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研究生: 江承恩
Cheng-en Jiang
論文名稱: 以超短脈衝雷射沉積技術製作鍺/矽薄膜之研究
growth of Ge/Si thin film with ultrashort pulse laser deposition and its study
指導教授: 陳賜原
Szu-yuan Chen
口試委員:
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
畢業學年度: 99
語文別: 中文
論文頁數: 80
中文關鍵詞: 超短脈衝雷射沉積鍺/矽薄膜
外文關鍵詞: ultrashort pulse laser deposition, Ge/Si thin film
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  • 探討以超短脈衝雷射沉積技術製作鍺/矽薄膜之表面型態學。主
    要以原子力顯微鏡(AFM)作為主要診斷工具,包含了解鍺薄膜成長的
    時間演化過程、膜厚與基板溫度對磊晶成長的影響、電漿噴流密度之
    角度分布定性分析。
    接著,並使用共焦拉曼螢光顯微鏡量測鍺薄膜的拉曼光譜,由拉
    曼偏移訊號半高寬判斷鍺薄膜的結晶性,並與原子力顯微鏡觀察到的
    表面結構比較。
    最後,比較原子力顯微鏡與膜厚量測器(alpha stepper)所量測
    的薄膜表面高低起伏程度是否結果一致。並根據alpha stepper 量測
    之鍺薄膜平均膜厚值、雷射發數,進一步得到每發雷射所成長的平均
    膜厚。
    未來工作將參考每發雷射所成長的平均膜厚值,以超短脈衝雷
    射沉積技術製作鍺/矽量子點。同時在進行量子點製程時,以中紅外
    光控制量子點的大小。以期將尺寸大小相同的量子點應用於量子計算
    實驗中。


    We show that the islands formed in Stranski-Krastanow (SKI growth of Ge on Si(100) are initially
    dislocation-free. Island formation in true SK growth should be driven by strain relaxation in large,
    dislocated islands. Coherent SK growth is explained in terms of elastic deformation around the islands,
    which partially accommodates mismatch. The limiting critical thickness, h,, of coherent SK islands is
    shown to be higher than that for 2D growth. We demonstrate growth of dislocation-free Ge islands on
    Si to a thickness of -- 500 A, 50x higher than h, for 2D GeISi epitaxy.

    中文摘要 英文摘要 致謝 目錄 圖目錄 第一章 緒論........................................1 . 第二章 共焦拉曼與螢光顯微鏡之原理與設計............8 2-1 共焦顯微鏡的介紹...........................8 2-1-1 共焦顯微鏡之原理及優點................8 2-1-2 共焦顯微鏡之理論.....................10 2-2 拉曼效應之機制............................13 2-3 共焦拉曼與螢光顯微鏡......................15 2-3-1 光學架構.............................15 2-3-2 光譜校正.............................22 第三章 飛秒級脈衝雷射沉積系統 3-1 脈衝雷射沉積法簡介........................25 3-2 脈衝雷射沉積法的機制......................26 3-3 PLD光路...................................28 3-4 實驗硬體設備..............................29 第四章 超短脈衝雷射沉積(uPLD)技術製作鍺/矽薄膜及其診斷 ……………………………………………………………… 32 4-1 以化學方法清洗矽基板流程...........................32 4-2 以原子力顯微鏡診斷鍺/矽薄膜之結果………………………33 第五章 實驗結果分析與討論………………………………… 47 5-1 鍺/矽薄膜表面形態及其物理研究……………………………47 5-2 鍺/矽薄膜之拉曼光譜與結晶相………………………………53 5-3 鍺/矽薄膜表面平整度與uPLD 參數校正.................55 第六章 結論及後續工作..................................59 附錄...................................................60 參考文獻...............................................67

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