跳到主要內容

簡易檢索 / 詳目顯示

研究生: 林政逸
Jheng-Yi Lin
論文名稱: La、Ce微量稀土元素對A201合金微結構與機械性質之影響
Effect of Minor Rare Earth La and Ce Additions on the Microstructure and Mechanical Properties of A201 Alloys
指導教授: 李勝隆
Sheng-long Lee
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
畢業學年度: 94
語文別: 中文
論文頁數: 46
中文關鍵詞: A201合金稀土元素
外文關鍵詞: A201 alloy, Rare Earth
相關次數: 點閱:9下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • A201(Al-Cu-Mg-Ag)合金為可熱處理型高強度鋁合金,藉由Ω相及θ’相的析出而達到析出強化的效果。由文獻得知於鋁合金中添加微量稀土元素會產生介金屬化合物,同時成為異質成核點使晶粒產生細化效果,還能提升機械性質及增加合金高溫強度。
    故本研究探討添加微量稀土元素La、Ce元素對A201合金之微結構與機械性質之影響。試片經過T7時效處理,利用光學顯微鏡(OM)、掃描式電子顯微鏡(SEM)、微差掃描熱分析儀(DSC)、導電度(%IACS)、硬度試驗、拉伸試驗(Tensile Test)等方法,分析稀土元素的添加對合金微結構的變化與材料機械性質之關係。
    結果顯示,A201合金添加稀土元素La及Ce時,於鑄態中會晶出富La相及富Ce相,成為鋁基地異質成核點使晶粒產生細化。經EPMA分析得知富La相及富Ce相的生成消耗合金中Cu、Mg、Ag元素,且無法經由固溶處理回溶於鋁基地內,經T7時效處理後造成Ω及θ’相強化相析出量減少,使得合金硬度及強度降低,但延性提升。


    A201(Al-Cu-Mg-Ag) alloy has been widely applied in the aviation and military industries due to its very high mechanical strength and thermal stability which by Ω phase and θ’ phase. Rare earth elements in conventional casting of aluminum alloys have shown beneficial effects on melting and solidification such changes in grain size and precipitation behavior improved the tensile strength at both room and high temperatures.
    Effect of minor rare earth La and Ce additions on microstructure and mechanical properties of A201(Al-Cu-Mg-Ag) alloys were investigated. After different aging T7, using Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Differential Scanning Calorimeter (DSC), Electrical Conductivity Meter (%IACS), Rockwell Hardness Tester and Tensile Test, Analyzing the variation of microstructure of the alloys to compare with the variation of mechanical properties.
    Experimental results show that addition of La and Ce to A201(Al-Cu-Mg-Ag) alloys produces grain refinement due to the formation of La-rich compounds and Ce-rich compounds during solidification. The formation of La-rich compounds and Ce-rich compounds consumes the parts of Cu、Mg and Ag content, and can’t dissolve in subsequent solution treatment. The available amount of Cu、Mg and Ag which is dissolved in matrix reduces, diminishing the precipitates of Ω and θ’ phase, than the hardness and strength decrease but increase the elongation.

