| 研究生: |
許智偉 Chih-wei Hsu |
|---|---|
| 論文名稱: |
好氧堆肥及蚯蚓處理造紙污泥之研究 Aerobic composting and Vermicomosting of paper-mill sludge |
| 指導教授: |
曾迪華
Dyi-Hwa Tseng |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程研究所在職專班 Executive Master of Environmental Engineering |
| 畢業學年度: | 98 |
| 語文別: | 中文 |
| 論文頁數: | 128 |
| 中文關鍵詞: | 初始蚯蚓植入密度 、蚯蚓處理 、蚯蚓餵食負荷 、造紙污泥 、好氧堆肥 |
| 外文關鍵詞: | earthworm seeding density, feed loading rate, paper-mill sludge, vermicomposting, aerobic composting |
| 相關次數: | 點閱:12 下載:0 |
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造紙製程廢水的處理過程中,衍生了大量造紙污泥,如缺乏適當處理方法,會影響環境衛生及造成土地污染。有鑑於此,本研究運用好氧堆肥及蚯蚓之處理方法,以造紙污泥及其他有機廢棄物為堆肥材料,評估堆肥製作之可行性。
本研究堆肥材料組成分別為造紙污泥混合牛糞及造紙污泥混合豬糞及稻殼,放置於1m3容積的通氣式堆肥槽,進行好氧堆肥,運用好氧堆肥嗜熱期之高溫反應使堆肥材料穩定化,反應溫度下降至40℃以下,取出進行30天的蚯蚓處理。
堆肥材料經好氧堆肥後,根據堆肥的外觀及性質分析,作為後續適合蚯蚓處理的素材。另外根據30天後蚯蚓生長的狀況觀察,於堆肥中具有完整蚯蚓生長循環(卵包、幼蚓、無環帶蚯蚓及成蚓(有環帶蚯蚓)),為適合蚯蚓生長的基質。
試驗結果顯示,於不同初始蚯蚓植入密度下,處理造紙污泥混合牛糞最適操作條件為,初始蚯蚓植入密度4.5kg/m2及蚯蚓餵食負荷1.33 kg-feed/kg-worm/day,於不同通氣條件下,處理造紙污泥混合豬糞及稻殼最適操作條件為,初始蚯蚓植入密度4.5kg/m2、蚯蚓餵食負荷1.51 kg-feed/kg-worm/day及通氣量0.04 L-air/min/L-compost 。
本研究之造紙污泥經好氧堆肥及蚯蚓處理後的完熟堆肥,其結構呈現結實及緊密之現象,外觀相當溼潤黏稠,堆肥中營養元素及重金屬含量,亦均符合雜項堆肥規範的要求。
The treatment of wastewater from papermaking processes generally produces large quantities of paper-mill sludge. If the sludge do not properly treat and dispose, it will cause the problems of environmental sanitation and soil pollution. Therefore, this study evaluates the feasibility of making composts from paper-mill sludge and other organic waste materials by aerobic composting and vermicomposting.
The experiments were firstly put the mixture of paper-mill sludge (PMS) with cattle manure (CM) and the mixture of PMS with pig manure(PM) and rice husk (RK) into two 1m3 of in-vessel composting tanks, respectively. Then, the mixture was composted under thermophilic stage reaction of Aerobic composting to stabilize the material until the temperature went down to below 40℃. Finally, the pretreated composts were taken out the vessel and following a 30-day vermicomposting process with Eisenia foetida.
The suitability of pretreated composts as materials for vermicomposting was based on the appearance and properties analysis after aerobic composting process. In addition, the suitability also based on the observation of earthworm growth condition after 30-day of vermicomposting process. If a whole earthworm’s life cycle included cocoons, young worms, non-clitellated worms and clitellated worms were found in the composts, thus the materials were suitable for the growth of Eisenia foetida.
Experimental results indicated that the optimum earthworm seeding density was 4.5 kg/m2 and feed loading rate was 1.33 kg-feed/kg-worm/day for vermicomposting of the mixture of PMS with CM. In addition, the optimum air-flow rate for vermicomposting of the mixture of PMS with PM and RK was 0.04 L-air/min/L-compost at the conditions of 4.5 kg/m2 earthworm seeding density and 1.51 kg-feed/kg-worm/day feed loading rate.
