| 研究生: |
陳桂芳 Kuei-Fang Chen |
|---|---|
| 論文名稱: |
MOCVD高溫加熱系統之熱擋板 數值分析與實作驗證 Numerical Analysis and Experiment verification for the Baffle of Heating system in a Very-High temperature MOCVD reactor |
| 指導教授: | 利定東 |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 光機電工程研究所 Graduate Institute of Opto-mechatronics Engineering |
| 論文出版年: | 2017 |
| 畢業學年度: | 105 |
| 語文別: | 中文 |
| 論文頁數: | 128 |
| 中文關鍵詞: | 高溫加熱系統 、盤面均溫 、金屬化學氣相沉積 |
| 相關次數: | 點閱:11 下載:0 |
| 分享至: |
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MOCVD為磊晶製程的重要設備,其利用高溫熱裂解的方式將有機金屬源與氨氣等斷鍵,使離子結合並堆積在基板上,與基板產生化學作用並吸附堆積形成薄膜,分子吸附堆積之情形受基板溫度的影響,藉而影響薄膜品質,使其光電元件效能、壽命有優劣之分。而溫度均勻性直接影響磊晶薄膜之品質,因此,本研究以自行搭建之高溫實驗腔體進行以數值分析法設計加熱系統之熱擋板,藉由數值分析之結果再與升溫實驗進行驗證。下列為針對之參數分析
(1) 加熱系統對載盤盤面溫度分佈
(2) 加熱器與熱擋板對於載盤盤面之溫度影響
(3) 載盤厚度差異對盤面溫度分佈之影響
以數值分析結果得知盤面溫度分佈,晶圓區平均溫度差為4.35oC,最大標準差為1.53。針對載盤盤面晶圓區溫度之分佈情形,在載盤厚度減小時,載盤整體溫度差增加,因此厚度10mm載盤之溫度均勻性較其他優良。比較數值分析結果與升溫實驗結果,將兩層側邊熱擋板增設置自行建立之高溫腔體中,進行升溫實驗比對,載盤盤面晶圓區位置之溫度誤差最大值1.2 %,最小值小於0.1 %,由數值分析可知改善溫晶圓區之U型溫度分佈,實際升溫實驗後得知結果是可以利用數值分析法被預期的。
Metal Organic Chemical Vapor Deposition (MOCVD) is used for growing the epitaxy thin film, which usually can be divided into five sub-systems, (a) injecting system, (b) vacuum chamber, (c) heating system, (d) exhausting system and (e) control system. The processing condition of a MOCVD requires a high temperature to deposit epitaxy thin film, and the target temperature is higher than 1200oC at the heating system. So the temperature uniformity of the wafer area on susceptor is an important key for qualifying and performance of thin film process. As a result, this research focuses on the heating system of a MOCVD vacuum reactor. The numerical analysis is used to simulate the temperature distribution on the surface of susceptor in a very-high temperature vacuum reactor. The heating baffle is added to heating system not only below the heater but also around the susceptor and heater. This very-high temperature vacuum reactor is a home-made reactor in which size is six pieces of two-inch wafers can be placed, and the thermocouple on the surface of susceptor is used for the temperature measurement.
The heating baffle affects the thermal radiation distribution, and the temperature uniformity is progressive on the surface of susceptor. In the numerical analysis result, the temperature difference is 4.35oC at the wafer, and the standard deviation maximum is 1.53 while the heating baffle is added to the very-high temperature vacuum reactor and the thickness of susceptor is 10mm. When the two-tier heating baffle is added to heating system, to compare the results in simulation with experiments, the maximum 1.2% and the minimum 0.1% can be obtained for temperature difference of the wafer on the susceptor surface.
[1] 中華民國光電學會著,LED工程師基礎概念與應用,五南圖書出版股份有限公司,臺北市,2012年4月。
[2] 呂紹旭,「紫外光LED晶粒產業現況」,光連雙月刊,2012年1月,第29-30頁。
[3] 郭子菱,MOCVD設備發展現況與趨勢,Industrial Economics & Knowledge Center,pp.1-7,2012年。
[4] 方志烈編著,半導體照明技術,電子工業出版社,北京,2009年5月。
[5] Shuji Nakamura, Masayuki Senoh, and Takashi Mukai, “Highly P-Typed Mg-Doped GaN Films Grown with GaN Buffer Layers,” Jpn. J. Appl. Phys., vol. 30, 1991, pp. L1708-L1711.
