15keV H3+離子撞擊含NH鍵或CH鍵的化合物與水混合之冰晶

簡易檢索 / 詳目顯示

回結果列表

研究生：	游宗翰 You-zong Han
論文名稱：	15keV H3+離子撞擊含NH鍵或CH鍵的化合物與水混合之冰晶 15keV H3+ ion bombard the ice that include NH or OH bond chemical compound and H2O mixed, and analyze the quantity of the CO(2138cm-1)、CO2(2341cm-1) and OCN-(2165cm-1) bond that produced
指導教授：	李雄 Lee-Shyong 李敬萱 Lee-chin Shuang
口試委員:
學位類別：	碩士 Master
系所名稱：	工學院 - 機械工程學系 Department of Mechanical Engineering
畢業學年度：	97
語文別：	中文
論文頁數：	64
中文關鍵詞：	NH鍵、OH鍵、星際冰晶、傅式紅外光譜、氫離子
外文關鍵詞：	NHbond, OH bond, FTIR, H3+ ion
相關次數：	點閱：13 下載：0
分享至:	分享至facebook 分享至twitter

查詢本校圖書館目錄查詢臺灣博碩士論文知識加值系統勘誤回報

我們的行星系統，由星際間密集的分子雲(Dense molecular cloud)彼此重力相互的吸引後所形成。而星際間的密集分子雲主要是由氣體及微小晶粒(Sub-micrometer sized grain)所組成。在太空溫度如此低溫的狀態環境下氣體會附著於星際塵埃粒子的表面，形成星際冰晶。主要包含H2O、CO、CO2、CH3OH、CH4、OCN-及NH2COOH…等。這些冰晶在經過太陽風(Solar wind)的轟擊後，其演化的機制，是我們主要探討的地方。
本實驗室將模擬外太空環境，在低溫(24K)、超高真空(6 × 10-10 Torr)下，以15keV H3+離子轟擊含NH或OH鍵與水H2O相互混合之冰晶，藉由傅式紅外光譜儀(FTIR)掃瞄冰晶結冰與轟擊時的紅外光譜圖。
最後在進而分析在CO(2138 cm-1)、CO2(2341 cm-1)以及OCN-(2165 cm-1)三個位置上在含NH與OH鍵之化合物與水H2O相互混合不同比例下的生成影響。

Our planetary system is composed of the collapse of dense molecular cloud, and it is attracted each other by gravity. The collapse of dense molecular cloud are composed of gases and sub-micrometer sized grains. The main composition of the interstellar solid material include H2O、 CO、CO2、CH3OH、CH4、OCN-、and NH2COOH etc,. These interstellar ice after the energetic particle bombarded that are being come from the solar wind and how evolves its interstellar ice is the main place where we probe into.
In our experiment is to utilize cryogenic technique(24 K) and ultra high vacuum(6×10-10) to simulate the environment of outer space, it use H3+ ion to bombard the ice that include NH or OH bond chemical compound and H2O mixed, and the energy as 15keV. It used FTIR to scan the frozen and infrared spectrum of the ice crystal.
Finally, analyze the quantity of the CO(2138cm-1)、CO2(2341cm-1) and OCN-(2165cm-1) bond that produced, and analyze the influence of mixing and proportion of H2O with NH and OH bond.