The mature composts, converting from paper-mill sludge after aerobic composting and vermicomposting in this study, had good quality with moist appearance and adhesive texture. The contents of various nutrition elements and heavy metals in composts are also met the specification for plant growth
1.C.S.lin, L.P.Liu, S.F.Cheng, J.Huang & Y.Y.Kao, "Current Status and
Future Prospects of Industrial Sludge Recycling In Taiwan ",Proceedings of the 8th International Symposium on East Asian Resources Recycling Technology, pp. 127-133 (2005)
2.台灣區造紙同業公會,「台灣造紙工業統計」(2008)
3.李典友、潘根興、向昌國、褚清河、丁玉川,「土壤中蚯蚓資源 的開發應用
及展望」,農業資源與環境科學第21卷第10期 (2005)
4.天下雜誌股份有限公司,「天下雜誌」,第382期(2007)
5.劉庄泉,周毅,楊健,「蚯蚓在城市垃圾中的综合應用」,重慶環境科學第25卷第11期 (2003)
6.彰化銀行,「產業動態報導」(2009)
7.經濟部工業局,「經濟部工業生產統計月報」(2002)
8.行政院環境保護署,「廢棄物30年紀實」(2008)
9.經濟部工業局,「工業技術人才培訓計畫講義」
10.經濟部工業局,「造紙業水污染防治技術」 (1993)
11.行政院農委會,「肥料種類品目及規格」(2008)
12.經濟部工業局,「造紙業環保工安整合性技術手冊」(2000)
13.行政院環境保護署,「廢棄物申報統計資料」(2002)
14.經濟部工業局,工業廢棄物清理與資源化資訊網 http://www.moeaidb.gov.tw/(2008)
15.北京中綠華業有限公司,「中國環保商情」http://www.china-epa.com/ (2009)
16.TAKUMA CO., LTD.,「商品情報」
http://www.takuma.co.jp/index.html(2009)。
17.柴曉利,張華,趙由才,「固體廢物堆肥原理與技術(2005)
18.Narayan, R., "Biodegradation of polymeric materials (anthropogenic macromolecules) during composting", Science and Engineering of Composting: Design, Environmental, Microbiological and Utilization Aspects.Renaissance Pub., Worthington, Ohio, pp. 339-362 (2003)
19.王德漢,彭俊傑,戴 苗,「造紙污泥交替式好氧厭氧堆肥實驗」,中國造紙學報第18卷第1期 (2003).
20.周少奇,林雲琴,李 端,「造紙污泥好氧堆肥處理技術研究」,中國造紙學報第24卷第6期 (2005)
21.Rantala, P.- R., Vaajasaari, K., Juvonen, R., Schultz, E., Joutti, A. & Mäkelä-Kurtto, R., "Composting of forest industry wastewater sludges for agricultural use", Water Science and Technology, vol. 40, no. 11-12, pp. 187-194(1999)
22.Rantala, P.-.R, Vaajasaari, K., Juvonen, R., Schultz, E., Joutti, A. & Makela-Kurtto, R., "Composting and utilization of forest industry wastewater sludges", Water Science & Technology, vol. 42, no. 9, pp. 227-234(2000)
23.Jokela, J., Rintala, J., Oikari, A., Reinikainen, O., Mutka, K. & Nyrönen, T., "Aerobic composting and anaerobic digestion of pulp and paper mill sludges", Water Science and Technology, vol. 36, no. 11, pp. 181-188 (1997)
24.吳國雄,「食品廢棄物好氧生物降解」,碩士論文,國立高雄第一科技大學環境與安全衛生工程系 (2003)
25.謝錦松,黃正義,「固體廢物處理」(1991)
26.林財旺,「禽畜糞堆肥之製造」,堆肥製造技術,行政院農業委員會農業試驗所(1999)
27.簡宣裕,「製造堆肥時材料的碳氮比及水分含量之調整」,堆肥製造技術,行政院農業委員會農業試驗所(1999)
28.林財旺,「禽畜糞堆肥化處理」,堆肥技術及其利用研討會論文集,中華生質能源學會(1994)
29.官路,「下水污泥堆肥化操作因數之研究」,碩士論文,國立中央大學土木工程學研究所(1990)
30.Mohajer, A., Trémier, A., Barrington, S., Martinez, J., Teglia, C. & Carone, M., "Microbial oxygen uptake in sludge as influenced by compost physical parameters", Waste Management, vol. 29, no. 8, pp. 2257-2264(2009)
31.K.C.Das.E.W.Tollner and M.A.Eiteman “Improving composting by control of the Solid Matrix Structue”, Reserch and Development Session(2009)
32.鄭正勇,「堆肥是什麼」台大園藝系
http://ecaaser3.ecaa.ntu.edu.tw/weifang/compost/(2009)
33.林家棻,「如何飼養蚯蚓化廚房垃圾為金肥」,《園藝之友》第68~70期 http://www.tari.gov.tw/霧峰總所/合理化施肥/蚯蚓/(2009)
34.Frederickson, J., Howell, G., Hobson, A. & Lane, J., "Adding value to waste derived compost: performance and environmental impact of a combined in-vessel composting and vermicomposting system"(2006)
35.Butt, K.R., "Utilisation of solid paper-mill sludge and spent brewery yeast as a feed for soil-dwelling earthworms", Bioresource technology, vol. 44, no. 2, pp. 105-107(1993)