[6] Shuji Nakamura, “GaN Growth Using GaN Buffer Layers,” Jpn. J. Appl. Phys., vol. 30, 1991, pp. L1705-L1707.
[7] 蘇石川,孔為,陳代芬,韓雷濤編著,熱能工程與先進能源技術仿真設計,化學工業出版社,北京,2014年12月。
[8] 葛志祥,孫永慶,徐吉浣,「傘型紅外線輻射採暖器反射罩的研究」,煤氣與熱力,2001年,06期。
[9] 詹少彬,「MOCVD加熱系統研究」,中國武漢,華中科技大學,碩士論文,2008年。
[10] D. Fahle, H. Behmenburg, C. Mauder, et al, “Growth of GaN in a planetary MOCVD hotwall system,” Journal of Physics Status Solid, 2011, Vol. 8, pp. 2041-2043.
[11] Yinglu Hu, Peixian Li, Zhiming Li, Limin Wu, Hongcai Liu, Dingwei Li, Junchun Bai, “Simulation and Analysis of Temperature Modulate Curve in MOCVD with the Chipped Intrared Heating System,” Electronic Sci. & Tech., 2012, Vol. 25, pp. 108-111.
[12] 邱顯智,「以數值分析法優化MOCVD高溫反應腔體之加熱系統暨實作驗證」,台灣,國立中央大學,碩士論文,民國104年。
[13] 郭勃亨,「雙加熱器有機金屬化學氣相沉積系統上下加熱板溫度對氮化銦鎵薄膜成長研究」,台灣,國立交通大學,碩士論文,民國101年。
[14] Long-quan Xu, Song Fang, Zi-han Tang, Xin-wei Liu, ”Research on Heating Uniformity of MOCVD Heating Device,” Chinese Journal of Luminescsnce, 2017, Vol. 38, No. 2, pp. 220-225.
[15] Yiren Chen, Hang Song, Dabing Li, Xiaojuan Sun, Hong Jiang, Zhiming Li, Guoqing Miao, Zhiwei Zhang, and Yue Zhou, “Influence of the growth temperature of AlN nucleation layer on AlN template grown by high-temperature MOCVD,” Materials Letters, 114 (2014), pp. 26-28.
[16] Michael Quirk‧Julian Serda,Semiconductor Manufacturing Technology,羅文雄、蔡榮輝、鄭岫盈譯,半導體製造技術,台灣培生教育出版股份有限公司,台北,2016年7月。
[17] 伍秀菁、汪若文和林美吟主編,真空技術與應用,財團法人國家實驗研究院儀器科技研究中心,新竹市,民國九十年七月。
[18] 胡智愷,「大尺寸金屬有機化學氣相沉積反應腔體之數值分析模擬研究」,國立中央大學,碩士論文,民國101年。
[19] C. Ratsch, J. Garcia, and R. E. Caflisch,”Influence of edge diffusion on the growth mode on vicinal surfaces,” Appl. Phys. Lett. 87, 141901(2005).
[20] 莊達人,VLSI製造技術,第六版,高立圖書有限公司,2013。
[21] 陳玄宗,「以磁場模擬法設計磁鐵排列改善濺鍍機台之填洞能力」,國立中央大學,碩士論文,民國100年。
[22] SEMATECH, ”Deposition Processes,” in Furnace Processes and Related Topics (Austin, TX: SEMATECH, 1994), p.6.
[23] Zhang X., Moerman I., Sys C., et al, ” Highly uniform AlGaAs/GaAs and InGaAs(P)/InP structure grown in a multiwafer vertical rotating susceptor MOVPE reactor,” Journal of Crystal growth, Vol.170, pp.83-87, 1997.
