本研究利用揮發性有機物（Volatile organic compounds，VOCs）自動採樣設備，24小時監測某工業區周界揮發性有機物濃度、風速、風向、溫度及濕度等項目，同時當VOCs監測濃度較高時，自動觸發鋼瓶採樣分析污染物濃度，並運用異味活性值(Odor activity value，OAV)及權重分析結果，評估異味污染物來源及其污染指紋，期進一步勾稽比對異味污染來源，並作為環保機關稽查管制之參考依據。
本研究以苗栗縣高異味污染陳情之頭份工業區為研究對象，該工業區有高異味污染之虞的工廠，計有H公司頭份廠(塑膠品製造業)、C公司頭份廠(化學材料製造業)、F公司(紡織業)、T公司頭份廠(化學材料製造業)、O公司(化學材料製造業)、S公司(化學材料製造業)及V公司(化學材料製造業)等7家。研究結果顯示，監測期間共觸發5次自動採樣，分析結果有62種污染物，主要污染物為甲苯(9.88 ppb )、間對-二甲苯(2.64 ppb )、順式-1,2-二氯乙烯(2.56 ppb )、乙烷(2.26 ppb )及氯乙烯(1.92 ppb )等污染物，係屬該工業區之污染指紋。另以異味活性值分析之結果可知，甲苯（OAV = 0.706）、間對-二甲苯（OAV = 0.033）、正丙苯（OAV = 0.023）、異丙苯（OAV = 0.018）及異丁醛（OAV = 0.014）有較高之異味情形，可視為該工業區之異味污染指紋。另根據權重分析比對結果，氯乙烯、甲苯、苯、二氯甲烷及丙烯腈等污染物，為該工業區應優先管制之污染物。比對相關工廠原物料清冊結果，H公司頭份廠應加強管制甲苯及氯乙烯，C公司頭份廠及T公司頭份廠亦須加強管制甲苯，至於二氯甲烷及丙烯腈等污染物尚無比對出對應之污染來源。根據本研究初步建立監測採樣之方法，應可提供後續環保機關對於空氣污染物管制工作之參考，並藉以提升稽查管制之效能。

This study investigates that monitoring the concentrations of volatile organic compounds(VOCs), wind speed, wind direction, temperature and humidity in a industrial area for 24 hours by volatile organic compounds automatic sampling equipment. When the VOCs monitoring concentration is higher than alarm value, automatic trigger cylinder sampling will start to analysis of pollutant concentration. The odor activity value (OAV) and weight analysis method were discussed. To establish the pollutants sources, fingerprints and provide reference information for inspection control by Environmental Protection Bureau local government were also major objectives of this research.
This research is based on the high-odor pollution of Toufen industrial zone in Miaoli County. The industrial zone has the highly potential for odor pollutants emissions factory, including the H company (plastic products manufacturing), the C company (chemical materials manufacturing), F Company (textile industry), T Company (chemical materials manufacturing), O Company (chemical materials manufacturing), S Company (chemical materials manufacturing), and V Company (chemical materials manufacturing). The results of the study showed that 5 automatic samplings were triggered and 62 pollutants were analyzed during the monitoring period. The main pollutants were toluene (9.88 ppb), meta-xylene (2.64 ppb), cis-1,2-dichloroethylene (2.56 ppb), ethane (2.26 ppb) and vinyl chloride (1.92 ppb). These pollutants represented and matched the pollution fingerprints of this Toufen industrial zone. According to the analysis results of odor activity value, it obviously showed that toluene (OAV = 0.706), m-xylene (OAV = 0.033), n-propylbenzene (OAV = 0.023), cumene (OAV = 0.018) and isobutyraldehyde (OAV = 0.014) have a highly potential for odor emission. And these pollutants could be regarded as the odor pollution fingerprints of the Toufen industrial zone. Based on the results of weight analysis comparison, the pollutants, such as vinyl chloride, toluene, benzene, methylene chloride and acrylonitrile, should be preferentially controlled in the Toufen industrial zone. The results of the comparison with the raw materials data, H, C, and T company should strengthen the control of toluene and vinyl chloride respectively. However, methylene chloride and acrylonitrile were also still needed to compare and figure out the corresponding pollution emission sources.