36.Elvira, C., Goicoechea, M., Sampedro, L., Mato, S. & Nogales, R., "Bioconversion of solid paper-pulp mill sludge by earthworms", Bioresource technology, vol. 57, no. 2, pp. 173-177(1996)
37.Elvira, C., Sampedro, L., Benítez, E. & Nogales, R., "Vermicomposting of sludges from paper mill and dairy industries with Eisenia andrei: A pilot-scale study", Bioresource technology, vol. 63, no. 3, pp. 205-211(1998)
38.Piearce, T.G., Budd, T., Hayhoe, J.M., Sleep, D. & Clasper, P.J., "Earthworms of a land restoration site treated with paper mill sludge: The 7th international symposium on earthworm ecology • Cardiff • Wales • 2002", Pedobiologia, vol. 47, no. 5-6, pp. 792-795(2003)
39.Kaushik, P. & Garg, V.K., "Vermicomposting of mixed solid textile mill sludge and cow dung with the epigeic earthworm Eisenia foetida", Bioresource technology, vol. 90, no. 3, pp. 311-316(2003)
40.Kaplan, D.L., Hartenstein, R., Neuhauser, E.F. & Malecki, M.R., "Physicochemical requirements in the environment of the earthworm Eisenia foetida", Soil Biology and Biochemistry, vol. 12, no. 4, pp. 347-352(1980)
41.沈明星,王海候,沈曉萍,陳長嬰,吳彤東,劉鳳軍,施林林,姚月明,「溫度對蚯蚓處理牛糞能力的影響及其調控效果」,江蘇農業科學第3期 (2008)
42.陳德牛與張國慶,「蚯蚓養殖技術」(2008)
43.Ndegwa, P.M. & Thompson, S.A., "Effects of C-to-N ratio on vermicomposting of biosolids", Bioresource technology, vol. 75, no. 1, pp. 7-12.(2000)
44.Sherman, R., "Raising earthworms successfully", North Carolina Extension Service, North Carolina State University USA (2003)
45.Suthar, S., "Vermicomposting of vegetable-market solid waste using Eisenia fetida: Impact of bulking material on earthworm growth and decomposition rate", Ecological Engineering, vol. 35, no. 5, pp. 914-920 (2009)
46.Aira, M., Monroy, F. & Domínguez, J. , "Earthworms strongly modify microbial biomass and activity triggering enzymatic activities during vermicomposting independently of the application rates of pig slurry", Science of The Total Environment, vol. 385, no. 1-3, pp. 252-261(2007)
47.Frederickson, J., Howell, G. & Hobson, A.M., "Effect of pre-composting and vermicomposting on compost characteristics", European Journal of Soil Biology, vol. 43, no. Supplement 1, pp. S320-S326(2007)
48.李芳胤與陳士賢,「土壤分析實驗手冊」(2007)
49.Lazzari, L., Sperni, L., Bertin, P., Pavoni, B., “Correlation between inorganic (heavy metals) and organic (PCBs and PAHs) micropollutant concentrations during sewage sludge composting processes”, Chemosphere, Vol. 41, pp. 427-435(2000)
50.Zorpas, A.A., Constantinides, T., Vlyssides, A.G., Haralambous, I.,Loizidou, M., “Heavy metal uptake by natural zeolite and metals partitioning in sewage sludgecompost”, Bioresource Technology, Vol. 72, pp. 113-119(2000)
51.Hsu, J.H., Lo, S.L., “Effect of composting on characterization and leaching of copper, manganese, and zinc from swine manure”, Environmental Pollution, Vol.114, pp.119-127(2001)
52.Qiao, L., Ho, G., “The effects of clay amendment and composting on metal speciation in digested sludge”, Wat. Res., Vol. 31, No. 5, pp. 951-964(1997)
53.Ndegwa, P.M. & Thompson, S.A., "Integrating composting and vermicomposting in the treatment and bioconversion of biosolids", Bioresource technology, vol. 76, no. 2, pp. 107-112 (2001)
54.Kula, H. & Larink, O., "Development and standardization of test methods for the prediction of sublethal effects of chemicals on earthworms", Soil Biology and Biochemistry, vol. 29, no. 3-4, pp. 635-639 (1997)
55.梁容鐘,「以蚯蚓生長及生殖評估土壤重金屬污染之可行性研究」,碩士論文,國立中興大學土壤環境科學系(2003)
56.伏小勇,楊柳,黃魁,倪少仁,許生輝,「蚯蚓對城市污泥中鉛的富集作用」,蘭州安全與環境工程科學第15卷第2期 (2008)