    摘要………………………………………………………………… Ⅰ 謝誌………………………………………………………………… Ⅲ 總目錄……………………………………………………………… Ⅳ 圖目錄……………………………………………………………… Ⅵ 表目錄……………………………………………………………… Ⅶ 壹、前言……………………………………………………………… 1 1.1 A201鋁合金簡介………………………………………………… 1 1.2 稀土元素及應用領域之介紹…………………………………… 5 1.2.1 何謂稀土元素………………………………………………… 5 1.2.2 稀土元素的物理化學性質…………………………………… 5 1.2.3 稀土元素之應用領域………………………………………… 7 1.3 稀土元素對鋁合金之影響………………………………………10 1.4 實驗目的與合金設計……………………………………………11 貳、實驗步驟與方法…………………………………………………13 2.1 合金熔配及熱處理………………………………………………14 2.1.1 合金熔配與成分分析…………………………………………14 2.1.2 熱處理…………………………………………………………14 2.2 微結構分析………………………………………………………15 2.2.1 金相OM觀察……………………………………………………15 2.2.2 導電度(%IACS)量測…………………………………………15 2.2.3. 電子微探儀(EPMA)………………………………………… 15 2.2.4. 微差掃描熱分析儀(DSC)……………………………………15 2.2.5. 掃描式電子顯微鏡(SEM) ………………………………… 16 2.3 機械性質分析……………………………………………………16 2.3.1. 硬度試驗…………………………………………………… 16 2.3.2. 拉伸試驗…………………………………………………… 16 參、結果與討論………………………………………………………18 3.1 微結構分析………………………………………………………18 3.1.1 金相觀察及電子微探儀(EPMA)分析…………………………18 3.1.2 導電度(%IACS)分析…………………………………………24 3.1.3 微差掃瞄熱分析(DSC)分析………………………………… 26 3.2 機械性質分析……………………………………………………27 3.2.1. 硬度試驗…………………………………………………… 27 3.2.2. 拉伸試驗…………………………………………………… 29 肆、結論………………………………………………………………31 伍、未來研究方向……………………………………………………32 陸、參考文獻…………………………………………………………33

    1.R. E. Reed-Hill and R. Abbaschian, “Physical Metallurgy Principles”, 3rd ed., PWS Publishing Company, 1991, pp.697-698
    2.J. R. Davis, “Aluminum and Aluminum alloys”, ASM Specialty Handbook, ASM International, 1994, pp.706-707
    3.J. E. Hatch, “ Aluminum: Properties and Physical Metallurgy ”, ASM, 1984, metals park, Ohi
    4.I. J. Polmear, G. Pons, Y. Barbaux, H. Octor, C. Sanchez, A. J. Morton, W. E. Borbidge and S. Rogers, “After Concorde:Evaluation of creep resistant Al-Cu-Mg-Ag Alloys”, Materials Science and Technology, 1999, Vol.15, pp.861-868
    5.鄭嘉仁, “ Mn含量對A201鋁合金晶粒成長之影響 ”, 國立中央大學機械工程研究所碩士論文,1993
    6.J. R. Davis, “ Aluminum and Aluminum Alloys ” , ASM Specialty Handbook ASM International, 3rd printing, 1994, pp.708
    7.S. P. Ringer, K. Hono, T. Sakurai, I. J. Polmear, “ Cluster Hardening in an Aged Al-Cu-Mg Alloy ” , Scripta Materialia, Vol.36, No.5, 1997, pp.517-521
    8.J. Raffin, US Patent No.3475166, Oct.26, 1969
    9.J. R. Davis, “ Aluminum and Aluminum Alloys ” , ASM Specialty Handbook ASM International, 3rd printing, 1994, p.25
    10.N. J. Davidson, “ Review of the Mechanical Properties, Reliability and Usage of Ultra High Strength Aluminum Casting Alloys 201.0 and 206.0” , AFS, 1988, pp.232~247
    11.N. J. Davidson, “Review of the Mechanical Properties, Reliability and Usage of Ultra High Strength Aluminum and Application”, AFS, 1988, pp.232-247
    12.B. C. Muddle and I. J. Polmear, “The Precipitate Ω Phase in Al-Cu-Mg-Ag Alloys”, Acta Metall., 1989, Vol.37, pp.777-789
    13.R. J. Chester and I. J. Polmear, “TEM Investigation of Precipitates in Al-Cu-Mg-Ag and Al-Cu-Mg Alloys”, Micron, 1980, Vol.11, pp.311-312
    14.K. M. Knowles and W. M. Stobbs, “The Structure of {100} Age-hardening Precipitates in Al-Cu-Mg-Ag Alloys”, Acta Cryst., 1988, B44, pp.207-227
    15.S. P. Ringer, W. Yeung, B. C. Muddle and I. J. Polmear, “Precipitate Stability in Al-Cu-Mg-Ag Alloys Aged at High Temperatures”, Acta Metall. Mater., 1994, Vol.42, pp.1715-1725
