37) Kreuer, K. D.; Fuchs, A.; Ise, M.; Spaeth, M.; Maier, J. Electrochim. Acta 1998, 43, 1281.
(38) Schechter, A.; Savinell, R. F. Solid State Ionics 2002, 147, 181.
(39) Sun, J.; Jordan, L. R.; Forsyth, M.; MacFarlane, D. R. Electrochim. Acta 2001, 46, 1703.
(40) Dhar, H. U.S. Patent 5,242,764, 1993.
(41) Bahar, B.; Hobson, A. R.; Kolde, J. A.; Zuckerbrod, D. U.S. Patent 5,547,551, 1996.
(42) Higuchi, Y.; Terada, N.; Shimoda, H.; Hommura, S. U.S. Patent application 0026883A1; EP1139472, 2001.
(43) Bae, B.; Chun, B.-H.; Ha, H.-Y.; Oh, I.-H.; Kim, D. J. Membr. Sci. 2002, 202, 245
(44) Shim, J.; Ha, H. Y.; Hong, S.-A.; Oh, I.-H. J. Power Sources 2002, 109, 412.
(45) Haufe, S.; Stimming, U. J. Membr. Sci. 2001, 185, 95.
(46) Lin, J. C.; Jnuz, H. R.; Fenton, J. M. In Handbook of Fuel Cells; Vielstich, W., Lamm, A., Gasteiger, H. A., Eds.; John Wiley & Sons Ltd.: New York, 2003; Vol. 3, p 457.
(47) Watanabe, M.; Uchida, H.; Seki, Y.; Emori, M. The Electrochemical Society Meeting; PV94-2, Abstract No. 606; Electrochemical Society: Pennington, NJ, 1994; pp 946-947.
(48) (a) Stonehart P.; Watanabe M. U.S. Patent 5,523,181, 1996. (b) Watanabe, M.; Uchida, H. U.S. Patent 5,776,787, 1998. European Patent EP 631337A2, 1998. (c) Antonucci, V.; Arico, A.; DeNoras, P. A. European Patent Application 98123433.9, 1998. (d) Arico´, A. S.; Antonucci, V. European Patent EP 0926754A1, 1999.
(49) Watanabe, M.; Uchida, H.; Seki, Y.; Emori, M.; Stonehart, P. J. Electrochem. Soc. 1996, 143, 3847;
(50) Antonucci, P. L.; Arico´, A. S.; Creti, P.; Ramunni, E.; Antonucci, V. Solid State Ionics 1999, 125, 431.
(51) Mauritz, K. A. Mater. Sci. Eng., C 1998, 6, 121.
(52) Rothenberger, K. S.; GregoirePadro, C. E.; Brenner, J.; Tulyani, S.; Adjemian, K. T.; Krishnan, L.; Yang, C.; Srinivasan, S.; Bocarsly, A.; Benziger, J. Prepr. Pap.sAm. Chem. Soc. Div. Fuel Chem. 2002, 47, 675.
(53) Adjemian, K. T.; Srinivasan, S.; Benziger, J.; Bocarsly, A. B. J. Power Sources 2002, 109, 356.
(54) Adjemian, K. T.; Lee, S. J.; Srinivasan, S.; Benziger, J.; Bocarsly, A. B. J. Electrochem. Soc. 2002, 149, A256.
(55) Grot, W. G.; Rajendran, G. U.S. Patent 5,919,583, 1999.
(56) Staiti, P.; Arico, A. S.; Baglio, V.; Lufrano, F.; Passalacqua, E.; Antonucci, V. Solid State Ionics 2001, 145, 101.
(57) Yang, C.; Srinivasan, S.; Arico`, A. S.; Creti, P.; Baglio, V.; Antonucci, V. Electrochem. Solid-State Lett. 2001, 4, A31.
(58) Costamagna, P.; Yang, C.; Bocarsly, A. B.; Srinivasan, S. Electrochim. Acta 2002, 47, 1023.
(59) Alberti, G.; Casciola, M.; Palombari, R. J. Membr. Sci. 2000, 172, 233.
(60) Alberti, G.; Casciola, M.; Palombari, R. Solid State Ionics 1992, 58, 339.
(61) Alberti, G.; Casciola, M.; Costantino, U.; Peraio, A.; Montoneri, E. Solid State Ionics 1992, 50, 315.
(62) Stein, E. W.; Clearfield, A.; Subramanian, M. A. Solid State Ionics 1996, 83, 113.
(63) Alberti, G.; Boccali, L.; Casciola, M.; Massinelli, L.; Montoneri, E. Solid State Ionics 1996, 84, 97.
