跳到主要內容

簡易檢索 / 詳目顯示

回結果列表
研究生： 彭志剛
Zh-Gang Peng
論文名稱： 以電漿處理聚四乙烯表面改質之研究
指導教授： 徐新興
Shin-Shing Shyu
口試委員:
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程與材料工程學系
Department of Chemical & Materials Engineering
畢業學年度： 89
語文別： 中文
論文頁數： 79
中文關鍵詞： 雙馬來醯亞胺 、聚四氟乙烯 、電漿
外文關鍵詞： plasma, BMI, PTFE
相關次數： 點閱：6  下載：0 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

    • 本研究是以氨氣、氮氣等氣體無線電波電漿對聚四氟乙烯（PTFE）樹脂進行表面處理，之後在經由雙馬來醯亞胺（BMI）單體行接枝聚合反應，以探討PTFE及BMI樹脂介面黏著性質。處理之後的PTFE表面形態、化學組成及官能基可以SEM、FTIR-ATR、及ESCA加以分析。由ESCA的結果顯示，在短時間電漿處理下即有明顯的去氟效應及氮元素的形成；且在相同的氣體電漿處理條件下，氨氣（NH3）電漿會有較強的蝕刻效應，又兩個不同氣體的電漿處理其表面氮元素的鍵結方式亦不同。在接觸角的測試中，發現短暫的電漿處理即可使PTFE表面能增加，潤濕性變好。之後的BMI單體接枝反應，會隨著處理條件的不同接枝效果亦會受影響。PTFE與BMI間的黏著性質可由lap shear strength測試中知道，當經過電漿處理之PTFE，其lap shear strength會有明顯的增加。

    Surface modifications of poly(tetrafluoroethylene) (PTFE) films by radio-frequency gas (ammonia, nitrogen)plasma treatment as well as by graft copolymerization of the plasma-pretreated films with bismaleimide(BMI) has been carried out. After these treatments, the changes in the film topography, chemical compositions of the PTFE films surface, and the surface functional groups introduced to the surface of PTFE films were identified by SEM, FTIR-ATR, and ESCA. ESCA results shows that mild plasma treatment is sufficient to cause substantial surface defluorination and introduction of nitrogen containing group. Under similar experimental conditions, the NH3 plasma strongly etches onto PTFE surface. And it shows that nitrogen chemical bonding form is different with different gas plasma treatment. Contact angle measurements reveal that the surface energy of the PTFE film is considerably enhanced by the surface mild gas plasma treatment. The concentration of the surface-grafted BMI polymer increases with the plasma pretreatment condition. The lap shear strength between the PTFE film and BMI resin was remarkably improved by gas plasma treatment.

    目 錄 中文摘要 英文摘要 表目錄 圖目錄 第一章 緒論………………………………………………………. 1 第二章 文獻參考…………………………………………….…. 5 2.1聚四氟乙烯（PTFE）的性質…………………………………………… 5 2.2雙馬來醯亞胺樹脂（BMI）…………………………………………….. 8 2.3電漿………………………………………………………………………. 9 2.4 PTFE表面處理……………………………………………………….…. 15 2.5表面分析…………………………………………………………………. 17 2.6介面黏著理論……………………………………………………………. 20 第三章 實驗………………………………………………………. 24 3.1實驗目的…………………………………………………………………. 24 3.2材料與藥品………………………………………………………………. 26 3.3儀器設備…………………………………………………………………. 27 3.4實驗步驟…………………………………………………………………28 3.4.1聚四氟乙烯（PTFE）前處理…………………………………………. 28 3.4.2氣體電漿處理……………………………………………………….…. 28 3.4.3雙馬來醯亞胺單體（BMI）接枝共聚合反應……………………….. 30 3.4.4掃瞄式電子顯微鏡分析（SEM）……………………………………... 30 3.4.5霍氏全反射紅外線光譜分析（FTIR-ATR）………………………….. 30 3.4.6電子化學元素光譜分析（ESCA）…………………………………..… 30 3.4.7表面接觸角測試…………………………………………………….…. 31 3.4.8微量天平之量測…………………………………………………….…. 31 3.4.9 Lap shear strength測試………………………………………………... 31 第四章 結果與討論……………………………………………. 33 4.1 SEM表面形態分析……………………………………………………... 33 4.2 FTIR-ATR光譜定性分析…………………………………………….…. 33 4.3化學分析電子儀（ESCA）……………………………………………..38 4.3.1 ESCA之掃瞄譜圖定性分析……………………………………….…. 47 4.3.2 ESCA之掃瞄譜圖半定量分析…………………………………….…. 50 4.4接觸角分析……………………………………………………………….61 4.4.1經BMI接枝與未接枝之PTFE表面水接觸角變化…………………. 61 4.4.2經過不同氣體電漿處理之PTFE表面自由能改變情形…………….. 64 4.5整體重量分析……………………………………………………………. 65 4.6 Lap shear strength測試……………………………………………….…. 67 第五章 結論………………………………………………………. 73 Reference………………………………………………………………... 75