    16.I. J. Polmear and M. J. Couper, “Design and Development of an Experimental Wrought Aluminum Alloy for Use at Elevated Temperature”, Metallurgical Transaction A, 1988, Vol.19A, pp.1027-1035
    17.I. J. Polmear, G. Pons, Y. Barbaux, H. Octor, C. Sanchez, A. J. Morton, W. E. Borbidge and S. Rogers, “After Concorde: Evaluation of Creep Resistant Al- Cu-Mg-Ag Alloys”, Materials Science and Technology, 1999, Vol.15, pp.861-868
    18.K. Hono, N. Sano, S. S. Babu, R. Okano and T. Sakurai, “Atom Probe Stuty of the Precipitation Process in Al-Cu-Mg-Ag Alloys”, Acta Metall. Mater., 1993, vol.41, pp.829-838
    19.R. K. Wyss and R. E. Sanders, “Microstructure-Property Relationship in a 2xxx Aluminum Alloy with addition”, Metallurgical Transaction A, 1988, Vol.19A, pp.2523-2530
    20.C. H. Chang, S. L. Lee, J. C. Lin and R. R. Jeng, “The Effect of Silver Content on the Precipitation of the Al-4.6Cu-0.3Mg Alloy”, Materials Transactions, JIM, 2005, Vol.46, No.2, pp.236-240
    21.A. Grag, Y. C. Chang and J. M. Howe, “Precipitation of the Ω Phase in an Al-4.0Cu-0.5Mg alloy”, Scripta Metallurgica et Materialia, 1990, Vol.24, pp.677-680
    22.J. A. Taylor, B. A. Parker and I. J. Polmear, “Precipitation in Al-Cu-Mg-Ag Casting Alloy”, Metal Science, 1978, Vol.12, No.10, pp.478-482
    23.K. Hono, T. Sakurai and I. J. Polmear, “Pre-Precipitate Clustering in an Al-Cu-Mg-Ag Alloy”, Scripta Metallurgica et Materialia, 1994, Vol.30, No.6, pp.695-700
    24.S. P. Ringer, K. Hono, I. J. Polmear and T. Sakurai, “Nucleation of Precipitates in Aged Al-Cu-Mg-(Ag) Alloys with High Cu:Mg Ratios”, Acta Materialia, 1996, Vol.44, No.5, pp.1883-1898
    25.L. Reich, M. Murayama and K. Hono, “Evolution of Ω Phase in an Al-Cu-Mg-Ag Alloy – A Three-Dimensional Atom Probe Study”, Acta Materialia, 1998, Vol.46, No.17, pp.6053-6062
    26.R. E. Reed-Hill and R. Abbaschian, “Physical Metallurgy Principles”, 3rd ed., PWS Publishing Company, 1991, pp.534-535
    27.T. D. Burleigh, “The Postulated Mechanisms for Stress Corrosion Cracking of Aluminum Alloys”, Corrosion, 1991, Vol.47, pp.89-98
    28.M. S. Misra and K. J. Oswalt, “Corrosion Behavior of Al-Cu-Ag (A201) Alloy”, Metals Engineering Quarterly, 1976, pp.39-44
    29.“Aerospace Material Specification”, AMS, 1987, 4235A, AMS4236
    30.J. W. Shyu, C. L. Sheu, "The Application of Rare Earth Element in Cast Alloy (Ⅰ)", Journal of Chinese Foundrymen''s Association, 1993, Vol.19, No.3, pp.45-69
    31.李紅英, “稀土功能材料:新材料與應用技術叢書”, 曉園出版社, 2006, pp.1-18
    32.王震東, “稀土元素的特性及其對電熱合金性質的影響”, 機械技術月刊, 1997, pp.124-133
    33.W. U. Meixia, “Progress Research of Novel Rare Earth Function Materials”, Journal of Shanxi Radio and TV University, 2005, No.5, pp.106-107
    34.W. Y. Zhang, “Applications of Rare-Earch Magnetostrictive Materials”, Metallic Functional Materials, 2004, Vol.11, No.4, pp.42-46
    35.Y. A. Zhang, “Manufacture Technology of Rare Earth Permanent Magnet Low Speed Synchronous Motor”, Production Technology, 2006, No.1, pp.5-8
    36.G. D. Li, “New Progress of Research of Metallic Magnetic Functional Materials in 2003-2004”, Metallic Functional Materials, 2005, Vol.12, No.5, pp.37-39