According to the results of this study, the automatic sampling technology of volatile organic compounds could be used as a model for the controlling of air pollutants by Environmental Protection Bureau of local government, and also could improve the effectiveness of audit control.

AIHA,(1989)Odor Thresholds for Chemicals with Established Occupational Health Standards.
Capelli, L., Sironi, S., Del Rosso, R., & Guillot, J.-M. (2013). Measuring odours in the environment vs. dispersion modelling: A review. Atmospheric Environment, 79, 731-743
Cetin E., Odabasi M., Seyfioglu R.,( 2003) Ambient volatile organic a petrochemical (VOC) concentrations around compound complex and a petroleum refinery. Science of the Total Environment 312, 103-112.
Cheng, W.-H., Hsu, S.-K., & Chou, M.-S. (2008). Volatile organic compound emissions from wastewater treatment plants in Taiwan: Legal regulations and costs of control. Journal of Environmental Management,88(4),1485-1494.
Gardner J W, Bartlet P N,(1994) A brief history of electronic nose [J]. Sensors and Actuators B,(18/19)：211-220.
Jelen,H.H.,Majcher,M.,Zawirska-Wiewiorowska,M.,Wasowicz,E.,(2003)Determination of geosmin, 2-methylisoborneol, and a musty-earthy odor in wheat by SPME-GC-MS,profiling volatiles,and sensory analysis.J Agr Food Chem,51(24),7079-7085.
Lee, H.-D., Jeon, S.-B., Choi, W.-J., Lee, S.-S., Lee, M.-H., & Oh, K.-J. (2013). A novel assessment of odor sources using instrumental analysis combined with resident monitoring records for an industrial area in Korea. Atmospheric Environment, 74, 277-290.
Li, G., Wei, W., Shao, X., Nie, L., Wang, H., Yan, X., & Zhang, R. (2017). A comprehensive classification method for VOC emission sources to tackle air pollution based on VOC species reactivity and emission amounts. Journal of Environmental Sciences, 67, 78-88.
Lin T.-Y., Sree U., Tseng S.-H., Chiu K. H., Wu C.-H., Lo J.-G., (2004) Volatile organic compound concentrations in ambient air of Kaohsiung petroleum refinery in Taiwan.Atmos Environ 38, 4111-4122.
Loriato A., Salvador N., Santos J., Moreira D.M., Costa Junior N. (2012). Odour - A Vision On The Existing Regulation. Chemical Enginnering Transaction VOL. 30
Monod, A., Sive, B. C., Avino, P., Chen, T., Blake, D. R., & Sherwood Rowland, F. (2001). Monoaromatic compounds in ambient air of various cities: a focus on correlations between the xylenes and ethylbenzene. Atmospheric Environment, 35(1), 135-149.
Padhi, S. K., & Gokhale, S. (2014). Biological oxidation of gaseous VOCs – rotating biological contactor a promising and eco-friendly technique. Journal of Environmental Chemical Engineering, 2(4), 2085-2102.
Raysoni, A. U., Stock, T. H., Sarnat, J. A., Chavez, M. C., Sarnat, S. E., Montoya, T., Li, W.-W. (2017). Evaluation of VOC concentrations in indoor and outdoor microenvironments at near-road schools. Environmental Pollution, 231, 681-693.
Stuetz R.,(1998)Electronic nose：A new tool in odor management [J]. Water Quality Index,(7/8)：112-116.
Su, Y.-C., Chen, S.-P., Tong, Y.-H., Fan, C.-L., Chen, W.-H., Wang, J.-L., & Chang, J. S. (2016). Assessment of regional influence from a petrochemical complex by modeling and fingerprint analysis of volatile organic compounds (VOCs). Atmospheric Environment, 141(Supplement C), 394-407.
Wu, C., Liu, J., Yan, L., Chen, H., Shao, H., & Meng, T. (2015). Assessment of odor activity value coefficient and odor contribution based on binary interaction effects in waste disposal plant. Atmospheric Environment, 103, 231-237.
Wu, C., Liu, J., Zhao, P., Piringer, M., & Schauberger, G. (2016). Conversion of the chemical concentration of odorous mixtures into odour concentration and odour intensity: A comparison of methods. Atmospheric Environment, 127, 283-292.