    1. K. L. Berry and J. H. Peterson, J. Am. Chem. Soc., 73, p.5195(1951)
    .
    2. T. Suwa, M.Takehisa and S. Machi, J. Appl. Polym. Sci., 17, p.3253(1973).
    3. C. W. Bunn, J. Polym. Sci., 16, p.332(1955).
    4. K. N. Vinan, K. Krishnan and J. Mathew, J. Appl. Polym. Sci., 32, p.6033(1986).
    5. F. Grundschober, J. Sambeth, U. S. Par 3, 380, p.964(1986).
    6. D. Wilson, H. D. Stenzenberger, “Polyimide”, New York(1990).
    7. R. C. P. Cubbon, Polymer, 6, p.419(1965).
    8. H. D. Stenzenberger and M. Herzog, 30th Nat. SAMPE Symp., 30, p.1568(1985).
    9. H. D. Stenzenberger, P. Koing, and W. Romer, 29th Nat. SAMPE Symp., 29, p.1043(1984).
    10. J. King, M. Chaudhari, and S. Zahir, 29th Nat. SAMPE Symp., 29, p.392(1984).
    11. H. V. Boenig, “Plasma Science and Technology”, Cornell University Press, New York, 1982.
    12. D. T. Clark, A. Dilks, and D. Shuttleworth, D. T. Clark and W. J. Feast (Eds.), John Wiley, New York, 1987, p.185.
    13. A. T. Bell, J. R. Hollahan and A. T. Bell (Eds.), John Wiley, New York, 1974, p.1.
    14. M. Hudis, J. R. Hollahan and A. T. Bell (Eds.), John Wiley, New York, 1974, p.113.
    15. M. Shen and A. T. Bell, A. T. Bell (Eds.), ACS Symposium Series 108, 1979, p.1.
    16. H. Yasuda, M. Shen (Eds.), Marcel Dekker, New York, 1976, p.15.
    17. E. M. Liston, J. Adhesion, 30, p.199(1989).
    18. M. Son, B. Hu, Y. Wu, Y. Tang, W. Huang, and Y. Da, Composite Sci. Technol., 34, 353(1989).
    19. S. V. Gangal, in: Encyclopedia of Polymer Science and Engineering, J. I. Kroschwitz(Eds.), Vol. 16. Wiley, New York(1989).
    20. A. Celerier and J. Machet, Thin Solid Films, 148, p.323(1987).
    21. I. Mathieson, D. M. Brewis, I. Sutherland and R. A. Cayless, J. Adhesion, 46, p.49(1994).
    22. R. Rye, G. W. Arnold and A. J. Ricco, J. Electrochem. Soc., 140, p.3233(1993).
    23. 高振育, “PTFE表面改質之研究與應用”, 中原大學化學系博士論文, 民國八十七年六月。
    24. C. A. Costello and T. J. McCarthy, Macromolecules, 17, p.2940(1984).
    25. J. P. Badey, E. U. Espuche, Y. Jugnet, D. Sage, Tran Minh Duc and B. Chabert, Polymer, 35, p.2472(1994).
    26. D. T. Clark, D. R. Hutton, J. Polym. Sci.: A: Polym. Chem., 25, p.2643(1987).
    27. M. Kusabiraki, Jpn. J. Appl. Phys., 29, p.2809(1990).
    28. T. Hirotsu, S. Ohnishi, J. Adhesion, 11, p.57(1980).
    29. X. Xie, T. R. Gengenbach, H. J. Griesser, J. Adhesion Sci. Technol., 6, p.1411(1992).
    30. K. L. Tan, L. L. Woon, H. K. Wong, E. T. Kang, K. G. Neoh, Macromolecules, 26, p.2832(1993).
    31. R. Winter, D. Korzec, N. Sprang, D. Theirich, J. Engemann, Surf. Coat. Technol., 74/75, p.618(1995).
    32. T. R. Gengenbach, X. Xie, R. C. Chatelier, H. J. Griesser, J.Adhesion Sci. Technol., 8, p.305(1994).
    33. M. Charbonnier, M. Romand, M. Alami and Tran Minh Duc, Polymer Surface Modification: Relevance to Adhesion, 2, p.3(2000).
    34. M. Okoshi, M. Murahara and K. Toyota, J. Mater. Res., 7, p.1912(1992).