    37.J. L. Zhang, G. Y. Hong, “Progress on the Study of Nanoscale Rare Earth Luminescent Materials”, Chinese Journal of Luminescence, 2005, Vol.26, No.3, pp.285-293
    38.V. V. Jhn, K. Fa, et al., “Philips Res Reports”,1970,Vol.25 ,p.133
    39.曲遠方, “儲氫材料:新材料與應用技術叢書”, 曉園出版社, 2006, pp.45-91
    40.G. D. Zhang, Z. Huang and D. L. Duan, “Investigation on the Effect of Rare-Earth Catalytic Converter on Purification for Automotive Exhaust”, Journal of Shanghai Jiaotong University, 2000, Vol.34, No.9, pp.1215-1219
    41.Q. Jlang, X. Z. Li, Z. Q. Gao, “Research Progress of the Application of Rare Earth in Catalysts”, Journal of Xinyang Normal University, 2005, Vol.18, No.4, pp.467-470
    42.C. M. Lu, Q. C. Sun, M. X. Xu, Y. F. Luo, “Study on Properties of PMSZT Piezoelectric Ceramics”, Journal of Materials Engineering, 2005, Vol.12, pp.48-52
    43.S. C. Yu, S. Q. Wu, J. Q. Yan, Y. J. Gong, Y. S. Gong, M. S. Lian, G. Ye, Y. J. Cheng, H. S. Ke, D. J. Zhai, “Influence of Rare Earth on Microstructure and Mechanical Properties of 21-4N Steel”, Materials for Mechanical Engineering, 2005, Vol.29, No.6, pp.33-36
    44.J. W. Shyu, C. L. Sheu, “The Application of Rare Earth Element in Cast Alloy (Ⅱ) ”, Journal of Chinese Foundrymen''s Association, 1993, Vol.19, No.4, pp.28-44
    45.X. T. Guo, P. J. Li, Y. H. Xiong, S. X. Liu and D. B. Zeng, “Application of Rare Earth in Aluminum and Magnesium Alloys”, Journal of Materials Engineering, 2004, No.8, pp.60-64
    46.D. Q. Wang, Q. L. Wang, “Effects of Rare Earth Additions on the As-Cast Microstructure and the Mechanical Properties of AlZnMgCu Alloy”, Special Casting & Nonferrous Alloys, 1998, No.6, pp.3-6
    47.Y. Xu, X. B. Li, W. X. Yu, Z. D. Zhao, Y. H. Liu, J. Q. Zhang, “Effects of Rare Earth on Mechanical Properties and Stress Corrosion Behavior of Al-Zn-Mg Alloy”, Journal of Jilin University, 2003, Vol.41, No.4, pp.506-509
    48.B. D. Sun, K. Li, J. Wang, Y. H. Zhou, “Effects of La and Y on Hypereutectic Al-Si Alloy”, Journal of Shanghai Jiaotong University, 1999, Vol.33, No.7, pp.795-798
    49.A. R. Daud, Karen M. C. Wong, “The Effect of Cerium Additions on Dent Resistance of Al-0.5Mg-1.2Si-0.25Fe Alloy for Automotive Body Sheets” Materials Letters, 2004, Vol.58, pp.2545-2547
    50.M. Liang, Z. Xiulin, T. Li , “Effect of Alkali Metal Impurities and Cerium Modification on The Fatigue Behaviour of 8090 Alloy Sheets” Materials Science and Engineering A, 1995, Vol.196, pp.191-196
    51.J. H. Jun, J. M. Kim, K. D. Seong, K. T. Kim, W. J. Jung, “Enhanced Mechanical Properties of A206 Aluminum Casting Alloy By Addition of Rare Earth Elements” Materials Science Forum, 2005, Vol.475-479, pp.441-444
    52.“ASTM E112-88”, Annual Book of ASTM Standards, 1990, Vol.03.01
    53.“ASTM B557M-81”, Annual Book of ASTM Standards, 1991, Vol.03.01
    54.A. K. Mukhopadhyay, “On the Nature of the Second Phase Particles Present in an As-Cast Al-Cu-Mg-Ag Alloy”, Scripta Materialia, 1999, Vol.41, pp.667-672
    55.A. K. Mukhopadhyay, “Compositional Characterization of Cu-Rich Phase Particles Present in As-Cast Al-Cu-Mg-(Li) Alloys Containing Ag”, Metallurgical and Materials Transactions A, 1999, Vol.30A, pp.1693-1704
    56.劉國雄, 林樹均, 李勝隆, 鄭晃忠, 葉均蔚, “工程材料科學”, 全華科技圖書股份有限公司, 1999, pp.399-432

    QR CODE
    :::