| 研究生: |
何峻維 Jiun-wei Ho |
|---|---|
| 論文名稱: |
鋁奈米顆粒間交互作用對自發磁性之影響 Effects of interparticle interaction on spontaneous magnetism of Al nanoparticles |
| 指導教授: |
李文献
Wen-Hsien Li |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 物理學系 Department of Physics |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 66 |
| 中文關鍵詞: | 奈米粒子 、鋁 |
| 外文關鍵詞: | Al, nanoparticles |
| 相關次數: | 點閱:13 下載:0 |
| 分享至: |
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本實驗利用熱蒸鍍法製備奈米鋁微粒,在利用X 光繞峰形與原子力顯微鏡影像,判斷樣品的平均粒徑為10.1 奈米。並且由X 光繞射峰形也沒有發現氧化的繞射峰形。
為了探討鋁奈米微粒磁特性,我們對鋁奈米微粒進行ㄧ系列M-H量測,並利用朗之萬函數(Langevin function)加線性抗磁項來擬合磁化曲線。飽和磁化強度Ms,隨著溫度增加而變小的趨勢;平均微粒磁矩排列隨溫度增加,有呈現線性的趨勢,且隨著微粒間距減少,平均微粒磁矩有越來越小的趨勢。在溫度為55K時,CD5和CD6磁化強度與外加磁場關係圖中也觀察到類似反鐵磁性的蜂腰型磁滯現象。
An Al nanoparticle powder was fabricated by the thermal evaporation method.The mean particle diameter was determined to be 10.1 nm by the X-ray diffraction
profiles and the AFM images. No trace of oxidation may be found.
Magnetic properties were studied by magnetization measurement. The M-H curve may be described by a modified Langevin function plus a diamagnetic linear term. The results show that the saturation magnetization Ms decreases with increasing temperature, while the average particle moment μp increase with increasing temperature. It was found that μp decreases as the interparticle separation is decreased. A hysteresis loop was also found around 55 K.
[1] A. P. Sannino, H. J. Rack, “Dry sliding wear of discontinuously reinforcedaluminum composites : review and discussion”, Wear, 189,1995, pp.1-19.
[2] G. Timmermans, L. Froyen, “Fretting wear behaviour of
hypereutectic P/M Al-Si in oil enviroment”, Wear, 230, 1999,pp.105-117.
[3] R. S. Mottram, A. J. Williams, I. R. Harris,“Blending additions of aluminum and cobalt to Nd16Fe76B8 milled powder to produce sintered magnets”, Journal of Magnetism and Magnetic Materials,Vol.222, 2000, pp.305-313.
[4] O. Filip, A .M. El-Aziz, R. Hermann, K. Mummert, L. Schultz,“Effect of Al additives and annealing time on microstructure and corrosion resistance of Nd–Fe–B alloys”, Materials Letters, Vol.51,2001, pp.213–218.
[5] L. Schultz, A. M. El-Aziz, G. Barkleit, K. Mummert, “Corrosion behaviour of Nd–Fe–B permanent magnetic alloys”, Materials Science and Engineering A, Vol.267, 1999, pp.307–313.
[6] T. Teranishi, I. Kiyokawa, and M. Miyake, Adv.Mater. 10, 596(1998).
[7] H. Hori, T. Teranishi, Y. Nakae, Y. Seino, M.Miyake, and S. Yamada,Phys. Lett. A 263, 406(1999).
[8] W. –H. Li, S. Y. Wu, C. C. Yang, S. K. Lai, K. C.Lee, H. L .Huang,and H. D. Yang, Phys. Rev. Lett.89, 135504 (2002).
[9] Y. Yamamoto, T. Miura, M. Suzuki, N. Kawamura,H. Miyagawa, T.Nakamura, K. Kobayashi, T.Teranishi, and H. Hori, Phys. Rev. Lett.93,116801(2004).
[9] H. Hori, Y. Tamamoto, T. Iwamoto, T. Miura,T.Ternishi, and M .Miyake, Phys. Rev. B 69, 174411(2004).
[10] P. Crespo, R. Litrán, T. C. Rojas, M. Multigner, J. M.de la Fuente, J.C. Sánchez-López, M. A. García, A.Hernando, S. Penadés, and A.Fernández, Phys. Rev.Lett. 93, 087204 (2004).
[11] 羅吉宗、戴明鳳、林鴻明、鄭振宗、蘇程裕、吳育民著,奈米
科技導論,全華科技圖書股份有限公司。
[12] 盧希鵬、馬振基,“奈米材料技術地圖” ,國科會科學技術資料中心,P.4(2003)。
[13] A. Punnoose, H. Magnone, M. S. Seehra, Phys. Rev. B 65, 174420(2001)
[14] H. Hori, T. Teranishi, Y. Nakae, Y. Seino, M. Miyake, S. Yamada,“Anomalous magnetic polarization effect of Pd and Au nano-particles,” Phys. Lett. A 263 406 (1999)
[15] T. Shinohara and T. Sato, “Surface Ferromagnetism of Pd Fine Particles,” Phys. Rev. Lett. 91 197201 (2003)
[16] H. Hori, Y. Yamamoto, T. Iwamoto, T. Miura, T. Teranishi, and M. Miyake, “Diameter dependence of ferromagnetic spin moment in Au nanocrystals,” Phys. Rev. B 69 174411 (2004)
[17]Y. Yamamoto, T. Miura, M. Suzuki, N. Kawamura, H. Miyagawa, T. Nakamura, K. Kobayashi, T. Teranishi, and H. Hori, “Direct Observation of Ferromagnetic Spin Polarization in Gold Nanoparticles,” Phys. Rev. Lett 93, 116801 (2004)
[18] S. Y. Wu, and W. H. Li, “Observation of magnetic anomalous in Ag nanoparticles” (unpublish)
[19]郭正次 朝春光,“奈米結構材料科學" ,初版,全華科技圖書股份有限公司 (2004)
[20]王進威,“擬合X光繞射峰形判定奈米微粒粉末的粒徑分佈”,
中央大學碩士論文(2006)
[21]Neil W.Ashcroft and N.David Mermin,Solid State
Physics,P673 (Cornell University)
[22] Nicola A.Spaldin,MAGNETIC MATERIALS
[23] S. H. Kilcoyne, R. Cywinski, J. Magn. Magn. Mater. 140, 1446(1995)
[24] T. Shinohara and T. Sato, “Surface Ferromagnetism of Pd Fine Particles,”Phys. Rev. Lett. 91 197201 (2003)