| 研究生: |
張雅頌 Ya-sung Chang |
|---|---|
| 論文名稱: |
鏡煤素反射率抑制問題與熱模擬之探討 Studies of suppression and thermal simulation of vitrinite reflectance |
| 指導教授: |
蔡龍珆
Louis L. Tsai |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
地球科學學院 - 應用地質研究所 Graduate Institute of Applied Geology |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 56 |
| 中文關鍵詞: | 熱模擬 、鏡煤素反射率 |
| 外文關鍵詞: | Thermal simulation, Vitrinite reflectance |
| 相關次數: | 點閱:8 下載:0 |
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鏡煤素反射率被廣泛應用於地層對比、變質度及有機物成熟度指標等,然常有被抑制的現象,影響油氣潛能評估。本研究以台灣三峽裕鋒煤(中新世石底層)透過膜煤素富集後,將煤樣製成薄片,在顯微鏡下以反射光與透射光交互觀察,以研究當膜煤素隱伏於鏡煤素之下對反射率的影響。
在透射光下發現當測量面的鏡煤素下方有膜煤素存在時,反射率呈現明顯下降,且反射率被抑制之情形與膜煤素和鏡煤素間的距離相關,即兩者間愈近,反射率測值愈低。
本研究亦以不同的加熱溫度、停溫時間以及加熱速率分別對44個煤樣(裕峰煤)進行熱模擬,並測得其加熱後的鏡煤素反射率。實驗結果發現,較高的加熱速率與加熱溫度確實造成鏡煤素反射率的上升,且以較快速率加熱,到達較高的溫度後,停溫時間(soaking time)對鏡煤素反射率才有較顯著的影響,且反射率隨著停溫時間的增加而有上升趨勢。
The reflectance of vitrinite is useful in many aspects, such as stratigraphic correlation, index of metamorphism and thermal maturation of organic matters. However, suppression of vitrinite reflectance had been reported and did affect the assessment of HC potential. Coal samples were collected from Yu-Feng mine in San-Hsia, North Taiwan. Exinite-enriched coal mixtures were prepared by density centrifuge of ZnCl2 solution and then made into thin sections and polished pellets. Samples were observed both in transmitted and reflected light under microscope. Reflectance of vitrinite particles were measured, so as to evaluate the effects of underneath exinite.
The result shows that vitrinite reflectance was lowered due to exinite existed underneath the measuring surface of thin-layered vitrinite, especially when exinites were close to the vitrinite surface.
44 coal samples were heated in different rate, different temperature and different soaking time. The reflectance of vitrinite measured after heating indicate that the vitrinite reflectance increases with increasing heating temperature and heating rate. In addition, the reflectance was affected by soaking time when higher heating rate and temperature were performed. i.e, the longer the soaking time, the higher reflectance will be.
ASTM, 1975, Standard D-2797, ASTM Standard manual, Part 26, p.350-354.
ASTM, 1980, Standard D-2797, Microscopical determination of volume percent of physical components in a polished specimen of coal, ASTM. Philadelphia, PA.
Bensley, D. F. and J.C. Crelling, 1992, Low intensity spectral analysis (LISA) of coal maceral and the assessment of DGC fractions. Org. Geochem., V.18, No.3, 365-372.
Berger, I. A., 1961, Kerogen. In:McGraw Hill Encyclopedia of Science and Technology, New York, McGraw Hill.
Burgess, J. D., 1974, Microscopic examination of kerogen (dispersed organic matter) in petroleum exploration. Geol. Soc. Am.,Special Paper 153, p. 19-30.
Carr, A.D., 2000, Suppression and retardation of vitrinite reflectance, part1. Formation and significance for hydrocarbon generation, Journal of Petroleum Geology, v.23(3), p. 313-343
Crum-Brown, A., 1912, Oil shale of Lothians. Memoirs Geol. Survey, 143.
Davis, A., 1978, The reflectance of coal. In: Karr, C. Jr. (ed.):Analytical Methods for Coal and Coal Products. Academic Press, Inc., New York, p. 27-81.