中文摘...............................................................................................................I
英文摘要………………………………………………………………………II
目錄.................................................................................................................. Ⅲ
圖目錄................................................................................................................Ⅵ
表目錄................................................................................................................IX
第一章 序論......................................................................................................1
1-1簡介......................................................................................................1
1-2各章摘要..............................................................................................2
第二章 實驗原理..............................................................................................3
2-1高能粒子..............................................................................................3
2-2紅外光譜術..........................................................................................3
2-2-1振動模式.....................................................................................4
2-2-2 麥克森干涉儀............................................................................4
2-2-3 傅立葉轉換................................................................................6
第三章 實驗設備、步驟及參數.......................................................................8
3-1 實驗設備.............................................................................................8
3-1-1 離子源系統...............................................................................8
3-1-2 電磁鐵.......................................................................................9
3-1-3 傅式紅外光譜儀......................................................................10
3-2 實驗步驟.............................................................................................11
第四章 實驗結果與討論...................................................................................19
4-1 光譜圖介紹..........................................................................................19
4-2 光譜分析..............................................................................................20
4-3 純冰晶光譜……..................................................................................21
4-3-1 NH3冰晶紅外光譜....................................................................21
4-3-2 CH3OH冰晶紅外光譜..............................................................22
4-4 混合冰晶光譜分析.............................................................................23
4-4-1 NH3+CH3OH (1:1) (1:6) (3:1) (6:1)冰晶紅外光譜………......23
4-4-2 CH3OH + H2O (CH3OH) (1:1) (1:6) (3:1) (6:1)冰晶紅外光          譜..............................................................................................27
4-4-3 NH3 + CH3OH + H2O (1:1:1) (1:1:3) (1:1:6) (1:3:1) (1:6:1)                           (3:1:1) (6:1:1)冰晶紅外光譜………………………………....30
第五章 總結.....................................................................................................57
5-1 結論...................................................................................................57
參考文獻...........................................................................................................60
附錄………………………………………………………..………………….62

                                

1.Max P. Bernstein, Scott A. Sandford, Louis J. Allamandola,J.Seb Gillette, Simon J. Clemett, Richard N. Zare, Science,283,1135.(1999)
2.章朝盛，航向未知，天文館期刊，第九期。
3.Hollenbach, D. J., and Thronson, H. A. Interstellar Processes.Dordrecht: Reidel (1987).
4.陳俞融，UV / EUV光子對星際冰晶的光化作用，博士論文，民96
5.潘俊良，氧氣覆著在金屬表面的濺射研究，碩士論文，民87
6.FTLA2000 Series Laboratory FT-IR Spectrometers Reference Manual,2004
7.“Ion Beams for Research and Industry – Instruction Manual Model 358 Duoplasmatron”, pp.13-14 General Ionex Corporation
8. L. B. d，Hendecourt (1,2) and L. J. Allamandola (1,3), Astron. Astrophys. Suppl. Ser. 64, 453-467 (1986)
9. W.A. SCHUTTE,1 A.G.G.M. TIELENS,2 AND S.A. SANDFORD1, THE ASTROPHYSICAL JOURNAL,382:523-529,(1991)
10.FALK,M. WHALLEY, E., J. Chem. Phys.34,1554,(1961)
11. Corey S. Jamieson, Alexander M. Mebel, and Ralf I. Kaiser, The Astrophysical Journal, 163:184-206, (2006)
12.P. A. Gerakines, J. J. Bray, A. Davis, and C. R. Richey , The Astrophysical Journal, 620:1140-1150, (2005)
13. M.H. Moorea,* and R.L. Hudsonb , Icarus. 161 :486-500, (2003)
14. Sebastien Raunier..et. al., Chemical Physics 288,197-210,(2003)
15. M.H. Moore, R.L. Hudson, Icarus 135,518-527(1998)
16.M. H. Moore , R. F. Ferrante and J. A. Nuth III , Planet. Space Sci. , Vol. 44 , No. 9 , pp. 927-935 , (1996)
17.J. V. Keane , A. G. G. M. Tielens, A. C. A. Boogert , W. A. Schutte , and D. C. B. Whittet , A&A 376, 254-270(2001)
18.R.L. Hudson,1 M.H. Moore,2 and P. A. Gerakines3,The Astrophysical Journal,550:1140-1150,(2001)
19.F.A. van Broekhuizen, J.V. Keane, and W.A. Schutte, A&A Feb 2,2008
20.S. Raunier, T. Chiavassa, F. Marinelli, A. Allouche, J.P. Aycard, Chemical Physics Letters 368,594-600,(2003)
21.廖鐿全，15keV H3+離子轟擊含CH鍵或CO鍵的化合物與水混合之冰晶產生OH與CH化合物的FTIR光譜分析，碩士論文，民97

簡易檢索 / 詳目顯示

相關論文