(64) Wang, H.; Holmberg, B. A.; Huang, L.; Wang, Z.; Mitra, A.; Norbeck, J. M.; Yan, Y. J. Mater. Chem. 2002, 12, 834.
(65) Costamagna, P.; Yang, C.; Bocarsly, A. B.; Srinivasan, S. Electrochim. Acta 2002, 47, 1023.
(66) Park, Y.-I.; Kim, J.-D.; Nagai, M. J. Mater. Sci. Lett. 2000, 19, 1621.
(67) Park, Y.-I.; Kim, J.-D.; Nagai, M. In Materials Research Society Symposium Proceedings, Vol. 600; Zhang, Q. M., Furukawa, T., Bar-Cohen, Y., Scheinbeim, J., Eds.; Materials Research Society: Warrendale, PA, 2000; p 299.
(68) Tazi, B.; Savadogo, O. Electrochim. Acta 2000, 45, 4329.
(69) Dimitrova, P.; Friedrich, K. A.; Stimming, U.; Vogt, B. Solid State Ionics 2002, 150, 115.
(70) Kerres, J. A. J. Membr. Sci. 2001, 185, 3.
(71) Savadogo, O. J. New Mater. Electrochem. Syst. 1998, 1, 47.
(72) Kreuer, K. D. J. Membr. Sci. 2001, 185, 29.
(73) Akovali, G.; O? zkan, A. Polymer 1986, 27, 1277.
(74) Carretta, N.; Tricoli, V.; Picchioni, F. J. Membr. Sci. 2000, 166, 189.
(75) Garcia, A. G. G.; Pintauro, P. N.; Verbrugge, M. W.; Schneider, E. W. J. Appl. Electrochem. 1992, 22, 204.
(76) Hong, L.; Chen, N. J. Polym. Sci., Part B 2000, 38, 1530.
(77) Gupta, B.; Scherer, G. G. J. Appl. Polym. Sci. 1993, 50, 2129.
(78) Gupta, B.; Scherer, G. G. Chimia 1994, 48, 127.
(79) Glipa, X.; Haddad, M. E.; Jones, D. J.; Rozie`re, J. Solid State Ionics 1997, 97, 323.
(80) Gupta, B.; Buechi, F. N.; Scherer, G. G.; Chapiro, A. Polym. Adv. Technol. 1994, 5, 493.
(81) Kuhn, H.; Gubler, L.; Schmidt, T. J.; Scherer, G. G.; Brack, H.- P.; Simbek, K.; Rager, T.; Geiger, F. Proceedings of the 2nd European PEFC Forum, June 30-July 4, 2003, Lucerne, Switzerland; p 69.
(82) Flint, S. D.; Slade, R. C. T. Solid State Ionics 1997, 97, 299.
(83) Hietala, S.; Holmberg, S.; Karjalainen, M.; Nasman, J.; Paronen, M.; Serimaa, R.; Sundholm, F. J. Mater. Chem. 1997, 7, 721.
(84) Hietala, S.; Koel, M.; Skou, E.; Elomaa, M.; Sundholm, F. J. Mater. Chem. 1998, 8, 1127.
(85) Holmberg, S.; Nasman, J. H.; Sundholm, F. Polym. Adv. Technol. 1998, 9, 121.
(86) Ostrovskii, D. I.; Torell, L. M.; Paronen, M.; Hietala, S.; Sundholm, F. Solid State Ionics 1997, 97, 315
(87) Hietala, S.; Maunu, S. L.; Sundholm, F. J. Polym. Sci., Part B 2000, 38, 3277.
(88) Wei, J.; Stone, C.; Steck, A. E. WO 95/08581, 1995.
(89) Stone, C.; Hu, L. Q.; Daynard, T.; Mah, C.; Steck, A. E. Extended Abstracts of the 3rd International Symposium on New Materials for Electrochemical Systems, Montreal, Canada, July 4-8, 1999; pp 238-239.
(90) Steck, A.; Stone, C.; Proceedings of the 2nd International Symposium on New Materials for Fuel-Cell and Modern Battery Systems, Montreal, Canada, July 6-10, 1997; Savadogo, O., Roberge, P. R., Eds.; pp 792-807.
(91) Brinker, C. H.; Scherer, G. Sol-gel Science; Academic Press: London, 1990.
(92) Hench, L. L.; West, J. K. Chem. Rev. 1990, 90, 33.
(93) Schmidt, T. J. Non-Cryst. Solids, 1985, 73, 681.
(94) Kreuer, K. D. J. Membr. Sci. 2001, 185, 29.