Dow, W. G, 1977, Kerogen studies and geological interpretation. J. Geochem. Explor., Vol. 7, p. 17-99.
Fujii, K., S. Yamazaki, K. Shoda, and K. Miki, 1982, Effect of degradinite of coal properties and its conversion at Ikeshima coal mine. AAPG Bulletin, Vol. 66, p. 968.
Hunt, J. M., 1979, Petroleum geochemistry and geology: San Francisco, W. H., Freeman and Company, p. 617.
Hutton, A. C. and A. C. Cook, 1980, Influence of alginite on the reflectance of vitrinite from Joadja, NSW, and some other coals and oil shales containing alginite, Fuel, Vol. 59, p. 711-714.
Komorek, J., R. Morga, M. Pozzi, 2003, Vitrinite reflectance property change during heating under inert conditions. International Journal of Coal Geology ,Vol 54, p. 125-136.
Newman, J. and N. A. Newman, 1982, Reflectance anomalies in Pike Rive coals: evidence of variability in vitrinite type, with implication for maturation studies and “Suggate rank”. New Zealand Journ. Geol. Geophys. 25, p. 233-243.
Price, L. C. and C. E. Barker, 1985, Suppression of vitrinite reflectance in amorphous rich kerogen – A major unrecognized problem. Journ. Petrol. Geol., Vol. 8, No. 1, p. 59-84.
Sitler, J. A., 1979, Effects of source material on vitrinite reflectance, Master thesis, West Virginia University, 103p.
Stach, E., M-Th. Mackowsky, M. Teichmüller, G. H. Taylor, D. Chandra, and R. Teichmüller, 1982, Stach’s Textbook of coal petrology (3rd ed.), Berlin Stuttgar, Gebruder Borntraeger, 535p.
Stopes, M. C., 1935, On the petrology of banded bituminous coals. Fuel 14, 4-13..
Teichmüller, M., 1989, The genesis of coal from the view point of Coal Petrology. In: P. C. Lyons and B. Alperns (Eds), Peat and Coal:Facies and Depositional Models. Int. Journ. Coal Geol., Vol. 12, p.1-87.
Ting, F. T. C., 1978, Petrographic techniques in coal analysis. In: Karr, C., Jr. (ed.):Analytical Methods for Coal and Coal Products.Academic Press, Inc., New York, p. 3-26.
Tissot, B. P. and D. H. Welte, 1984, Petroleum formation and occurrence;a new approach to oil gas exploration, Springer-Verlag, Berlin, Heidelberg, NewYork, 699p.
van Krevelen, D. W., 1961, Coal. Elsevier scientific publishing Co., Amsterdam-London-New York-Princeton, 514p.
何春蓀,1966,台灣北部石底層之研究,台灣省地質調查所彙刊 第
十七號,第1-7 頁。
何春蓀,1975,台灣地質概論台灣地質說明書,經濟部中央地質調
查所出版,共163 頁。
陳佳芬,2001,台灣中新世石底層煤中硫及微量元素含量之沈積涵
義,國立中央大學地球物理研究所碩士論文,共79頁。
孫立中,2000,抑制鏡煤素反射率之量測成因—以分離台灣裕峰煤
樣為例,國立中央大學地球物理研究所博士論文,共81頁。
游能悌,鄧屬予,1996,台灣北部中上中新統的岩相與沈積循環,
地質第15卷第二期,第29-60 頁。
游能悌,鄧屬予,1999,台灣北部大寮層與石底層之沈積環境,經
濟部中央地質調查所彙刊 第十二號,第99-131 頁。
趙師慶,1991,實用煤岩學,地質出版社出版,共205頁。
蔡龍珆,1988,基隆-台北間煤層鏡煤素之共生次序含意,地質第
8 卷,1-2 期,63-70 頁。
鄭國東、羅斌杰、程克明、段毅,1996,源岩鏡質體反射率和有機
質演化的熱模擬研究,沉積學報,第14期(Supp.),第122-
130頁。
盧東郎,1981,鏡煤素反射率測定與評估生油岩成熟度之研究。石油季刊,Vol. 17, No. 2, 49-67.