    35. N. Ichinose, M. Maruo, S. Kawanishi, Y. Izumi and T. Yamamoto, Chem. Lett., (1995)943.
    36. Hiroyuki Niino, Hiroaki Okano, Kazuyuki Inui and Akira Yabe, Appl. Surf. Sci., 109/110, p.259(1997) .
    37. K. L. Tan, L. L. Woon, H. K. Wong, E. T. Kang and K. G. Neoh, Macromolecules, 26, p.2832(1993).
    38. E. T. Kang, K. L. Tan, K. Kato, Y. Uyama and Y. Ikada, Macromolecules, 29, p.6872(1996).
    39. E. T. Kang, K. G. Neoh, Z. F. Li, K. L. Tan and D. J. Liaw, Polymer, 39, p.2429(1998).
    40. L. Y. Ji, E. T. Kang, K. G. Neoh and K. L. Tan, Macromolecules, 32, p.8183(1999).
    41. Tie Wang, E. T. Kang, K. G. Neoh, K. L. Tan, C. Q. Cui and T. B. Lin, J. Adhesion Sci. Technol., 11, p.679(1997).
    42. Junfeng Zhang, C. Q. Cui, T. B. Lin, E. T. Kang, K. G. Neoh, J. Adhesion Sci. Technol., 12, p.1205(1998).
    43. M. C. Zhang, E. T. Kang, K. G. Neoh, H. S. Han and K. L. Tan, Polymer, 40, p.299(1999).
    44. Chi-Yuan Huang, Wen-Yen Chiang, Angew. Makromol. Chem., 209, p.9(1993).
    45. R. Holm and S. Storp, Surf. Interface Anal., 2(3), 96(1980).
    46. G. Kampf, Hanser Publishers, New York, 1986, Ch.7, p.233.
    47. Z. F. Li and A. N. Netravali, J. Appl. Polym. Sci., 44, 319(1992).
    48. S. Lehmann, R. Robinson, and M. K. Tes, 31st International SAMPE Sympos., April 7-10, 1986, p.291.
    49. W. C. Wake, Polymer, 19, 291(1978).
    50. J. B. Donnet, M. Brendle, T. L. Dhami, and O. P. Bahl, Carbon, 24, 757(1986).
    51. T. F. Cooke, J. Polym. Eng., 7, 179(1986).
    52. L. A. Belfiore, R. J. Shah, and C. Cheng, Polym. Composites, 10, 122(1989).
    53. L. Dilandro and M. Pegoraro, J. Mater. Sci., 22,1980(1987).
    54. J. R. Hollahan, B. B. Stafford, R. D. Falb and S. T. Payne, J. Appl. Polym. Sci., 13, p.807(1969).
    55. J. P. Badey, E. Espuche, D. Sage, B. Chabert, Y. Jugnet, C. Batier and Tran Minh Duc, Polymer, 37, p.1377(1996).
    56. K. S. Chen, Yoshikimi Uyama and Yoshito Ikada, J. Adhesion Sci. Technol., 6, p.1023(1992).
    57. G. Socrates, Infrared Characteristic Group Frequencies, Juhn Wiley & Sons, Ltd. (1980).
    58. N. Sprang, D. Theirich, J. Engemann, Surface and Coatings Technology, 98, p.865(1998).
    59. G. E. Muilenburg, Ed. Handbook of X-ray Photoelectron Spectroscopy, Perkin- Elmer, Eden Prarie, MN, 1997.
    60. T. R. Gegenbach, X. Xie, R. C. Chatelier and H. J. Griesser, in Plasma Surface Modifications of Polymer: Relevance to Adhesion, M. Strobel, C. S. Lyons and K. L. Mittal, (Eds.), p.123, VSP, Utrecht,1994.
    61. H. J. Griesser, D. Youxian, A. E. Hughes, T. R. Gegenbach and A. W. H. Mau, Langmuir, 7, p.2484(1991).
    62. F. M. Fowkes, Ind. Eng. Chem. 56, p.40(1964).
    63. J. P. Badey, E. Urbaczewski-Espuche, Y. Jugnet, D. Sage, Tran Minh Duc and B. Chabert, Polymer, 35, p.2472(1994).
    64. N. Inagaki, S. Tasaka and H. Kawai, J. Adhesion Sci. Techonl., 3, p.637(1989).
    65. Y. D. Youxian, J. H. Griesser, H. W. A. Mau and R. Schmidt, Polymer, 32, p.1126(1991).

    QR CODE
    :::