(95) Rikukawa, M.; Sanui, K. Prog. Polym. Sci. 2000, 25, 1463.
(96) Nolte, R.; Ledjeff, K.; Bauer, M.; Mu lhaupt, R. J. Membr. Sci. 1993, 83, 211.
(97) Kerres, J.; Zhang, W.; Cui, W. J. Polym. Sci. Part A 1998, 36, 1441
(98) Kerres, L.; Cui, W.; Junginger, M. J. Membr. Sci. 1998, 139, 227.
(99) Nakajima, H.; Honma, I. Solid State Ionics 2002, 148, 607.
(100) Honma, I.; Nomura, S.; Nakajima, H. J. Membr. Sci. 2001, 185, 83.
(101) Nakajima, H.; Nomura, S.; Sugimoto, T.; Nishikawa, S.; Honma, I, J. Electrochem. Soc. 2002, 149, A953.
(102) Staiti, P.; Minutoli, M.; Hocevar, S. J. Power Sources 2000, 90, 231.
(103) Staiti, P.; Minutoli, M. J. Power Sources 2001, 94, 9.
(104) Genova-Dimitrova, P.; Baradie, B.; Foscallo, D.; Poinsignon, C.; Sanchez, J. Y. J. Membr. Sci. 2001, 185, 59.
(105) Baradie, B.; Poinsignon, C.; Sanchez, J. Y.; Piffard, Y.; Vitter, G.; Bestaoui, N.; Foscallo, D.; Denoyelle, A.; Delabouglise, D.; Vaujany, M. J. Power Sources 1998, 74, 8.
(106) Bonnet, B.; Jones, D. J.; Roziere, J.; Tchicaya, L.; Alberti, G.; Casciola, M. Massinelli, L.; Baner, B.; Peraio, A.; Ramunni, E. J. New Mater. Electrochem. Syst. 2000, 3, 87.
(107) Zaidi, S. M. J. Mikhailenko, S. D.; Robertson, G. P.; Guiver, M. D.; Kaliaguine, S. J. Membr. Sci. 2000, 173, 17.
(108) Nunes, S. P.; Ruffmann, B.; Rikowski, E.; Vetter, S.; Richau, K. J. Membr. Sci. 2002, 203, 215.
(109) Mikhailenko, S. D.; Zaidi, S. M. J.; Kaliaguine, S. Catal. Today, 2001, 67, 225.
(110) Rozie´re, J.; Jones, D. J.; Tchicaya-Bouckary, L.; Bauer, B. WO 02/05370, 2000.
(111) Hickner, M.; Kim, Y. S.; Wang, F.; Zawodzinski, T. A.; McGrath, J. E. Proc. 33rd Int. SAMPE Techn. Conf. 2001, 33, 1519.
(112) Poinsignon, C.; Amodio, I.; Foscallo, D.; Sanchez, J. Y. Mater. Res. Soc. Symp. Proc. 2000, 548, 307.
(113) He, R.; Li, Q.; Xiao, G.; Bjerrum, N. J. J. Membr. Sci. 2003, 226, 169.
(114) Peled, E.; Duvdevani, T.; Melman, A. Electrochem. Solid State Lett. 1998, 1, 210.
(115) Peled, E.; Duvdevani, T.; Aharon, A.; Melman, A. Electrochem. Solid State Lett. 2000, 3, 525.
(116) Boysen, D. A.; Chrisholm, C. R. I.; Haile, S. M.; Sekharipuram, V.; Narayanan, R. J. Electrochem. Soc. 2000, 147, 3610.
(117) Amarilla, J. M.; Rojas, R. M.; Rojo, J. M.; Cubillo, M. J.; Linares, A.; Acosta, J. L. Solid State Ionics 2000, 127, 133.
(118) Park, Y.; Nagai, M. Solid State Ionics 2001, 145, 149.
(119) Stangar, U. L.; Orel, B.; Groselj, N.; Judeinstein, P.; Decker, F.; Lianos, P. Monatsh. Chem. (Chem. Monthly) 2001, 132, 103.
(120) Honma, I.; Nakajima, H.; Nishikawa, O.; Sugimoto, T.; Nomura, S. J. Electrochem. Soc. 2002, 149, A1389.
(121) Lavrencic S. U.; Groselj, N.; Orel, B.; Schmitz, A.; Colomban, P. Solid State Ionics 2001, 145, 109.
(122) Vaivars, G.; Azens, A.; Grangvist, C. G. Solid State Ionics 1999, 119, 269.
(123) Poltarzewski, Z.; Wieczorek, W.; Przyluski, J.; Antonucci, V. Solid State Ionics 1999, 119, 301.