Zhang,Q.T. , Wang,P. , Li,J.P. , Gao, X. G. , (2000) Diagnosis of diabetes by image detection of breath using usung gas-sensitive laps. Biosens Bioelectron,15(5-6),249-256.
行政院環保署「空氣品質標準」，(2004)。
行政院環保署固定污染源管理資訊系統，（2018）。
行政院環境保護署環保報案中心公害陳情案件管理系統， http：//ww3.epa.gov.tw/，(2018)。
行政院環境保護署譯「惡臭防制技術參考手冊(I-IV)」，(1988)。
李中光「淺談煉油廠惡臭污染防治」，http://setsg.ev.ncu.edu.tw/newsletter/epnews7-2-3.html
李秉燦「工業區異味污染物來源調查與改善以臺中工業區為例」，國立中興大學碩士論文(2014)。
林忠霆「南部某工業區大氣中揮發性有機物時空特徵調查」，國立中山大學碩士論文(2014)。
邱郁凱「工業區氣味化合物分析及降解技術」，國立清華大學博士論文(2009)。
金繼武「運用揮發性有機物異味威脅值評估工業區污染排放特徵及異味陳情案件污染來源之研究」，國立聯合大學碩士論文(2012)。
洪銘宏「運用開徑式傅立葉轉換紅外光譜儀判定工業區揮發性有機物來源」，國立中山大學碩士論文(2016)。
苗栗縣政府環保局「105年度苗栗縣石化業揮發性有機物稽查管制計畫期末報告」(2016)。
苗栗縣政府環保局「105年度苗栗縣固定污染源許可審查及稽查管制計畫期末報告」(2016)。
苗栗縣政府環保局「106年度苗栗縣石化業揮發性有機物稽查管制計畫期末報告」(2017)。
苗栗縣政府環保局「106年度苗栗縣固定污染源許可審查及稽查管制計畫期末報告」(2017)。
國家衛生研究院國家環境毒物研究中心，http://nehrc.nhri.org.tw/toxic/toxfaq.php，(2018)。
陳清涼「空氣中VOC分析及其在石化廠的應用」，國立雲林科技大學博士論文(2005)。
陳揚桓「南部某工業園區空氣品質與異味調查」，國立中山大學碩士論文(2014)。
曾文興「石化工業區逸散污染源臭味排放特性及影響」，國立台灣大學環境工程學研究所碩士論文(1998)。
臺中市政府環保局「102年中部科學工業園區空氣污染物稽查管制計畫期末報告」(2013)
臺中市政府環保局「103年臺中市空氣品質資訊服務及中部科學工業園區空氣污染物稽查管制計畫期末報告」(2014)
劉巧蓮「大社石化工業區臭味特徵成分分析研究」，國立成功大學環境工程學系碩士論文(2004)。
劉至中「石化工業區空氣中揮發性有機物與含硫異味物質季節變化趨勢及污染源排放特徵之相關性分析」，國立中山大學碩士論文(2012)。
謝明錚「揮發性有機物排放源之指紋建置研究」，朝陽科技大學碩士論文(2011)。
行政院環境保護署「固定污染源空氣污染物排放標準」，(2011)。
行政院環境保護署「固定污染源設置與操作許可證管理辦法」，(2007)。
行政院環境保護署「空氣中揮發性有機化合物檢測方法－不銹鋼採樣桶/氣相層析質譜儀法」，環境檢驗所空氣類標準檢測方法NIEA A715.14B(2011)。
行政院環境保護署「空氣污染行為管制執行準則」，(2002)。
行政院環境保護署「空氣污染防制法」，(2011)。
行政院環境保護署「空氣污染防制法施行細則」，(2003)。
行政院環境保護署「從事烹飪將烹飪廢氣逕行排放至溝渠中，致產生油煙或惡臭者，為空氣污染行為」，(2007)。
行政院環境保護署「異味污染物官能測定法—三點比較式嗅袋法」，環境檢驗所空氣類標準檢測方法NIEA A201.14A (2011)。
行政院環境保護署「異味污染物為空氣污染物」，(2007)。
行政院環境保護署「揮發性有機物空氣污染管制及排放標準」，(2011)。