| 研究生: |
周德瑜 Der-Yu Chou |
|---|---|
| 論文名稱: |
四氯化鈦之控制水解研究 |
| 指導教授: |
蔣孝澈
A.S.T. Chiang |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程與材料工程學系 Department of Chemical & Materials Engineering |
| 畢業學年度: | 89 |
| 語文別: | 中文 |
| 論文頁數: | 63 |
| 中文關鍵詞: | 氧化鈦 、四氯化鈦 |
| 相關次數: | 點閱:9 下載:0 |
| 分享至: |
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本研究主要目的有二:首先,以四氯化鈦為原料製備出粒子粒徑介於20∼50nm、具有結晶性之氧化鈦穩定懸浮溶液。其次,將上述氧化鈦粒子添加有機界面劑,避免粒子聚集。
我們以共沈澱法於酸性的環境下(pH=1.5)合成氫氧化鈦溶膠。經去離子水洗除溶膠中大部分的離子後,再以適當的酸量解膠。所產生氫氧化鈦可以較少量的酸達到解膠的目的。我們還比較了不同老化時間、解膠溫度、解膠時溶液酸鹼值對最後氫氧化鈦粒子大小之影響。於酸性環境下滴定合成的氫氧化鈦,只需添加酸鈦比為0.2左右的酸量,使溶液酸鹼值約介於1.2∼1.5之間即可。於60℃加熱4小時內解膠即可製備出平均粒徑25nm的銳鈦礦(anatase)相氧化鈦結晶粒子。此時溶液本身成分為TiO2/HCl/H2O=1/0.196/44.27,氧化鈦固含量佔9.05wt﹪。
另外,於合成出之氧化鈦結晶懸浮液中添加有機酸等界面劑,能有效將表面改質而產生穩定之作用。氧化鈦粒子之界面電位隨著界面劑所帶有之羧基(-COOH)增加而增大。有機酸若只含一個羥基對氧化鈦粒子界面電位的影響並不大,但已足以造成立體屏障效應維持粒子的穩定懸浮。而雙酸或三酸對界面電位影響較大,但氧化鈦粒子卻有聚集現象發生。
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