[24] Yang Liu, Takashi Egawa, Hiroyasu Ishikawa, Baijun Zhang, and Maosheng Hao,”Influence of Growth Temperature on Quaternary AlInGaN Epilayers for Ultraviolet Emission Grown by Meralorganic Chemical Vapor Deposition,” Jpn. J. Appl. Phys., vol. 43, 2004, pp. 241-2418.
[25] 陸大成,段樹坤,金屬有機化合物氣相外延基礎及應用,中國科學院科學出版,北京,2009年5月。
[26] Kish F A, Fletcher R M, AlGaInP light emitting// Stringfellow Gb, Craford M G, high brightnedd light emitting diodes: SEMICONDUCTORS AND Semimetal. Academic Press, 1997, 48: Chap. 5.
[27] Kizhayev S S, et al, “Powerful InAsSbP/InAsSb light emitting diodes grown by MOVPE,” J. Crystal Growth, 2003, 248, pp. 296-300.
[28] 張政彬,「以數值分析法優化MOCVD高溫反應腔體之二段加熱系統暨實作驗證」,台灣,國立中央大學,碩士論文,民國105年。
[29] M. Dauelsberg, C. Martin, H. Protzmann et al, “Modeling and process design of III-nitride MOVPE at near-atmospheric pressure in close coupled showerhead and planetary reactors,” Journal of Crystal Growth, Vol. 298, pp. 418-424, 2007.
[30] 詹少彬,mocvd加熱系統研究,中國,華中科技大學,碩士論文,2008年
[31] Li Zhi-Ming, Jiang Hai-Ying, Han Yan-Bin, Li Jin-Ping, Yin Jian-Qin, Zhang Jin-Cheng, “Temperature Uniformity of Wafer on a Large-Sized Susceptor for a Nitride Vertical MOCVD Reactor,” CHIN. PHYS. LEET., Vol. 29, No. 3(2012)030701, pp. 030701-1-030701-4.
[32] M. Dauelsberg, E. J. Thrush, B. Schineller and J. Kaeppeler, “Technology of MOVPE Production Tools,” Elsevier Ltd, 2004.
[33] D. G. Zhao, J. J. Zhu, D. S. Jiang et al., “Parasitic reaction and its effect on the growth rate of AlN by metalorganic chemical vapor deposition,” Journal of Crystal Growth, Vol. 289, pp.72-75, 2006.
[34] R. Loganathan, M. Balaji, K. Prabakaran, R. Ramesh, M. Jayasakthu. P. Arivazhagan, Shubra Singh, K. Baskr, “The effect of growth temperature on structural quality of AlInGaN/AlN/GaN heterostructures grown by MOCVD,” J Mater Sci: Mater Electron, 26, 2015. pp. 5373-5380.
[35] H. W. Jackson, J. L. Watkins, S. Chung et al., “Conductive sphere in a radio frequency filed: Theoty and applications to postitioners, heating, and noncontact measurements,” J. Appl. Phys., Vol. 79, pp. 3370-3384, 1996.
[36] T. Murakami, Y. Okuno, and H. Yamasaki, “Performance of rf-assisted magnetohydrodynamics power generator,” Physics of Plasmas, Vol. 12, pp. 113503-1~113503-8, 2005.
[37] L. M. Kaufmann, F. Heuken, M. R. Tilders, et al., “Safety aspects of MOVPE in research and development: a example,” Journal of Crystal Growth, Vol. 93, pp. 279-284, 1988.
[38] 林義鈞,「最佳化設計金屬有機化學氣相沉積高溫加熱系統數值分析研究」,台灣,國立中央大學,碩士論文,民國102年。
[39] B. Harris, University Physics, Ver. 2, John Wiley & Sons Inc, USA, 1995.
[40] Y. A. Cengel, Heat and mass transfer, McGraw-Hill Eduactuin(Asia), Third Edition, Singapore, 2006.
[41] J. P. Holman,HEAT TRANSFER,胡凡勳,朱朝煌,邱漢傑,第10版,熱傳遞學,高立圖書有限公司,台北市,2011年01月。
[42] 白長城,張海興,方湖寶,高等學校教材紅外物理,電子工業出版社,北京,1989年。
[43] 王勖成,有限單元法,清華大學出版社,北京,2003年七月。