(124) Park, Y.-I.; Dong, K. J.; Nagai, M. J. Mater. Sci. Lett. 2000, 19, 1735.
(125) Lasse´gues, J. C. In Proton Conductors, Solids, Membranes and Gels - Materials and Devices; Colomban, Ph., Ed.; Cambridge University Press: New York, 1992; pp 311-328.
(126) Vaivars, G.; Azens, A.; Grangvist, C. G. Solid State Ionics 1999, 119, 269.
(127) Dabrowska, A.; Stys, S.; Wieczorek, W.; Przyluski J. Proceedings of the 1st International Symposium on New Materials for Fuel Cell Systems, Montreal, Canada, 1995; Electrochemical Society, Inc.: Pennington, NJ, 1995, p 95.
(128) Petty-Weeks, S.; Zupancic, J. J.; Swedo, J. R. Solid State Ionics 1988, 31, 117.
(129) Tanaka, R.; Yamamoto, H.; Shono, A.; Kubo, K.; Sakurai, M. Electrochim. Acta 2000, 45, 1385.
(130) Grondin, J.; Rodriguez, D.; Lassegues, J. C. Solid State Ionics 1995, 77, 70.
(131) Bozkurt, A.; Ise, M.; Kreuer, K. D.; Meyer W. H.; Wegner, G. Solid State Ionics 1999, 125, 225.
(132) Lasse´gues, J. C.; Grondin, J.; Hernandez, M.; Maree, B. Solid State Ionics 2001, 145, 37.
(133) Senadeera, G. K. R.; Careem, M. A.; Skaarup, S.; West, K. Solid State Ionics 1996, 85, 37.
(134) Peled, E.; Duvdevani, T.; Melman, A. Electrochem. Solid-State Lett. 1998, 1, 210.
(135) Raducha, D.; Wieczorek, W.; Florjanczyk, Z.; Stevens, J. R. J. Phys. Chem. 1996, 100, 20126.
(136) Ericson, H.; Svanberg, C.; Brodin, A.; Grillone, A. M.; Panero, S.; Scrosati, B.; Jacobsson, P. Electrochim. Acta 2000, 45, 1409.
(137) Bouchet, R.; Siebert, E. Solid State Ionics 1999, 118, 287.
(138) Glipa, X.; Bonnet, B.; Mula, B.; Jones, D. J.; Rozie´re, J. J. Mater. Chem. 1999, 9, 3045.
(139) Kerres, J.; Ullrich, A.; Ha ring, Th.; Baldauf, M.; Geghardt, U.; Preidel, W. J. New Mater. Electrochem. Syst. 2000, 3, 229.
(140) Guiver, M. D.; Robertson, G. P.; Foley, S. Macromolecules 1995, 28, 7612.
(141) Jorissen, L.; Gogel, V.; Kerres, J.; Garche, J. J. Power Sources 2002, 105, 267.
(142) Deimede, V.; Voyiatzis, G. A.; Kallitsis, J. K.; Li, Q.; Bjerrum, N. J. Macromolecules 2000, 33, 7609.
(143) Hasiotis, C.; Li, Q.; Deimede, V.; Kallitsis, J. K.; Kontoyannis, C. G.; Bjerrum, N. J. J. Electrochem. Soc. 2001, 148, A513.
(144) Bauer, B.; Jones, D. J.; Roziere, J.; Tchicaya, L.; Alberti, G.; Massinelli, M.; Peraio, A.; Besse, S.; Ramunni, E. J. New Mater. Electrochem. Syst. 2000, 3, 93.
(145) Li, Q.; Hjuler, H. A.; Bjerrum, N. J. J. Appl. Electrochem. 2001, 31, 773.
(146) Wang, J.-T.; Savinell, R. F.; Wainright, J. S.; Litt, M.; Yu, H. Electrochim. Acta 1996, 41, 193.
(147) Savadogo, O.; Xing, B. J. New Mater. Electrochem. 2000, 3, 345.
(148) Deimede, V.; Voyiatzis, G. A.; Kallitsis, J. K.; Li, Q.; Bjerrum, N. J. Macromolecules 2000, 33, 7609.
(149) Haile, S. M.; Boysen, D. A.; Chisholm, C. R. I.; Merle, R. B. Nature 2001, 410, 910.
(150) Wainright, J. S.; Wang, J.-T.; Weng, D.; Savinell R. F.; Litt, M. J. Electrochem. Soc.1995, 142, L121.
(151) Wang, J.-T.; Wainright, J. S.; Savinell R. F.; Litt, M. J. Appl. Electrochem. 1996, 26, 751.

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